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Vol. 27 No. 1 (2015): Vol 27 Issue 1

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Efficient Photooxygenation of Furans using Oxygen with Wool-Immobilizing Rose Bengal as Green Photosensitizer

https://doi.org/10.14233/ajchem.2015.16745
Yan Zhang
School of Materials Science and Engineering, Beijing Institute of Fashion Technology, No. A2, East Yinghua Street, Chaoyang District, Beijing 100029, P.R. China
Wei Wang
School of Materials Science and Engineering, Beijing Institute of Fashion Technology, No. A2, East Yinghua Street, Chaoyang District, Beijing 100029, P.R. China
Shushu Li
School of Materials Science and Engineering, Beijing Institute of Fashion Technology, No. A2, East Yinghua Street, Chaoyang District, Beijing 100029, P.R. China

Corresponding Author(s) : Yan Zhang

clyzhy@bift.edu.cn

Asian Journal of Chemistry, Vol. 27 No. 1 (2015): Vol 27 Issue 1

Abstract

A new type of solid-supported photosensitizer was prepared from Rose Bengal and wool via acid dye dyeing process. The wool-Rose-bengal photosensitizer was characterized by Fourier transform infrared spectrometer (FTIR), scanning electron microscope and fastness test. This sensitizer was used as heterogeneous photocatalyst to promote furans oxidation to the corresponding butenolides in excellent yields (90 %). The sensitizer could be easily recovered from the reaction mixture by filtration and reused in the new cycle of the reaction.

Keywords

Wool Rose bengal Sensitizer Photooxidation Furans Singlet oxygen
Zhang, Y., Wang, W., & Li, S. (2014). Efficient Photooxygenation of Furans using Oxygen with Wool-Immobilizing Rose Bengal as Green Photosensitizer. Asian Journal of Chemistry, 27(1), 111–116. https://doi.org/10.14233/ajchem.2015.16745
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