Copyright (c) 2015 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Impact of UV/TiO2/H2O2 on Degradation of Disperse Red F3BS
Corresponding Author(s) : Tanveer Hussain Bokhari
Asian Journal of Chemistry,
Vol. 27 No. 1 (2015): Vol 27 Issue 1
Abstract
The object of this work was to establish methods for the treatment of dye disperse red F3BS using UV radiation in the presence of H2O2 and TiO2. The degradation was monitored through UV/visible, FTIR and GC-MS techniques. The efficiency of advanced oxidation processes was evaluated on the basis of extent of degradation, improvement of water quality parameters and cytotoxicity reduction. The toxicities were determined through allium cepa and shrimptest. The independent variables such as radiation dose, catalysts concentration, exposure time, pH, temperature, etc. were optimized for maximum degradation of dyes. The advanced oxidation processes showed promising efficiency for the degradation of pollutants and it was observed that g-irradiation in the presence of H2O2 was more efficient for the degradation of toxic residues, improvement in water quality parameters and toxicity reduction as compared to UV/TiO2/H2O2 treatment. From the results, it is also concluded that the advanced oxidation processes such as UV/TiO2/H2O2 could be successfully used for the treatment of industrial wastewater contain dyes at commercial scale because the water quality parameters values fall within the permissible limits recommended by the international environmental agencies.
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- J. Bianchi, E.L.G. Espindola and M.A. Marin-Morales, Ecotoxicol. Environ. Saf., 74, 826 (2011); doi:10.1016/j.ecoenv.2010.11.006.
- D.T. Sponza, Ecotoxicol. Environ. Saf., 54, 74 (2003); doi:10.1016/S0147-6513(02)00024-6.
- S. Tabrez, S. Shakil, M. Urooj, G.A. Damanhouri, A.M. Abuzenadah and M. Ahmad, J. Environ. Sci. Health, 29, 250 (2011); doi:10.1080/10590501.2011.601849.
- C.K. Grisolia, M.R. Bilich and L.M. Formigli, Ecotoxicol. Environ. Saf., 59, 123 (2004); doi:10.1016/j.ecoenv.2004.01.014.
- M.M. Hoshina and M.A. Marin-Morales, Ecotoxicol. Environ. Saf., 72, 2090 (2009); doi:10.1016/j.ecoenv.2009.07.002.
- D.M. Leme and M.A. Marin-Morales, Mutat. Res. Rev. Mutat. Res., 682, 71 (2009); doi:10.1016/j.mrrev.2009.06.002.
- D.M. Leme and M.A. Marin-Morales, Mutat. Res. Genet. Toxicol. Environ. Mutagen., 650, 80 (2008); doi:10.1016/j.mrgentox.2007.10.006.
- J. Margot, C. Kienle, A.S. Magnet, M. Weil, L. Rossi, L.F. de Alencastro, C. Abegglen, D. Thonney, N. Chèvre, M. Schärer and D.A. Barry, Sci. Total Environ., 461-462, 480 (2013); doi:10.1016/j.scitotenv.2013.05.034.
- F.P. Rodrigues, J.P.F. Angeli, M.S. Mantovani, C.L.B. Guedes and B.Q. Jordao, Genet. Mol. Biol., 33, 169 (2010); doi:10.1590/S1415-47572010005000006.
- J. Bai, H. Xu, Y. Zhang, Z. Peng and G. Xu, Biochem. Eng. J., 70, 115 (2013); doi:10.1016/j.bej.2012.10.009.
- B. Malmqvist and S. Rundle, Environ. Conserv., 29, 134 (2002); doi:10.1017/S0376892902000097.
- I. Oller, S. Malato and J.A. Sánchez-Pérez, Sci. Total Environ., 409, 4141 (2011); doi:10.1016/j.scitotenv.2010.08.061.
- T. Meyer and F. Wania, Atmos. Environ., 41, 2757 (2007); doi:10.1016/j.atmosenv.2006.11.053.
- K. Prevedouros, I.T. Cousins, R.C. Buck and S.H. Korzeniowski, Environ. Sci. Technol., 40, 32 (2006); doi:10.1021/es0512475.
- M. Auriol, Y. Filali-Meknassi, R.D. Tyagi, C.D. Adams and R.Y. Surampalli, Process Biochem., 41, 525 (2006); doi:10.1016/j.procbio.2005.09.017.
