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Synthesis, Spectral and Thermal Studies of Mixed Ligand Complexes of Rh3+ with Nucleobase and Amino Acid
Corresponding Author(s) : R. Ilavarasi
Asian Journal of Chemistry,
Vol. 27 No. 12 (2015): Vol 27 Issue 12
Abstract
Mixed ligand complexes of rhodium with nucleobases and amino acid have been synthesized. The complexes have been characterized on the basis of analytical data, thermogravimetric studies, IR, NMR, electronic and XPS studies. The magnetic measurements suggest that all the complexes are diamagnetic as expected for octahedral rhodium(III) complexes. From the infrared spectral studies, it is inferred that in adenine derivatives (ade, amp and C6H5CH2-ade) N7 atoms is involved in coordination and in guanine derivatives (Cl-gua and S-gua) both N1 and N7 atom are involved in coordination. The studies suggest that adenine derivatives (amp, C6H5 CH2-ade) gave mononuclear complexes and guanine derivatives (Cl-gua, S-gua) lead to binuclear complexes.
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- R.F. Carbonaro, Y.B. Atalay and D.M. Di Toro, Geochim. Cosmochim. Acta, 75, 2499 (2011); doi:10.1016/j.gca.2011.02.027.
- N. Farrell, J. Chem. Soc. Chem. Commun., 21, 1014 (1980); doi:10.1039/c39800001014.
- I. Sinha, J. Kosters, A. Hepp and J. Muller, Dalton Trans., 42, 16080 (2013); doi:10.1039/c3dt51691a.
- T.A. Ryan, Coord. Chem. Rev., 41, 251 (1982); doi:10.1016/S0010-8545(00)80532-9.
- F.P. Pruchnik, P. Jakimowicz, Z. Ciunik, J. Zakrzewska-Czerwinska, A. Opolski, J. Wietrzyk and E. Wojdat, Inorg. Chim. Acta, 334, 59 (2002); doi:10.1016/S0020-1693(02)00776-4.
- H. Junicke, R.J. Hart, J. Kisko, O. Glebov, R. Ilan Kirsch and K.J. Barton, Proc. Natl. Acad. Sci. USA, 100, 3737 (2003); doi:10.1073/pnas.0537194100.
- A.W. Addison, K. Dawson, R.D. Gillard, B.T. Heaton and H. Shaw, J. Chem. Soc., Dalton Trans., 589 (1972); doi:10.1039/DT9720000589.
- B.T. Khan, M.R. Somayajulu and M.M.T. Khan, J. Inorg. Nucl. Chem., 40, 1251 (1978b); doi:10.1016/0022-1902(78)80548-X.
- G. Sánchez, J. García, J. Pérez, G. García and G. López, Thermochim. Acta, 307, 127 (1997); doi:10.1016/S0040-6031(97)00315-8.
- R. Ilavarasi, L. Muthulakshmi and S. Selvanayagam, Chem. Sci. Transac., 4, 81 (2015); doi:10.7598/cst2015.929.
- K.V. Sharma, S. Srivastava and A. Srivastava, Bioinorg. Chem. Appl., Article ID 68374 (2007); doi:10.1155/2007/68374.
- K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley Interscience, New York (1986).
- I.P. Khullar and U. Agarwala, Aust. J. Chem., 28, 1529 (1975); doi:10.1071/CH9751529.
- K.V. Sharma and A. Srivastava, Indian J. Chem., 46A, 1963 (2007).
- M. Tyagi and S. Chandra, Open J. Inorg. Chem., 2, 19764 (2012); doi:10.4236/ojic.2012.23007.
- J.R. Lusty, J. Peeling and M.A. Abdel-Aal, Inorg. Chim. Acta, 56, 21 (1981); doi:10.1016/S0020-1693(00)88542-4.
- J.J. Ziarek, F.C. Peterson, B.L. Lytle and B.F. Volkman, Methods Enzymol., 493, 241 (2011); doi:10.1016/B978-0-12-381274-2.00010-8.
- Y. Ávila-Torres, L. Huerta and N. Barba-Behrens, J. Chem., Article ID 370637 (2013); doi:10.1155/2013/370637.
References
R.F. Carbonaro, Y.B. Atalay and D.M. Di Toro, Geochim. Cosmochim. Acta, 75, 2499 (2011); doi:10.1016/j.gca.2011.02.027.
N. Farrell, J. Chem. Soc. Chem. Commun., 21, 1014 (1980); doi:10.1039/c39800001014.
I. Sinha, J. Kosters, A. Hepp and J. Muller, Dalton Trans., 42, 16080 (2013); doi:10.1039/c3dt51691a.
T.A. Ryan, Coord. Chem. Rev., 41, 251 (1982); doi:10.1016/S0010-8545(00)80532-9.
F.P. Pruchnik, P. Jakimowicz, Z. Ciunik, J. Zakrzewska-Czerwinska, A. Opolski, J. Wietrzyk and E. Wojdat, Inorg. Chim. Acta, 334, 59 (2002); doi:10.1016/S0020-1693(02)00776-4.
H. Junicke, R.J. Hart, J. Kisko, O. Glebov, R. Ilan Kirsch and K.J. Barton, Proc. Natl. Acad. Sci. USA, 100, 3737 (2003); doi:10.1073/pnas.0537194100.
A.W. Addison, K. Dawson, R.D. Gillard, B.T. Heaton and H. Shaw, J. Chem. Soc., Dalton Trans., 589 (1972); doi:10.1039/DT9720000589.
B.T. Khan, M.R. Somayajulu and M.M.T. Khan, J. Inorg. Nucl. Chem., 40, 1251 (1978b); doi:10.1016/0022-1902(78)80548-X.
G. Sánchez, J. García, J. Pérez, G. García and G. López, Thermochim. Acta, 307, 127 (1997); doi:10.1016/S0040-6031(97)00315-8.
R. Ilavarasi, L. Muthulakshmi and S. Selvanayagam, Chem. Sci. Transac., 4, 81 (2015); doi:10.7598/cst2015.929.
K.V. Sharma, S. Srivastava and A. Srivastava, Bioinorg. Chem. Appl., Article ID 68374 (2007); doi:10.1155/2007/68374.
K. Nakamoto, Infrared and Raman Spectra of Inorganic and Coordination Compounds, Wiley Interscience, New York (1986).
I.P. Khullar and U. Agarwala, Aust. J. Chem., 28, 1529 (1975); doi:10.1071/CH9751529.
K.V. Sharma and A. Srivastava, Indian J. Chem., 46A, 1963 (2007).
M. Tyagi and S. Chandra, Open J. Inorg. Chem., 2, 19764 (2012); doi:10.4236/ojic.2012.23007.
J.R. Lusty, J. Peeling and M.A. Abdel-Aal, Inorg. Chim. Acta, 56, 21 (1981); doi:10.1016/S0020-1693(00)88542-4.
J.J. Ziarek, F.C. Peterson, B.L. Lytle and B.F. Volkman, Methods Enzymol., 493, 241 (2011); doi:10.1016/B978-0-12-381274-2.00010-8.
Y. Ávila-Torres, L. Huerta and N. Barba-Behrens, J. Chem., Article ID 370637 (2013); doi:10.1155/2013/370637.