Synthesis, Characterization and Catalytic Activity of Oxovanadium(IV) Complexes of Heterocyclic Acid Hydrazones

Manju Pandey; K.R. Sunaja Devi; P.B. Sreeja

doi:10.14233/ajchem.2015.19115

Issue

Vol. 27 No. 11 (2015): Vol 27 Issue 11

Issue Published : July 16, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis, Characterization and Catalytic Activity of Oxovanadium(IV) Complexes of Heterocyclic Acid Hydrazones

https://doi.org/10.14233/ajchem.2015.19115

Manju Pandey

Department of Chemistry, Christ University, Bangalore-560 029, India

K.R. Sunaja Devi

Department of Chemistry, Christ University, Bangalore-560 029, India

P.B. Sreeja

Department of Chemistry, Christ University, Bangalore-560 029, India

Corresponding Author(s) : P.B. Sreeja

sreeja.pb@christuniversity.in

Asian Journal of Chemistry, Vol. 27 No. 11 (2015): Vol 27 Issue 11
Article Published : July 16, 2015

Abstract

Two acid hydrazones, furan-2-carbaldehyde nicotinic hydrazone (L₁) and furan-2-carbaldehyde benzhydrazone (L₂) have been synthesized and they are characterized by elemental analysis, IR, NMR and UV spectral analysis. Oxovanadium(IV) complexes of these two hydrazones were synthesized and characterized by elemental analysis, IR, UV, EPR, molar conductivity and magnetic susceptibility measurements. Conductivity measurements reveal that the complexes are non-electrolytes. Spectral data indicates the square pyramidal geometry for the monomeric five coordinated oxovanadium(IV) complexes with the general formula [VO(L)(OCH₃)]. The complex was studied for its catalytic activity and was found to be a good catalyst in quinoxaline synthesis.

Keywords

Acid hydrazones Oxovanadium complexes EPR spectrum Square pyramidal Catalytic activity

Pandey, M., Sunaja Devi, K., & Sreeja, P. (2015). Synthesis, Characterization and Catalytic Activity of Oxovanadium(IV) Complexes of Heterocyclic Acid Hydrazones. Asian Journal of Chemistry, 27(11), 4135–4137. https://doi.org/10.14233/ajchem.2015.19115

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References

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B.K. Kaymakcioglu and S. Rollas, Farmaco, 57, 595 (2002); doi:10.1016/S0014-827X(02)01255-7.

R. Maccari, R. Ottana and M.G. Vigorita, Bioorg. Med. Chem. Lett., 15, 2509 (2005); doi:10.1016/j.bmcl.2005.03.065.

M.M. Heravi, L. Ranjbar, F. Derikvand, H.A. Oskooie and F.F. Bamoharram, J. Mol. Catal. Chem., 265, 186 (2007); doi:10.1016/j.molcata.2006.10.006.

R.C. Maurya and S. Rajput, J. Mol. Struct., 833, 133 (2007); doi:10.1016/j.molstruc.2006.09.022.

U.O. Ozmen and G. Olgun, Spectrochim. Acta A, 70, 641 (2008); doi:10.1016/j.saa.2007.08.012.

F. Cariati, U. Caruso, R. Centore, W. Marcolli, A.D. Maria, B. Panunzi, A. Roviello and A. Tuzi, Inorg. Chem., 41, 6597 (2002); doi:10.1021/ic020127k.

O. Pouralimardan, A.-C. Chamayou, C. Janiak and H. Hosseini-Monfared, Inorg. Chim. Acta, 360, 1599 (2007); doi:10.1016/j.ica.2006.08.056.

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C. Basu, S. Chowdhury, R. Banerjee, H.S. Evans and S. Mukherjee, Polyhedron, 26, 3617 (2007); doi:10.1016/j.poly.2007.03.053.

M.O. Bakir, O. Green and W.H. Mulder, J. Mol. Struct., 873, 17 (2008); doi:10.1016/j.molstruc.2007.03.001.

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C.M. Armstrong, P.V. Bernhardt, P. Chin and D.R. Richardson, Eur. J. Inorg. Chem., 1145 (2003); doi:10.1002/ejic.200390146.

P.B. Sreeja, M.R.P. Kurup, A. Kishore and C. Jasmin, Polyhedron, 23, 575 (2004); doi:10.1016/j.poly.2003.11.005.

S.N. Rao, D.D. Mishra, R.C. Maurya and N.N. Rao, Polyhedron, 16, 1825 (1997); doi:10.1016/S0277-5387(96)00487-1.

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M. Carcelli, P. Cozzini, T. Maccagni, C. Pelizzi and L. Righi, Inorg. Chim. Acta, 303, 238 (2000); doi:10.1016/S0020-1693(00)00040-2.

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F.E. Dickson, C.J. Kunesh, E.L. McGinnis and L. Petrakis, Anal. Chem., 44, 978 (1972); doi:10.1021/ac60314a009.

P. Corona, A. Carta, M. Loriga, G. Vitale and G. Paglietti, Eur. J. Med. Chem., 44, 1579 (2009); doi:10.1016/j.ejmech.2008.07.025.

Q. Weng, D. Wang, P. Guo, L. Fang, Y. Hu, Q. He and B. Yang, Eur. J. Pharmacol., 581, 262 (2008); doi:10.1016/j.ejphar.2007.12.006.

S. Wagle, A.V. Adhikari and N.S. Kumari, Eur. J. Med. Chem., 44, 1135 (2009); doi:10.1016/j.ejmech.2008.06.006.

Issue

Vol. 27 No. 11 (2015): Vol 27 Issue 11

Synthesis, Characterization and Catalytic Activity of Oxovanadium(IV) Complexes of Heterocyclic Acid Hydrazones

Corresponding Author(s) : P.B. Sreeja

Abstract

Keywords

Full Article

Download Citation

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