Synthesis and Characterization of Self-Assembled Porous Microspheres of Poly(o-chloroaniline)

Muhammad Naveed Anjum; Khalid Mahmood Zia; Lihua Zhu; Mirza Nadeem Ahmad; Tahir Farooq; Mohammad Zuber; Heqing Tang

doi:10.14233/ajchem.2015.17035

Issue

Vol. 27 No. 2 (2015): Vol 27 Issue 2

Issue Published : January 10, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Characterization of Self-Assembled Porous Microspheres of Poly(o-chloroaniline)

https://doi.org/10.14233/ajchem.2015.17035

Muhammad Naveed Anjum

Institute of Chemistry, Government College University, Faisalabad-38030, Pakistan; College of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, P.R. China

Khalid Mahmood Zia

Institute of Chemistry, Government College University, Faisalabad-38030, Pakistan

Lihua Zhu

College of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, P.R. China

Mirza Nadeem Ahmad

Institute of Chemistry, Government College University, Faisalabad-38030, Pakistan

Tahir Farooq

Institute of Chemistry, Government College University, Faisalabad-38030, Pakistan

Mohammad Zuber

Institute of Chemistry, Government College University, Faisalabad-38030, Pakistan

Heqing Tang

Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission and Ministry of Education, College of Chemistry and Materials Science, South-Central University for Nationalities, Wuhan 430074, P.R. China

Corresponding Author(s) : Muhammad Naveed Anjum

anjumccj@hotmail.com

Asian Journal of Chemistry, Vol. 27 No. 2 (2015): Vol 27 Issue 2
Article Published : January 10, 2015

Abstract

Self-assembled porous microspheres poly(o-chloroaniline) have been fabricated by simple oxidative polymerization of o-chloroaniline with camphor-sulfonic acid as dopant acid and ammonium persulfate as oxidant. In the synthesis system, formation of micelles of camphor-sulfonic acid in aqueous solution is a key factor in fabrication of porous microspheres of poly(o-chloroaniline). The conducting poly(o-chloroaniline) microspheres were characterized by means of Fourier transform infrared spectroscopy, UV-visible spectroscopy, X-ray diffraction and scanning electron microscopy. A mechanism has been proposed to explain the formation of poly(o-chloroaniline) microsphere which was supported by UV-visible spectroscopy and SEM data.

Keywords

Porous microspheres Poly(o-chloroaniline) Self-assembly

Naveed Anjum, M., Mahmood Zia, K., Zhu, L., Nadeem Ahmad, M., Farooq, T., Zuber, M., & Tang, H. (2015). Synthesis and Characterization of Self-Assembled Porous Microspheres of Poly(o-chloroaniline). Asian Journal of Chemistry, 27(2), 561–564. https://doi.org/10.14233/ajchem.2015.17035