- N.N. Rao, K.M. Somasekhar, S.N. Kaul and L. Szpyrkowicz, J. Chem. Technol. Biotechnol., 76, 1124 (2001); doi:10.1002/jctb.493.
- M. Molinos-Senante, F. Hernández-Sancho and R. Sala-Garrido, J. Environ. Manage., 92, 3091 (2011); doi:10.1016/j.jenvman.2011.07.023.
- V.K. Singh and J. Singh, J. Environ. Biol., 27, 385 (2006).
- M. Wong, Chemosphere, 50, 775 (2003); doi:10.1016/S0045-6535(02)00232-1.
- Y.J. Chan, M.F. Chong, C.L. Law and D. Hassell, Chem. Eng. J., 155, 1 (2009); doi:10.1016/j.cej.2009.06.041.
- R. Chandra, R.N. Bharagava, A. Kapley and H.J. Purohit, Bioresour. Technol., 102, 2333 (2011); doi:10.1016/j.biortech.2010.10.087.
- F. Fu and Q. Wang, J. Environ. Manage., 92, 407 (2011); doi:10.1016/j.jenvman.2010.11.011.
- S. Judd, Chapter 1 – Introduction; In: The MBR Book, in eds.: S. Judd and C. Judd, Butterworth–Heinemann, Oxford, edn 2, Butterworth-Heinemann Publisher, Oxford, pp. 1-54 (2011).
- N.M. Mahmoodi, B. Hayati, M. Arami and C. Lan, Desalination, 268, 117 (2011); doi:10.1016/j.desal.2010.10.007.
- M. Muneer, I.A. Bhatti, M. Iqbal and M. Akhter, J. Chem. Soc. Pak., 34, 787 (2012).
- N. Schwarzenbeck, J. Borges and P. Wilderer, Appl. Microbiol. Biotechnol., 66, 711 (2005); doi:10.1007/s00253-004-1748-6.
- G. Thompson, J. Swain, M. Kay and C.F. Forster, Bioresour. Technol., 77, 275 (2001); doi:10.1016/S0960-8524(00)00060-2.
- C. Comninellis, A. Kapalka, S. Malato, S.A. Parsons, I. Poulios and D. Mantzavinos, J. Chem. Technol. Biotechnol., 83, 769 (2008); doi:10.1002/jctb.1873.
- T.H. Bokhari, M. Kashif, I.A. Bhati, M. Zubair, A. Shahid, M. Yousf, M. Ahmad, M. Iqbal, M. Usman, M. Zubar and A. Mansha, Asian J. Chem., 25, 8668 (2013); doi:10.14233/ajchem.2013.14996.
- V. Belgiorno, V. Naddeo and L. Rizzo, DegliStudi di Salerno, 1, 272 (2011).
- S. Esplugas, J. Giménez, S. Contreras, E. Pascual and M. Rodríguez, Water Res., 36, 1034 (2002); doi:10.1016/S0043-1354(01)00301-3.
- A.A. Basfar, H.M. Khan, A.A. Al-Shahrani and W.J. Cooper, Water Res., 39, 2085 (2005); doi:10.1016/j.watres.2005.02.019.
- W.J. Cooper, M.G. Nickelsen, S.P. Mezyk, G. Leslie, P.M. Tornatore, W. Hardison and P.A. Hajali, Radiat. Phys. Chem., 65, 451 (2002); doi:10.1016/S0969-806X(02)00344-4.
- P. Shukla, I. Fatimah, S. Wang, H.M. Ang and M.O. Tadé, Catal. Today, 157, 410 (2010); doi:10.1016/j.cattod.2010.04.015.
- J. Xue and J. Wang, J. Environ. Sci. (China), 20, 1153 (2008); doi:10.1016/S1001-0742(08)62203-2.
- N. Getoff, Radiat. Phys. Chem., 65, 437 (2002); doi:10.1016/S0969-806X(02)00342-0.
- B. Han, J. Ko, J. Kim, Y. Kim, W. Chung, I. Makarov, A. Ponomarev and A. Pikaev, Radiat. Phys. Chem., 64, 53 (2002); doi:10.1016/S0969-806X(01)00452-2.
- H.S. Shin, Y.R. Kim, B.S. Han, I.E. Makarov, A.V. Ponomarev and A.K. Pikaev, Radiat. Phys. Chem., 65, 539 (2002); doi:10.1016/S0969-806X(02)00348-1.
