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Aligned Arrays of Fe3+ Ions Decorated TiO2 Nanotubes for Photocatalytic Application under Sunlight Irradiation
Corresponding Author(s) : Weiming Wu
Asian Journal of Chemistry,
Vol. 27 No. 1 (2015): Vol 27 Issue 1
Abstract
Titanium dioxide nanotubes arrays were successfully synthesized by an anodizing route, which were designed as a photocatalyst. Through adsorbing Fe3+ ions on the surface of the TiO2 nanotubes, their photocatalytic activity can be effectively improved. The photodegradation experiments show that, under presence of H2O2, the methylene blue pollutant (1 × 10-6 M) was almost completely decomposed by as-fabricated Fe3+ ions doped TiO2 nanotubes arrays under irradiation of sunlight for 0.5 h. Comparing with the pure TiO2 nanotubes arrays photocatalysts, the photocatalytic activity of the Fe3+ ions doped TiO2 nanotubes arrays is obviously higher.
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- M.R. Hoffmann, S.T. Martin, W.Y. Choi and D.W. Bahnemann, Chem. Rev., 95, 69 (1995); doi:10.1021/cr00033a004.
- L.X. Cao, A.M. Huang, F.J. Spiess and S.L. Suib, J. Catal., 188, 48 (1999); doi:10.1006/jcat.1999.2596.
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- I. Tsuji, H. Kato, H. Kobayashi and A. Kudo, J. Am. Chem. Soc., 126, 13406 (2004); doi:10.1021/ja048296m.
- X. Wang, S. Meng, X. Zhang, H. Wang, W. Zhong and Q. Du, Chem. Phys. Lett., 444, 292 (2007); doi:10.1016/j.cplett.2007.07.026.
- Y. Li, D.-S. Hwang, N.H. Lee and D.-J. Kim, Chem. Phys. Lett., 404, 25 (2005); doi:10.1016/j.cplett.2005.01.062.
- D.W. Hess, J. Electrochem. Soc., 124, 735 (1977); doi:10.1149/1.2133396.
- W. Choi, A. Termin and M.R. Hoffmann, J. Phys. Chem., 98, 13669 (1994); doi:10.1021/j100102a038.
- M. Anpo, Catal. Surv. Jpn., 1, 169 (1997); doi:10.1023/A:1019024913274.
- R. Breckenridge and W. Hosler, Phys. Rev., 91, 793 (1953); doi:10.1103/PhysRev.91.793.
- D.C. Cronemeyer and W.R. Hosler, Phys. Rev., 113, 1222 (1959); doi:10.1103/PhysRev.113.1222.
- S.P. Albu, A. Ghicov, J.M. Macak, R. Hahn and P. Schmuki, Nano Lett., 7, 1286 (2007); doi:10.1021/nl070264k.
- J.M. Macak, H. Tsuchiya, L. Taveira, S. Aldabergerova and P. Schmuki, Angew. Chem. Int. Ed., 44, 7463 (2005); doi:10.1002/anie.200502781.
- T. Ohsaka, F. Izumi and Y.J. Fujiki, Raman Spectrosc., 7, 321 (1978); doi:10.1002/jrs.1250070606.
- S. Jain, G. Dangi, J. Vardia and S.C. Ameta, Int. J. Energy Res., 23, 71 (1999); doi:10.1002/(SICI)1099-114X(199901)23:1<71::AID-ER464>3.0.CO;2-G.
References
M.R. Hoffmann, S.T. Martin, W.Y. Choi and D.W. Bahnemann, Chem. Rev., 95, 69 (1995); doi:10.1021/cr00033a004.
L.X. Cao, A.M. Huang, F.J. Spiess and S.L. Suib, J. Catal., 188, 48 (1999); doi:10.1006/jcat.1999.2596.
S. Sato, T. Kadowaki and K. Yamaguti, J. Phys. Chem., 88, 2930 (1984); doi:10.1021/j150658a002.
S. Sakthivel and H. Kisch, Angew. Chem. Int. Ed., 42, 4908 (2003); doi:10.1002/anie.200351577.
I. Tsuji, H. Kato, H. Kobayashi and A. Kudo, J. Am. Chem. Soc., 126, 13406 (2004); doi:10.1021/ja048296m.
X. Wang, S. Meng, X. Zhang, H. Wang, W. Zhong and Q. Du, Chem. Phys. Lett., 444, 292 (2007); doi:10.1016/j.cplett.2007.07.026.
Y. Li, D.-S. Hwang, N.H. Lee and D.-J. Kim, Chem. Phys. Lett., 404, 25 (2005); doi:10.1016/j.cplett.2005.01.062.
D.W. Hess, J. Electrochem. Soc., 124, 735 (1977); doi:10.1149/1.2133396.
W. Choi, A. Termin and M.R. Hoffmann, J. Phys. Chem., 98, 13669 (1994); doi:10.1021/j100102a038.
M. Anpo, Catal. Surv. Jpn., 1, 169 (1997); doi:10.1023/A:1019024913274.
R. Breckenridge and W. Hosler, Phys. Rev., 91, 793 (1953); doi:10.1103/PhysRev.91.793.
D.C. Cronemeyer and W.R. Hosler, Phys. Rev., 113, 1222 (1959); doi:10.1103/PhysRev.113.1222.
S.P. Albu, A. Ghicov, J.M. Macak, R. Hahn and P. Schmuki, Nano Lett., 7, 1286 (2007); doi:10.1021/nl070264k.
J.M. Macak, H. Tsuchiya, L. Taveira, S. Aldabergerova and P. Schmuki, Angew. Chem. Int. Ed., 44, 7463 (2005); doi:10.1002/anie.200502781.
T. Ohsaka, F. Izumi and Y.J. Fujiki, Raman Spectrosc., 7, 321 (1978); doi:10.1002/jrs.1250070606.
S. Jain, G. Dangi, J. Vardia and S.C. Ameta, Int. J. Energy Res., 23, 71 (1999); doi:10.1002/(SICI)1099-114X(199901)23:1<71::AID-ER464>3.0.CO;2-G.