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Vol. 27 No. 12 (2015): Vol 27 Issue 12

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Residue and Dissipation of Cyprodinil in Apple Using RRLC-QQQ-MS/MS Combined with QuEChERS Method

https://doi.org/10.14233/ajchem.2015.19192
X.X. Chen
Laboratory of Pesticide Residues and Environmental Toxicology, College of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, P.R. China
B.Z. Dong
Laboratory of Pesticide Residues and Environmental Toxicology, College of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, P.R. China
J.Y. Hu
Laboratory of Pesticide Residues and Environmental Toxicology, College of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing 100083, P.R. China

Corresponding Author(s) : J.Y. Hu

jyhu@ustb.edu.cn

Asian Journal of Chemistry, Vol. 27 No. 12 (2015): Vol 27 Issue 12

Abstract

A simple, quick and efficient approach for quantitative analysis of cyprodinil residues in apple and soil was established and validated with rapid resolution liquid chromatography tandem mass spectrometry (RRLC-MS/MS) combined with QuEChERS preparation method. The limits of quantification in soil and apple were 0.005 and 0.01 mg/kg. The mean recoveries (n = 5) in apple varied from 88.05 to 92.45 % with the relative standard deviation of 3.74-6.16 %. The recoveries in soil were 84.12-105.70 % with the RSDs of 3.99-8.83 %. The dissipation kinetics followed the pseudo-first-order model and the half-lives in apple ranged from 7.1 to 14.1 days and that in soil were 9.4-15.4 days. The terminal residue in apple found 28 days after application were much lower than the maximum residue limit (MRLs) by America, European, Korea and Japan. These findings will be contribution to provide scientific basis for Chinese government about establishing the MRLs of cyprodinil in apple.

Keywords

Cyprodinil Dissipation Apple QuEChERS RRLC-QQQ-MS/MS
Chen, X., Dong, B., & Hu, J. (2015). Residue and Dissipation of Cyprodinil in Apple Using RRLC-QQQ-MS/MS Combined with QuEChERS Method. Asian Journal of Chemistry, 27(12), 4485–4489. https://doi.org/10.14233/ajchem.2015.19192
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References
  1. M.S. Munitz, S.L. Resnik and M.I.T. Montti, Food Addit. Contam: Part A, 30, 1299 (2013); doi:10.1080/19440049.2013.801085.
  2. P. Cabras, A. Angioni, V.L. Garau and E.V. Meselli, J. AOAC Int., 80, 867 (1997).
  3. P. Cabras, A. Angioni, V.L. Garau, M. Melis, F.M. Pirisi, E. Minelli, F. Cabitza and M. Cubeddu, J. Agric. Food Chem., 45, 2708 (1997); doi:10.1021/jf960939x.
  4. F. Cus, H.B. Cesnik, S.V. Bolta and A. Gregorcic, Food Contr., 21, 150 (2010); doi:10.1016/j.foodcont.2009.04.010.
  5. C. Blasco, Y. Picó and V. Andreu, Electrophoresis, 30, 1698 (2009); doi:10.1002/elps.200800696.
  6. S.J. Lehotay, K.A. Son, H. Kwon, U. Koesukwiwat, W. Fu, K. Mastovska, E. Hoh and N. Leepipatpiboon, J. Chromatogr. A, 1217, 2548 (2010); doi:10.1016/j.chroma.2010.01.044.
  7. A. Belmonte Vega, A. Garrido Frenich and J.L. Martínez Vidal, Anal. Chim. Acta, 538, 117 (2005); doi:10.1016/j.aca.2005.02.003.
  8. F. Hernández, O.J. Pozo, J.V. Sancho, L. Bijlsma, M. Barreda and E. Pitarch, J. Chromatogr. A, 1109, 242 (2006); doi:10.1016/j.chroma.2006.01.032.
  9. G. Knauf-Beiter, H. Dahmen, U. Heye and T. Staub, Plant Dis., 79, 1098 (1995); doi:10.1094/PD-79-1098.
  10. M. Navarro, Y. Picó, R. Marín and J. Mañes, J. Chromatogr. A, 968, 201 (2002); doi:10.1016/S0021-9673(02)00846-4.
  11. J. Fenoll, P. Hellín, C.M. Martínez, M. Miguel and P. Flores, Food Chem., 105, 711 (2007); doi:10.1016/j.foodchem.2006.12.060.
  12. G.C. Fernández, O.R. Rial, G.B. Cancho and G.J. Simal, J. AOAC Int., 86, 1008 (2003).
  13. X.G. Chu, X.Z. Hu and H.Y. Yao, J. Chromatogr. A, 1063, 201 (2005); doi:10.1016/j.chroma.2004.12.003.
  14. E.D. Guerrero, R. Castro Mejías, R.N. Marín and C.G. Barroso, J. Chromatogr. A, 1165, 144 (2007); doi:10.1016/j.chroma.2007.07.058.
  15. R.M. González-Rodríguez, R. Rial-Otero, B. Cancho-Grande and J. Simal-Gándara, J. Chromatogr. A, 1196-1197, 100 (2008); doi:10.1016/j.chroma.2008.02.087.
  16. R.M. González-Rodríguez, R. Rial-Otero, B. Cancho-Grande and J. Simal-Gándara, Food Chem., 107, 1342 (2008); doi:10.1016/j.foodchem.2007.09.045.
  17. S. Walorczyk, J. Chromatogr. A, 1208, 202 (2008); doi:10.1016/j.chroma.2008.08.068.
  18. S. Walorczyk, Rapid Commun. Mass Spectrom., 22, 3791 (2008); doi:10.1002/rcm.3800.
  19. S. Walorczyk and B. Gnusowski, J. Chromatogr. A, 1216, 6522 (2009); doi:10.1016/j.chroma.2009.07.045.
  20. E.G. Amvrazi and N.G. Tsiropoulos, J. Chromatogr. A, 1216, 7630 (2009); doi:10.1016/j.chroma.2009.08.092.
  21. R.R. Otero, C.Y. Ruiz, B.C. Grande and J.S. Gándara, J. Chromatogr. A, 942, 41 (2002); doi:10.1016/S0021-9673(01)01352-8.
  22. L. Alder, S. Lüderitz, K. Lindtner and H.-J. Stan, J. Chromatogr. A, 1058, 67 (2004); doi:10.1016/j.chroma.2004.08.120.
  23. A. Garrido-Frenich, J.L. Martínez Vidal, T.L. López, S.C. Aguado and I.M. Salvador, J. Chromatogr. A, 1048, 199 (2004); doi:10.1016/j.chroma.2004.07.027.
  24. A. Economou, H. Botitsi, S. Antoniou and D. Tsipi, J. Chromatogr. A, 1216, 5856 (2009); doi:10.1016/j.chroma.2009.06.031.
  25. A. Wilkowska and M. Biziuk, Food Chem., 125, 803 (2011); doi:10.1016/j.foodchem.2010.09.094.
  26. S.H. Abd-Alrahman, Food Chem., 159, 1 (2014); doi:10.1016/j.foodchem.2014.02.124.
  27. B.Z. Dong, W. Qian and J.Y. Hu, Chemosphere, 120, 486 (2015); doi:10.1016/j.chemosphere.2014.09.016.
  28. A. Marín, J. Oliva, C. Garcia, S. Navarro and A. Barba, J. Agric. Food Chem., 51, 4708 (2003); doi:10.1021/jf021222e.
  29. V. Lavtizar, C.A.M. van Gestel, D. Dolenc and P. Trebse, Chemosphere, 95, 408 (2014); doi:10.1016/j.chemosphere.2013.09.057.
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