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Cooperative Interactions in Methanol-Water Mixtures Studied by Microwave Dielectric Data
Corresponding Author(s) : Yong-Qiang Chen
Asian Journal of Chemistry,
Vol. 27 No. 3 (2015): Vol 27 Issue 3
Abstract
Based on the dielectric data, the methanol-water mixtures in the water rich region (0-0.1) at 293, 298 and 303 K were performed. We estimated the cooperative interaction of methanol-water cluster by extended Froehlich theory. We get different aspect of the interaction of molecules, which help to understand the relaxation acts.
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- L.P. Singh and R. Richert, Phys. Rev. Lett., 109, 167802 (2012); doi:10.1103/PhysRevLett.109.167802.
- H. Fröhlich, Theory of Dielectrics, Clarendon Press Oxford (1958).
- C.J.F. Böttcher, O.C. van Belle, P. Bordewijk and A. Rip, Theory of Electric Polarization, Elsevier, Amsterdam (1973).
- C.J.F. Böttcher and P. Bordewijk, Theory of Electric Polarization, Vol. II, Elsevier Scientific Publishing Company, Amsterdam, Oxford, New York (1978).
- J.N. Murrell and A.D. Jenkins, Properties of Liquids and Solutions, Wiley & Sons, edn 2 (1994).
- J.B. Hasted, Aqueous Dielectrics, Chapman and Hall, London (1973).
- T. Sato, A. Chiba and R. Nozaki, J. Chem. Phys., 112, 2924 (2000); doi:10.1063/1.480865.
- E. Levy, A. Puzenko, U. Kaatze, P.B. Ishai and Y. Feldman, J. Chem. Phys., 136, 114502 (2012); doi:10.1063/1.3687914.
References
L.P. Singh and R. Richert, Phys. Rev. Lett., 109, 167802 (2012); doi:10.1103/PhysRevLett.109.167802.
H. Fröhlich, Theory of Dielectrics, Clarendon Press Oxford (1958).
C.J.F. Böttcher, O.C. van Belle, P. Bordewijk and A. Rip, Theory of Electric Polarization, Elsevier, Amsterdam (1973).
C.J.F. Böttcher and P. Bordewijk, Theory of Electric Polarization, Vol. II, Elsevier Scientific Publishing Company, Amsterdam, Oxford, New York (1978).
J.N. Murrell and A.D. Jenkins, Properties of Liquids and Solutions, Wiley & Sons, edn 2 (1994).
J.B. Hasted, Aqueous Dielectrics, Chapman and Hall, London (1973).
T. Sato, A. Chiba and R. Nozaki, J. Chem. Phys., 112, 2924 (2000); doi:10.1063/1.480865.
E. Levy, A. Puzenko, U. Kaatze, P.B. Ishai and Y. Feldman, J. Chem. Phys., 136, 114502 (2012); doi:10.1063/1.3687914.