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Vol. 27 No. 11 (2015): Vol 27 Issue 11

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Structure and Characterization of 1D Double Chain Copper(II) Complex [Cu(BTZX)2(CH3OH)2]n

https://doi.org/10.14233/ajchem.2015.19104
Zhi-Jun Yang
Department of Chemistry, School of Basic Medical Science, Xinxiang Medical University, Xinxiang 453003, Henan Province, P.R. China
Tian-Jun Ni
Department of Chemistry, School of Basic Medical Science, Xinxiang Medical University, Xinxiang 453003, Henan Province, P.R. China
Guang-Jie He
Department of Forensic Medicine, Xinxiang Medical University, Xinxiang 453003, Henan Province, P.R. China
Qian-Qian Huang
Department of Chemistry, School of Basic Medical Science, Xinxiang Medical University, Xinxiang 453003, Henan Province, P.R. China
Qiang-Tao Yuan
Department of Chemistry, School of Basic Medical Science, Xinxiang Medical University, Xinxiang 453003, Henan Province, P.R. China
Wen-Qi Zheng
College of Pharmacy, Xinxiang Medical University, Xinxiang 453003, Henan Province, P.R. China

Corresponding Author(s) : Guang-Jie He

guangjiehe@163.com

Asian Journal of Chemistry, Vol. 27 No. 11 (2015): Vol 27 Issue 11

Abstract

A novel copper(II) complex [Cu(btzx)2(CH3OH)2]n (1) [btzx = 1,3-bis(tetrazol-1-ylmethyl)benzene] has been synthesized and characterized by elemental analysis, IR and single crystal X-ray diffraction. Results show that in copper(II) complex 1, the Cu(II) atom is eight-coordinated in a elongated octahedron geometry, with four tetrazol N atoms of the ligand and two O atoms of methanol molecules. Ligands in copper(II) complex 1 adopt a trans-conformation acts as a bidentate linker using its two tetrazol groups to coordinate with two Cu atoms extending into an infinite 1D double chain structure. Possible partial p-p stacking interactions involving the tetrazol rings are observed in the crystal structure.

Keywords

1 3-Bis(tetrazol-1-ylmethyl)benzene Coordination polymers Copper complex
Yang, Z.-J., Ni, T.-J., He, G.-J., Huang, Q.-Q., Yuan, Q.-T., & Zheng, W.-Q. (2015). Structure and Characterization of 1D Double Chain Copper(II) Complex [Cu(BTZX)2(CH3OH)2]n. Asian Journal of Chemistry, 27(11), 4103–4105. https://doi.org/10.14233/ajchem.2015.19104
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References
  1. J.L.C. Rowsell and O.M. Yaghi, J. Am. Chem. Soc., 128, 1304 (2006); doi:10.1021/ja056639q.
  2. S. Kitagawa, R. Kitaura and S. Noro, Angew. Chem. Int. Ed., 43, 2334 (2004); doi:10.1002/anie.200300610.
  3. M. Clemente-Leon, E. Coronado, C. Marti-Gastaldo and F.M. Romero, Chem. Soc. Rev., 40, 473 (2011); doi:10.1039/c0cs00111b.
  4. M. Fujita, M. Tominaga, A. Hori and B. Therrien, Acc. Chem. Res., 38, 369 (2005); doi:10.1021/ar040153h.
  5. M.B. Zaman, K. Udachin, J.A. Ripmeester, M.D. Smith and H.-C. Zur Loye, Inorg. Chem., 44, 5047 (2005); doi:10.1021/ic050080d.
  6. M. Deniz, J. Pasan, J. Ferrando-Soria, O. Fabelo, L. Canadillas-Delgado, C. Yuste, M. Julve, J. Cano and C. Ruiz-Perez, Inorg. Chem., 50, 10765 (2011); doi:10.1021/ic201314k.
  7. P. Thuery, CrystEngComm, 11, 1081 (2009); doi:10.1039/b821895a.
  8. H.Y. Bai, J.F. Ma, J. Yang, L.P. Zhang, J.C. Ma and Y.Y. Liu, Cryst. Growth Des., 10, 1946 (2010); doi:10.1021/cg100032n.
  9. L. Bergmann, J. Friedrichs, M. Mydlak, T. Baumann, M. Nieger and S. Brase, Chem. Commun., 49, 6501 (2013); doi:10.1039/c3cc42280a.
  10. X.B. Li, J.Y. Zhang, Y.Q. Wang, Y. Song and E.Q. Gao, Chem. Eutr. J., 17, 13883 (2011); doi:10.1002/chem.201101477.
  11. M.X. Yang, L.J. Chen, S. Lin, X.H. Chen and H. Huang, Dalton Trans., 40, 1866 (2011); doi:10.1039/C0DT00781A.
  12. Q. Wang, K. Tang, X. Jin, X. Huang, W. Liu, X. Yao and Y. Tang, Dalton Trans., 41, 3431 (2012); doi:10.1039/c2dt11761d.
  13. X.J. Li, F.L. Jiang, M.Y. Wu, S.Q. Zhang, Y.F. Zhou and M.C. Hong, Inorg. Chem., 51, 4116 (2012); doi:10.1021/ic202373a.
  14. T.J. Ni, Y.M. Zhao, M. Shao, S.R. Zhu, F.F. Xing and M.X. Li, Z. Anorg. Allg. Chem., 637, 689 (2011); doi:10.1002/zaac.201000433.
  15. T. Ni, F. Xing, M. Shao, Y. Zhao, S. Zhu and M. Li, Cryst. Growth Des., 11, 2999 (2011); doi:10.1021/cg2002749.
  16. M. Quesada, F. Prins, E. Bill, H. Kooijman, P. Gamez, O. Roubeau, A.L. Spek, J.G. Haasnoot and J. Reedijk, Chem. Eur. J., 14, 8486 (2008); doi:10.1002/chem.200800990.
  17. G.M. Sheldrick, SHELXS97, A Program for the Solution of Crystal Structures from X-ray Data, University of Göttingen, Germany (1997).
  18. G.M. Sheldrick, SHELXL97, A Program for the Refinement of Crystal Structures from X-ray Data, University of Göttingen, Göttingen, Germany (1997).
  19. A.J. Graham, J.C. Tan, D.R. Allan and S.A. Moggach, Chem. Commun., 48, 1535 (2012); doi:10.1039/C1CC16045A.
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