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Thermal Degradation Mechanism of UV Curable Intumescent Flame Retardant Coating Based on Acryloyloxyethylneopentyl Phosphate
Corresponding Author(s) : Hongbo Liang
Asian Journal of Chemistry,
Vol. 27 No. 2 (2015): Vol 27 Issue 2
Abstract
In this work, series of UV curable intumescent flame retardants were prepared by blending acryloyloxyethylneopentyl phosphate with methacrylated phenolic melamine and pentaerythritol triacrylate. The thermal degradation mechanism of their cured films was studied by thermogravimetric analysis and in situ Fourier-transform infrared spectroscopy and a possible mechanism for the thermal degradation was proposed. The limiting oxygen index values of the cured films were measured. The expansion behaviors were also studied by unidirectional expansion degree. The results showed that the ANP/MAPM/PETA (35/25/40, wt/wt/wt) blend (ANP35MAPM25PETA40) had the best comprehensive properties among all the samples.
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- H.B. Liang, W.F. Shi and M. Gong, Polym. Degrad. Stab., 90, 1 (2005); doi:10.1016/j.polymdegradstab.2005.01.022.
- Y. Chen, Y. Liu, Q. Wang, H. Yin, N. Aelmans and R. Kierkels, Polym. Degrad. Stab., 81, 215 (2003); doi:10.1016/S0141-3910(03)00091-0.
- Y. Cao, Y. Chen, L. Lu, Z. Xue and T. Mu, Ind. Eng. Chem. Res., 52, 2073 (2013); doi:10.1021/ie302850z.
- K. Cao, S.L. Wu, K.L. Wang and Z. Yao, Ind. Eng. Chem. Res., 50, 8402 (2011); doi:10.1021/ie2007938.
- Z.Z. Wang, K. Wu and Y. Hu, Polym. Eng. Sci., 48, 2426 (2008); doi:10.1002/pen.21198.
- Y.J. Chen, J. Zhan, P. Zhang, S.B. Nie, H.D. Lu, L. Song and Y. Hu, Ind. Eng. Chem. Res., 49, 8200 (2010); doi:10.1021/ie100989j.
- S. Bourbigot and S. Duquesne, Mater. Chem., 17, 2283 (2007); doi:10.1039/b702511d.
- S. Bourbigot, M. Le Bras, S. Duquesne and M. Rochery, Macromol. Mater. Eng., 289, 499 (2004); doi:10.1002/mame.200400007.
- L.J. Chen, L. Song, P. Lv, G.X. Jie, Q.L. Tai, W.Y. Xing and Y. Hu, Prog. Org. Coat., 70, 59 (2011); doi:10.1016/j.porgcoat.2010.10.002.
- Y.X. Wang and H.W. Jiang, Acta. Polym. Sin, 9, 325 (2009); doi:10.3724/SP.J.1105.2009.00325.
- Y.M. Chen, H.B. Liang and L. Xiong, Inform. Recording Mater., 11, 29 (2010).
- H. Liang, A. Asif and W. Shi, Polym. Degrad. Stab., 87, 495 (2005); doi:10.1016/j.polymdegradstab.2004.10.006.
- X.L. Chen, Y. Hu, C.M. Jiao and L. Song, Prog. Org. Coat., 59, 318 (2007); doi:10.1016/j.porgcoat.2007.05.002.
References
H.B. Liang, W.F. Shi and M. Gong, Polym. Degrad. Stab., 90, 1 (2005); doi:10.1016/j.polymdegradstab.2005.01.022.
Y. Chen, Y. Liu, Q. Wang, H. Yin, N. Aelmans and R. Kierkels, Polym. Degrad. Stab., 81, 215 (2003); doi:10.1016/S0141-3910(03)00091-0.
Y. Cao, Y. Chen, L. Lu, Z. Xue and T. Mu, Ind. Eng. Chem. Res., 52, 2073 (2013); doi:10.1021/ie302850z.
K. Cao, S.L. Wu, K.L. Wang and Z. Yao, Ind. Eng. Chem. Res., 50, 8402 (2011); doi:10.1021/ie2007938.
Z.Z. Wang, K. Wu and Y. Hu, Polym. Eng. Sci., 48, 2426 (2008); doi:10.1002/pen.21198.
Y.J. Chen, J. Zhan, P. Zhang, S.B. Nie, H.D. Lu, L. Song and Y. Hu, Ind. Eng. Chem. Res., 49, 8200 (2010); doi:10.1021/ie100989j.
S. Bourbigot and S. Duquesne, Mater. Chem., 17, 2283 (2007); doi:10.1039/b702511d.
S. Bourbigot, M. Le Bras, S. Duquesne and M. Rochery, Macromol. Mater. Eng., 289, 499 (2004); doi:10.1002/mame.200400007.
L.J. Chen, L. Song, P. Lv, G.X. Jie, Q.L. Tai, W.Y. Xing and Y. Hu, Prog. Org. Coat., 70, 59 (2011); doi:10.1016/j.porgcoat.2010.10.002.
Y.X. Wang and H.W. Jiang, Acta. Polym. Sin, 9, 325 (2009); doi:10.3724/SP.J.1105.2009.00325.
Y.M. Chen, H.B. Liang and L. Xiong, Inform. Recording Mater., 11, 29 (2010).
H. Liang, A. Asif and W. Shi, Polym. Degrad. Stab., 87, 495 (2005); doi:10.1016/j.polymdegradstab.2004.10.006.
X.L. Chen, Y. Hu, C.M. Jiao and L. Song, Prog. Org. Coat., 59, 318 (2007); doi:10.1016/j.porgcoat.2007.05.002.