- V. Naddeo, S. Meriç, D. Kassinos, V. Belgiorno and M. Guida, Water Res., 43, 4019 (2009); doi:10.1016/j.watres.2009.05.027.
- V. Belgiorno, V. Naddeo and L. Rizzo, Dipartimento di Ingegneria Civile Universita' DegliStudi di Salerno, 1 (2011).
- V. Naddeo, L. Rizzo and V. Belgiorno, edn. 1.2 Lulu. Com (2011).
- S. Gomes de Moraes, R. Sanches Freire and N. Durán, Chemosphere, 40, 369 (2000); doi:10.1016/S0045-6535(99)00239-8.
References
J. Bianchi, E.L.G. Espindola and M.A. Marin-Morales, Ecotoxicol. Environ. Saf., 74, 826 (2011); doi:10.1016/j.ecoenv.2010.11.006.
D.T. Sponza, Ecotoxicol. Environ. Saf., 54, 74 (2003); doi:10.1016/S0147-6513(02)00024-6.
S. Tabrez, S. Shakil, M. Urooj, G.A. Damanhouri, A.M. Abuzenadah and M. Ahmad, J. Environ. Sci. Health, 29, 250 (2011); doi:10.1080/10590501.2011.601849.
C.K. Grisolia, M.R. Bilich and L.M. Formigli, Ecotoxicol. Environ. Saf., 59, 123 (2004); doi:10.1016/j.ecoenv.2004.01.014.
M.M. Hoshina and M.A. Marin-Morales, Ecotoxicol. Environ. Saf., 72, 2090 (2009); doi:10.1016/j.ecoenv.2009.07.002.
D.M. Leme and M.A. Marin-Morales, Mutat. Res. Rev. Mutat. Res., 682, 71 (2009); doi:10.1016/j.mrrev.2009.06.002.
D.M. Leme and M.A. Marin-Morales, Mutat. Res. Genet. Toxicol. Environ. Mutagen., 650, 80 (2008); doi:10.1016/j.mrgentox.2007.10.006.
J. Margot, C. Kienle, A.S. Magnet, M. Weil, L. Rossi, L.F. de Alencastro, C. Abegglen, D. Thonney, N. Chèvre, M. Schärer and D.A. Barry, Sci. Total Environ., 461-462, 480 (2013); doi:10.1016/j.scitotenv.2013.05.034.
F.P. Rodrigues, J.P.F. Angeli, M.S. Mantovani, C.L.B. Guedes and B.Q. Jordao, Genet. Mol. Biol., 33, 169 (2010); doi:10.1590/S1415-47572010005000006.
J. Bai, H. Xu, Y. Zhang, Z. Peng and G. Xu, Biochem. Eng. J., 70, 115 (2013); doi:10.1016/j.bej.2012.10.009.
B. Malmqvist and S. Rundle, Environ. Conserv., 29, 134 (2002); doi:10.1017/S0376892902000097.
I. Oller, S. Malato and J.A. Sánchez-Pérez, Sci. Total Environ., 409, 4141 (2011); doi:10.1016/j.scitotenv.2010.08.061.
T. Meyer and F. Wania, Atmos. Environ., 41, 2757 (2007); doi:10.1016/j.atmosenv.2006.11.053.
K. Prevedouros, I.T. Cousins, R.C. Buck and S.H. Korzeniowski, Environ. Sci. Technol., 40, 32 (2006); doi:10.1021/es0512475.
M. Auriol, Y. Filali-Meknassi, R.D. Tyagi, C.D. Adams and R.Y. Surampalli, Process Biochem., 41, 525 (2006); doi:10.1016/j.procbio.2005.09.017.
N.N. Rao, K.M. Somasekhar, S.N. Kaul and L. Szpyrkowicz, J. Chem. Technol. Biotechnol., 76, 1124 (2001); doi:10.1002/jctb.493.
M. Molinos-Senante, F. Hernández-Sancho and R. Sala-Garrido, J. Environ. Manage., 92, 3091 (2011); doi:10.1016/j.jenvman.2011.07.023.
V.K. Singh and J. Singh, J. Environ. Biol., 27, 385 (2006).