Download Citation

References

M.A. Abidian, H.D. Kim and D.C. Martin, Adv. Mater., 18, 405 (2006); doi:10.1002/adma.200501726.
L. Zhang, Z. Zhang, P.A. Kilmartin and J. Travas-Sejdic, Macromol. Chem. Phys., 212, 2674 (2011); doi:10.1002/macp.201100379.
Y. Yang, Y. Chu, F. Yang and Y. Zhang, Mater. Chem. Phys., 92, 164 (2005); doi:10.1016/j.matchemphys.2005.01.007.
C.S. Guo and C.M. Li, Phys. Chem. Chem. Phys., 12, 12153 (2010); doi:10.1039/c0cp00378f.
S. Virji, J. Huang, R.B. Kaner and B.H. Weiller, Nano Lett., 4, 491 (2004); doi:10.1021/nl035122e.
B.M. Lee, J.E. Kim, F.F. Fang, H.J. Choi and J.F. Feller, Macromol. Chem. Phys., 212, 2300 (2011); doi:10.1002/macp.201100306.
K. Ramanathan, M.A. Bangar, M. Yun, W. Chen, N.V. Myung and A. Mulchandani, J. Am. Chem. Soc., 127, 496 (2005); doi:10.1021/ja044486l.
S.Y. Park, M.S. Cho, C.A. Kim, H.J. Choi and M.S. Jhon, Colloid Polym. Sci., 282, 198 (2003); doi:10.1007/s00396-003-0998-7.
K. Ishizu, H. Tanaka, R. Saito, T. Maruyama and T. Yamamoto, Polymer, 37, 863 (1996); doi:10.1016/0032-3861(96)87266-1.
L. Yang, Z. Yang and W. Cao, J. Colloid Interf. Sci., 292, 503 (2005); doi:10.1016/j.jcis.2005.05.084.
L. Hao, C. Zhu, C. Chen, P. Kang, Y. Hu, W. Fan and Z. Chen, Synth. Met., 139, 391 (2003); doi:10.1016/S0379-6779(03)00193-0.
L. Zhang, H. Peng, P.A. Kilmartin, C. Soeller, R. Tilley and J. Travas-Sejdic, Macromol. Rapid Commun., 29, 598 (2008); doi:10.1002/marc.200700771.
J. Han, G. Song and R. Guo, Adv. Mater., 18, 3140 (2006); doi:10.1002/adma.200600282.
L. Zhang, M. Wan and Y. Wei, Macromol. Rapid Commun., 27, 888 (2006); doi:10.1002/marc.200600134.
Z. Wei and M. Wan, Adv. Mater., 14, 1314 (2002); doi:10.1002/1521-4095(20020916)14:18<1314::AID-ADMA1314>3.0.CO;2-9.
L. Zhang, H. Peng, J. Sui, C. Soeller, P.A. Kilmartin and J. Travas-Sejdic, J. Phys. Chem. C, 113, 9128 (2009); doi:10.1021/jp900267t.
J. Sui, L. Zhang, H. Peng, J. Travas-Sejdic and P.A. Kilmartin, Nanotechnology, 20, 415 (2009); doi:10.1088/0957-4484/20/41/415606.
X. Wang, N. Liu, X. Yan, W. Zhang and Y. Wei, Chem. Lett., 34, 42 (2005); doi:10.1246/cl.2005.42.
W. Li and H.L. Wang, J. Am. Chem. Soc., 126, 2278 (2004); doi:10.1021/ja039672q.
F. Yan and G. Xue, J. Mater. Chem., 9, 3035 (1999); doi:10.1039/a905146e.
S.A. Ashraf, L.A.P. Kane-Maguire, M.R. Majidi, S.G. Pyne and G.G. Wallace, Polymer, 38, 2627 (1997); doi:10.1016/S0032-3861(97)85595-4.
H.Q. Tang, A. Kitani and M. Shiotani, Electrochim. Acta, 41, 1561 (1996); doi:10.1016/0013-4686(95)00408-4.
M.R. Majidi, L.A.P. Kane-Maguire and G.G. Wallace, Polymer, 35, 3113 (1994); doi:10.1016/0032-3861(94)90427-8.
M.V. Kulkarni, A.K. Viswanath and P.K. Khanna, Int. J. Polym. Mater., 55, 501 (2006); doi:10.1080/00914030500210358.
I.D. Norris, L.A.P. Kane-Maguire and G.G. Wallace, Macromolecules, 33, 3237 (2000); doi:10.1021/ma991339c.
J.P. Pouget, M.E. Jozefowicz, A.J. Epstein, X. Tang and A.G. MacDiarmid, Macromolecules, 24, 779 (1991); doi:10.1021/ma00003a022.
S.K. Pillalamarri, F.D. Blum, A.T. Tokuhiro, J.G. Story and F.M. Bertino, Chem. Mater., 17, 227 (2005); doi:10.1021/cm0488478.
J. Li, L. Zhu, W. Luo, Y. Liu and H.Q. Tang, J. Phys. Chem. C, 111, 8383 (2007); doi:10.1021/jp068910b.
N.A. Zaidi, J.P. Foreman, G. Tzamalis, S.C. Monkman and A.P. Monkman, Adv. Funct. Mater., 14, 479 (2004); doi:10.1002/adfm.200305488.
M.N. Anjum, L. Zhu, Z. Luo, J. Yan and H.Q. Tang, Polymer, 52, 5795 (2011); doi:10.1016/j.polymer.2011.10.038.

References

M.A. Abidian, H.D. Kim and D.C. Martin, Adv. Mater., 18, 405 (2006); doi:10.1002/adma.200501726.

L. Zhang, Z. Zhang, P.A. Kilmartin and J. Travas-Sejdic, Macromol. Chem. Phys., 212, 2674 (2011); doi:10.1002/macp.201100379.

Y. Yang, Y. Chu, F. Yang and Y. Zhang, Mater. Chem. Phys., 92, 164 (2005); doi:10.1016/j.matchemphys.2005.01.007.

C.S. Guo and C.M. Li, Phys. Chem. Chem. Phys., 12, 12153 (2010); doi:10.1039/c0cp00378f.

S. Virji, J. Huang, R.B. Kaner and B.H. Weiller, Nano Lett., 4, 491 (2004); doi:10.1021/nl035122e.

B.M. Lee, J.E. Kim, F.F. Fang, H.J. Choi and J.F. Feller, Macromol. Chem. Phys., 212, 2300 (2011); doi:10.1002/macp.201100306.

