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Influences of pH and NaCl on Metanil Yellow Decolouration by Adsorption and Photocatalytic Decolouration
Corresponding Author(s) : Wenjie Zhang
Asian Journal of Chemistry,
Vol. 27 No. 1 (2015): Vol 27 Issue 1
Abstract
A combination of adsorption and photocatalytic decolouration was explored in decolouration of metanil yellow. The effects of pH and NaCl were studied for both processes. Adsorption of metanil yellow on the activated carbon decreases with increasing pH. Photocatalytic activity is also influenced by the variation of pH and the maximum photocatalytic decolouration efficiency appears at pH of 3. For the result of combination of adsorption and photocatalytic decolouration, a minimum decolouration rate is obtained at pH of 7. The decolouration rate increases obviously with decreasing pH of the solution. The addition of NaCl to the solution of metanil yellow can obviously enhance both adsorption efficiency of the dye on activated carbon and photocatalytic decolouration efficiency on TiO2. The overall decolouration efficiency does not change much with the variation of NaCl concentration.
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- A. Fujishima, T.N. Rao and D.A. Tryk, J. Photochem. Photobiol. Chem., 1, 1 (2000); doi:10.1016/S1389-5567(00)00002-2.
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References
S.A. Dastgheib, T. Karanfil and W. Cheng, Carbon, 42, 547 (2004); doi:10.1016/j.carbon.2003.12.062.
W. Buchanan, F. Roddick and N. Porter, Water Res., 42, 3335 (2008); doi:10.1016/j.watres.2008.04.014.
S.W. Krasner, P. Westerhoff, B.Y. Chen, B.E. Rittmann and G. Amy, Environ. Sci. Technol., 43, 8320 (2009); doi:10.1021/es901611m.
C. Musikavong, S. Wattanachira, T.F. Marhaba and P. Pavasant, J. Hazard. Mater., 127, 48 (2005); doi:10.1016/j.jhazmat.2005.06.042.
E.M. Thurman, Organic Geochemistry of Natural Waters, In: Distributors for the U.S. and Canada, M. Nijhoff/Kluwer Academic, Dordrecht/Boston, Hingham, MA, USA (1985).
M.H.B. Hayes and C.E. Clapp, Soil Sci., 166, 723 (2001); doi:10.1097/00010694-200111000-00002.
J.A. Leenheer and J.P. Croue, Environ. Sci. Technol., 37, 18A (2003); doi:10.1021/es032333c.
M.R. Hoffmann, S.T. Martin, W. Choi and W. Bahnemann, Chem. Rev., 95, 69 (1995); doi:10.1021/cr00033a004.
A. Fujishima, T.N. Rao and D.A. Tryk, J. Photochem. Photobiol. Chem., 1, 1 (2000); doi:10.1016/S1389-5567(00)00002-2.
D.H. Quiñones, A. Rey, P.M. Álvarez, F.J. Beltrán and P.K. Plucinski, Appl. Catal. B, 144, 96 (2014); doi:10.1016/j.apcatb.2013.07.005.
B.F. Gao, P.S. Yap, T.M. Lim and T.T. Lim, Chem. Eng. J., 171, 1098 (2011); doi:10.1016/j.cej.2011.05.006.
H. Slimen, A. Houas and J.P. Nogier, J. Photochem. Photobiol. A, 221, 13 (2011); doi:10.1016/j.jphotochem.2011.04.013.
X.J. Wang, Y.F. Liu, Z.H. Hu, Y.J. Chen, W. Liu and G.H. Zhao, J. Hazard. Mater., 169, 1061 (2009); doi:10.1016/j.jhazmat.2009.04.058.