M. Wong, Chemosphere, 50, 775 (2003); doi:10.1016/S0045-6535(02)00232-1.
Y.J. Chan, M.F. Chong, C.L. Law and D. Hassell, Chem. Eng. J., 155, 1 (2009); doi:10.1016/j.cej.2009.06.041.
R. Chandra, R.N. Bharagava, A. Kapley and H.J. Purohit, Bioresour. Technol., 102, 2333 (2011); doi:10.1016/j.biortech.2010.10.087.
F. Fu and Q. Wang, J. Environ. Manage., 92, 407 (2011); doi:10.1016/j.jenvman.2010.11.011.
S. Judd, Chapter 1 – Introduction; In: The MBR Book, in eds.: S. Judd and C. Judd, Butterworth–Heinemann, Oxford, edn 2, Butterworth-Heinemann Publisher, Oxford, pp. 1-54 (2011).
N.M. Mahmoodi, B. Hayati, M. Arami and C. Lan, Desalination, 268, 117 (2011); doi:10.1016/j.desal.2010.10.007.
M. Muneer, I.A. Bhatti, M. Iqbal and M. Akhter, J. Chem. Soc. Pak., 34, 787 (2012).
N. Schwarzenbeck, J. Borges and P. Wilderer, Appl. Microbiol. Biotechnol., 66, 711 (2005); doi:10.1007/s00253-004-1748-6.
G. Thompson, J. Swain, M. Kay and C.F. Forster, Bioresour. Technol., 77, 275 (2001); doi:10.1016/S0960-8524(00)00060-2.
C. Comninellis, A. Kapalka, S. Malato, S.A. Parsons, I. Poulios and D. Mantzavinos, J. Chem. Technol. Biotechnol., 83, 769 (2008); doi:10.1002/jctb.1873.
T.H. Bokhari, M. Kashif, I.A. Bhati, M. Zubair, A. Shahid, M. Yousf, M. Ahmad, M. Iqbal, M. Usman, M. Zubar and A. Mansha, Asian J. Chem., 25, 8668 (2013); doi:10.14233/ajchem.2013.14996.
V. Belgiorno, V. Naddeo and L. Rizzo, DegliStudi di Salerno, 1, 272 (2011).
S. Esplugas, J. Giménez, S. Contreras, E. Pascual and M. Rodríguez, Water Res., 36, 1034 (2002); doi:10.1016/S0043-1354(01)00301-3.
A.A. Basfar, H.M. Khan, A.A. Al-Shahrani and W.J. Cooper, Water Res., 39, 2085 (2005); doi:10.1016/j.watres.2005.02.019.
W.J. Cooper, M.G. Nickelsen, S.P. Mezyk, G. Leslie, P.M. Tornatore, W. Hardison and P.A. Hajali, Radiat. Phys. Chem., 65, 451 (2002); doi:10.1016/S0969-806X(02)00344-4.
P. Shukla, I. Fatimah, S. Wang, H.M. Ang and M.O. Tadé, Catal. Today, 157, 410 (2010); doi:10.1016/j.cattod.2010.04.015.
J. Xue and J. Wang, J. Environ. Sci. (China), 20, 1153 (2008); doi:10.1016/S1001-0742(08)62203-2.
N. Getoff, Radiat. Phys. Chem., 65, 437 (2002); doi:10.1016/S0969-806X(02)00342-0.
B. Han, J. Ko, J. Kim, Y. Kim, W. Chung, I. Makarov, A. Ponomarev and A. Pikaev, Radiat. Phys. Chem., 64, 53 (2002); doi:10.1016/S0969-806X(01)00452-2.
H.S. Shin, Y.R. Kim, B.S. Han, I.E. Makarov, A.V. Ponomarev and A.K. Pikaev, Radiat. Phys. Chem., 65, 539 (2002); doi:10.1016/S0969-806X(02)00348-1.
V. Naddeo, S. Meriç, D. Kassinos, V. Belgiorno and M. Guida, Water Res., 43, 4019 (2009); doi:10.1016/j.watres.2009.05.027.
V. Belgiorno, V. Naddeo and L. Rizzo, Dipartimento di Ingegneria Civile Universita' DegliStudi di Salerno, 1 (2011).
V. Naddeo, L. Rizzo and V. Belgiorno, edn. 1.2 Lulu. Com (2011).
S. Gomes de Moraes, R. Sanches Freire and N. Durán, Chemosphere, 40, 369 (2000); doi:10.1016/S0045-6535(99)00239-8.