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Vol. 27 No. 1 (2015): Vol 27 Issue 1

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Hydrothermal Synthesis and Crystal Structure of Non-Metallated Porphyrin

https://doi.org/10.14233/ajchem.2015.16821
Wen-Tong Chen
Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an 343009, Jiangxi Province, P.R. China; State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou 350002, Fujian Province, P.R. China
Rong-Hua Hu
Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an 343009, Jiangxi Province, P.R. China
Zhi-Gang Luo
Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an 343009, Jiangxi Province, P.R. China
Hua-Long Chen
Institute of Applied Chemistry, School of Chemistry and Chemical Engineering, Jiangxi Province Key Laboratory of Coordination Chemistry, Jinggangshan University, Ji'an 343009, Jiangxi Province, P.R. China

Corresponding Author(s) : Wen-Tong Chen

wtchen_2000@aliyun.com

Asian Journal of Chemistry, Vol. 27 No. 1 (2015): Vol 27 Issue 1

Abstract

A non-metallated porphyrin TCPP·4H2O (1) [TCPP = meso-tetra(4-carboxyphenyl)porphyrin] has been obtained from a solvothermal reaction and structurally characterized by single-crystal X-ray diffraction. The porphyrin is characteristic of an isolated structure and a saddle-distorted non-planar porphyrin macrocycle. The TCPP molecules and lattice water molecules interconnect together through abundant hydrogen bonding interactions to form a three-dimensional supramolecular network.

Keywords

Solvothermal reaction Crystal structure Porphyrin meso-Tetra(4-carboxyphenyl)porphyrin
Chen, W.-T., Hu, R.-H., Luo, Z.-G., & Chen, H.-L. (2014). Hydrothermal Synthesis and Crystal Structure of Non-Metallated Porphyrin. Asian Journal of Chemistry, 27(1), 158–160. https://doi.org/10.14233/ajchem.2015.16821
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