Thermal Decomposition of Nickel(II) and Copper(II) Hexaaza Macrotricyclic Complexes

Subramaniam Sujatha; Sengottuvelan Balasubramanian; Chellaiah Arunkumar

doi:10.14233/ajchem.2015.17194

Issue

Vol. 27 No. 1 (2015): Vol 27 Issue 1

Issue Published : December 27, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Thermal Decomposition of Nickel(II) and Copper(II) Hexaaza Macrotricyclic Complexes

https://doi.org/10.14233/ajchem.2015.17194

Subramaniam Sujatha

Department of Chemistry, National Institute of Technology, Calicut-673 601, India; Department of Inorganic Chemistry, University of Madras, Chennai-600 025, India

Sengottuvelan Balasubramanian

Department of Inorganic Chemistry, University of Madras, Chennai-600 025, India

Chellaiah Arunkumar

Department of Chemistry, National Institute of Technology, Calicut-673 601, India

Corresponding Author(s) : Subramaniam Sujatha

sujatha@nitc.ac.in

Asian Journal of Chemistry, Vol. 27 No. 1 (2015): Vol 27 Issue 1
Article Published : December 29, 2014

Abstract

The thermal behaviour of nickel(II) and copper(II) hexaaza macrotricyclic complexes was investigated from ambient temperature to 1200 ºC under nitrogen atmosphere. The complexes demonstrated good thermal stability and are of greatly determined by the nature of ligand molecule and the counter anion present in the macrocyclic complexes. A possible mechanism of the thermal decomposition of the various complexes is also suggested.

Keywords

Hexaaza macrocycle Metal complexes Thermal analysis

Sujatha, S., Balasubramanian, S., & Arunkumar, C. (2014). Thermal Decomposition of Nickel(II) and Copper(II) Hexaaza Macrotricyclic Complexes. Asian Journal of Chemistry, 27(1), 270–272. https://doi.org/10.14233/ajchem.2015.17194

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References

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L.F. Linday, The Chemistry of Macrocyclic Ligand Complexes, Cambridge University Press, UK (1989).
P. Dietrich, P. Viout and J.M. Lehn, Macrocyclic Chemistry, VCH Publishers Inc., New York (1993).
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S. Sujatha, S. Balasubramanian and B. Varghese, Polyhedron, 28, 3723 (2009); doi:10.1016/j.poly.2009.08.012.
S. Sujatha, S. Balasubramanian, B. Varghese, M. Jayaprakashvel and N. Mathivanan, Inorg. Chim. Acta, 386, 109 (2012); doi:10.1016/j.ica.2012.02.011.
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C. Pariya, A. Ghosh and N.R. Chaudhuri, Thermochim. Acta, 273, 185 (1996); doi:10.1016/0040-6031(95)02664-9.
A.M. Donia, Thermochim. Acta, 320, 187 (1998); doi:10.1016/S0040-6031(98)00472-9.
S. Ilhan, H. Temel, I. Yilmaz and M. Sekerci, J. Organomet. Chem., 692, 3855 (2007); doi:10.1016/j.jorganchem.2007.05.031.
S.P. Sovilj, K. Babić-Samardzija and D.M. Minić, Thermochim. Acta, 370, 29 (2001); doi:10.1016/S0040-6031(00)00773-5.
W.J. Geary, Coord. Chem. Rev., 7, 81 (1971); doi:10.1016/S0010-8545(00)80009-0.
T.D. George and W.W. Wendlandt, J. Inorg. Nucl. Chem., 25, 395 (1963); doi:10.1016/0022-1902(63)80190-6.
L.S. Prabhumirashi and J.K. Khoje, Thermochim. Acta, 383, 109 (2002); doi:10.1016/S0040-6031(01)00683-9.
G. Singh, S. Prem Felix and D.K. Pandey, Thermochim. Acta, 411, 61 (2004); doi:10.1016/j.tca.2003.07.011.
M.P. Suh, S.G. Kang, V.L. Goedken and S.H. Park, Inorg. Chem., 30, 365 (1991); doi:10.1021/ic00003a004.
M.R.R. Prasad and V.N. Krishnamurthy, Thermochim. Acta, 185, 1 (1991); doi:10.1016/0040-6031(91)80112-V.

References

D.H. Busch, Acc. Chem. Res., 11, 392 (1978); doi:10.1021/ar50130a005.

L.F. Linday, The Chemistry of Macrocyclic Ligand Complexes, Cambridge University Press, UK (1989).

P. Dietrich, P. Viout and J.M. Lehn, Macrocyclic Chemistry, VCH Publishers Inc., New York (1993).

S. Sujatha, S. Balasubramanian, H.K. Fun and K. Chinnakali, Polyhedron, 27, 1925 (2008); doi:10.1016/j.poly.2008.02.034.

S. Sujatha, S. Balasubramanian and B. Varghese, Polyhedron, 28, 3723 (2009); doi:10.1016/j.poly.2009.08.012.

S. Sujatha, S. Balasubramanian, B. Varghese, M. Jayaprakashvel and N. Mathivanan, Inorg. Chim. Acta, 386, 109 (2012); doi:10.1016/j.ica.2012.02.011.

S.Z. Bootwala, Asian J. Chem., 24, 3849 (2012).

E.M. Abdalla and A.A. Said, Thermochim. Acta, 405, 269 (2003); doi:10.1016/S0040-6031(03)00200-4.

H. Icbudak, V.T. Yilmaz and H. Olmez, Thermochim. Acta, 289, 23 (1996); doi:10.1016/S0040-6031(96)03041-9.

C. Pariya, A. Ghosh and N.R. Chaudhuri, Thermochim. Acta, 273, 185 (1996); doi:10.1016/0040-6031(95)02664-9.

A.M. Donia, Thermochim. Acta, 320, 187 (1998); doi:10.1016/S0040-6031(98)00472-9.

S. Ilhan, H. Temel, I. Yilmaz and M. Sekerci, J. Organomet. Chem., 692, 3855 (2007); doi:10.1016/j.jorganchem.2007.05.031.

S.P. Sovilj, K. Babić-Samardzija and D.M. Minić, Thermochim. Acta, 370, 29 (2001); doi:10.1016/S0040-6031(00)00773-5.

W.J. Geary, Coord. Chem. Rev., 7, 81 (1971); doi:10.1016/S0010-8545(00)80009-0.

T.D. George and W.W. Wendlandt, J. Inorg. Nucl. Chem., 25, 395 (1963); doi:10.1016/0022-1902(63)80190-6.

L.S. Prabhumirashi and J.K. Khoje, Thermochim. Acta, 383, 109 (2002); doi:10.1016/S0040-6031(01)00683-9.

G. Singh, S. Prem Felix and D.K. Pandey, Thermochim. Acta, 411, 61 (2004); doi:10.1016/j.tca.2003.07.011.

M.P. Suh, S.G. Kang, V.L. Goedken and S.H. Park, Inorg. Chem., 30, 365 (1991); doi:10.1021/ic00003a004.

M.R.R. Prasad and V.N. Krishnamurthy, Thermochim. Acta, 185, 1 (1991); doi:10.1016/0040-6031(91)80112-V.

Issue

Vol. 27 No. 1 (2015): Vol 27 Issue 1

Thermal Decomposition of Nickel(II) and Copper(II) Hexaaza Macrotricyclic Complexes

Corresponding Author(s) : Subramaniam Sujatha

Abstract

Keywords

Full Article

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References

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