K. Ramanathan, M.A. Bangar, M. Yun, W. Chen, N.V. Myung and A. Mulchandani, J. Am. Chem. Soc., 127, 496 (2005); doi:10.1021/ja044486l.

S.Y. Park, M.S. Cho, C.A. Kim, H.J. Choi and M.S. Jhon, Colloid Polym. Sci., 282, 198 (2003); doi:10.1007/s00396-003-0998-7.

K. Ishizu, H. Tanaka, R. Saito, T. Maruyama and T. Yamamoto, Polymer, 37, 863 (1996); doi:10.1016/0032-3861(96)87266-1.

L. Yang, Z. Yang and W. Cao, J. Colloid Interf. Sci., 292, 503 (2005); doi:10.1016/j.jcis.2005.05.084.

L. Hao, C. Zhu, C. Chen, P. Kang, Y. Hu, W. Fan and Z. Chen, Synth. Met., 139, 391 (2003); doi:10.1016/S0379-6779(03)00193-0.

L. Zhang, H. Peng, P.A. Kilmartin, C. Soeller, R. Tilley and J. Travas-Sejdic, Macromol. Rapid Commun., 29, 598 (2008); doi:10.1002/marc.200700771.

J. Han, G. Song and R. Guo, Adv. Mater., 18, 3140 (2006); doi:10.1002/adma.200600282.

L. Zhang, M. Wan and Y. Wei, Macromol. Rapid Commun., 27, 888 (2006); doi:10.1002/marc.200600134.

Z. Wei and M. Wan, Adv. Mater., 14, 1314 (2002); doi:10.1002/1521-4095(20020916)14:18<1314::AID-ADMA1314>3.0.CO;2-9.

L. Zhang, H. Peng, J. Sui, C. Soeller, P.A. Kilmartin and J. Travas-Sejdic, J. Phys. Chem. C, 113, 9128 (2009); doi:10.1021/jp900267t.

J. Sui, L. Zhang, H. Peng, J. Travas-Sejdic and P.A. Kilmartin, Nanotechnology, 20, 415 (2009); doi:10.1088/0957-4484/20/41/415606.

X. Wang, N. Liu, X. Yan, W. Zhang and Y. Wei, Chem. Lett., 34, 42 (2005); doi:10.1246/cl.2005.42.

W. Li and H.L. Wang, J. Am. Chem. Soc., 126, 2278 (2004); doi:10.1021/ja039672q.

F. Yan and G. Xue, J. Mater. Chem., 9, 3035 (1999); doi:10.1039/a905146e.

S.A. Ashraf, L.A.P. Kane-Maguire, M.R. Majidi, S.G. Pyne and G.G. Wallace, Polymer, 38, 2627 (1997); doi:10.1016/S0032-3861(97)85595-4.

H.Q. Tang, A. Kitani and M. Shiotani, Electrochim. Acta, 41, 1561 (1996); doi:10.1016/0013-4686(95)00408-4.

M.R. Majidi, L.A.P. Kane-Maguire and G.G. Wallace, Polymer, 35, 3113 (1994); doi:10.1016/0032-3861(94)90427-8.

M.V. Kulkarni, A.K. Viswanath and P.K. Khanna, Int. J. Polym. Mater., 55, 501 (2006); doi:10.1080/00914030500210358.

I.D. Norris, L.A.P. Kane-Maguire and G.G. Wallace, Macromolecules, 33, 3237 (2000); doi:10.1021/ma991339c.

J.P. Pouget, M.E. Jozefowicz, A.J. Epstein, X. Tang and A.G. MacDiarmid, Macromolecules, 24, 779 (1991); doi:10.1021/ma00003a022.

S.K. Pillalamarri, F.D. Blum, A.T. Tokuhiro, J.G. Story and F.M. Bertino, Chem. Mater., 17, 227 (2005); doi:10.1021/cm0488478.

J. Li, L. Zhu, W. Luo, Y. Liu and H.Q. Tang, J. Phys. Chem. C, 111, 8383 (2007); doi:10.1021/jp068910b.

N.A. Zaidi, J.P. Foreman, G. Tzamalis, S.C. Monkman and A.P. Monkman, Adv. Funct. Mater., 14, 479 (2004); doi:10.1002/adfm.200305488.

M.N. Anjum, L. Zhu, Z. Luo, J. Yan and H.Q. Tang, Polymer, 52, 5795 (2011); doi:10.1016/j.polymer.2011.10.038.

Issue

Vol. 27 No. 2 (2015): Vol 27 Issue 2

Synthesis and Characterization of Self-Assembled Porous Microspheres of Poly(o-chloroaniline)

Corresponding Author(s) : Muhammad Naveed Anjum

Abstract

Keywords

Full Article

Download Citation

References

Table Of Contents