Synthesis, Crystal Structure of One-Dimensional Chains {[Zn(ip)(py)2]&middot;NMP}n (py = Pyridine, NMP = N-methyl-pyrrolidone, H2ip = Isophthalic acid)

F.K. Wang

doi:10.14233/ajchem.2015.17901

Issue

Vol. 27 No. 2 (2015): Vol 27 Issue 2

Issue Published : January 10, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis, Crystal Structure of One-Dimensional Chains {[Zn(ip)(py)2]·NMP}n (py = Pyridine, NMP = N-methyl-pyrrolidone, H2ip = Isophthalic acid)

https://doi.org/10.14233/ajchem.2015.17901

F.K. Wang

College of Material and Chemical Engineering, Research Center for Solar Photovoltaic Material Development and Application, West Anhui University, Lu'an 237012, P.R. China

Corresponding Author(s) : F.K. Wang

wangfangkuo2491@126.com

Asian Journal of Chemistry, Vol. 27 No. 2 (2015): Vol 27 Issue 2
Article Published : January 10, 2015

Abstract

Hot-solution reactions of Zn(NO₃)₂·6H₂O, pyridine (py) with isophthalic acid (H₂ip) in N-methyl-pyrrolidone (NMP) yields one-dimensional (1D) coordination polymer. Single crystal analysis show that compound 1, {[Zn(ip)(py)₂]·NMP}_n with 1D zigzag chains and every two chains face to face to form the slide fastener. Crystal data of 1 are, orthorhombic, space group P, a = 8.5960(3), b = 10.1091(4), c = 26.2070(10), Z = 4. The results indicate that the geometry of ligands play the important roles in the frameworks of products.

Keywords

1D Zigzag Chains Pyridine Crystal structure

Wang, F. (2015). Synthesis, Crystal Structure of One-Dimensional Chains {[Zn(ip)(py)2]·NMP}n (py = Pyridine, NMP = N-methyl-pyrrolidone, H2ip = Isophthalic acid). Asian Journal of Chemistry, 27(2), 722–724. https://doi.org/10.14233/ajchem.2015.17901

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