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This work is licensed under a Creative Commons Attribution 4.0 International License.
Synthesis and Antibacterial Activities of Mixed Ligands Complexes of Cu(II) and Zn(II) Containing Tridentate Azo Anils Ligands and Bidentate Oxalate Ion
Corresponding Author(s) : Muhammad Ameen
Asian Journal of Chemistry,
Vol. 27 No. 11 (2015): Vol 27 Issue 11
Abstract
Mixed ligands complexes of copper(II) and zinc(II) were synthesized using azo anils ((HNPDBAB = 2-({2-hydroxy-5-[(4-nitrophenyl)diazenyl]benzylidene}amino)benzoic acid, HPIMNDP = 2-{[(2-hydroxyphen yl)imino]methyl}-4-[(4-nitrophenyl)diazenyl] phenol) and oxalate ion as a coordinating ligands. Elemental analysis, atomic absorption spectroscopy, FTIR, NMR, UV-visible. were used for the characterizations of synthesized azo anils ligands and their mixed ligands complexes. Distorted octahedral geometry was tentatively proposed for these new mixed ligands M(II) {Cu(II) and Zn(II)} complexes. Gram-positive (Bacillus subtilis and Staphylococcus aureus) and Gram-negative (Enterobacter aerogenes and Escherichia coli) were screen out for antibacterial activities of azo anils ligands, oxalic acid, metal salts and their mixed ligands M(II) complexes. The antibacterial activities were performed to assess the extent of inhibition potential of free ligand and their mixed ligands M(II) complexes. The results revealed that antibacterial activities of azo anils became more pronounced when these were coordinated to central metal atom.
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- O.B. Ibrahim, M.A. Mohamed and M.S. Refat, Can. Chem. Trans., 2, 108 (2014);
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- Z. Rezvani, L. Ahar, K. Nejati and S.M. Seyedahmadian, Acta Chim. Slov., 51, 675 (2004).
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- E. Canpolat and M. Kaya, Russ. J. Coord. Chem., 31, 790 (2005); doi:10.1007/s11173-005-0170-7.
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References
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O.B. Ibrahim, M.A. Mohamed and M.S. Refat, Can. Chem. Trans., 2, 108 (2014);
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R.A. Ahmadi and S. Amani, Molecules, 17, 6434 (2012); doi:10.3390/molecules17066434.
P. Bhattacharyya, J. Parr, A.T. Ross and A.M.Z. Slawin, Dalton Trans., 11, 3149 (1998); doi:10.1039/a806058d.
H. Nazir, N.S. Akben, M.B. Ates, H. Sözeri, I. Ercan, O. Atakol and F. Ercan, Z. Kristallogr., 221, 276 (2006); doi:10.1524/zkri.2006.221.4.276.
N.N. Das and A.C. Dash, Polyhedron, 14, 1221 (1995); doi:10.1016/0277-5387(94)00374-N.
A. Khandar and K. Nejati, Polyhedron, 19, 607 (2000); doi:10.1016/S0277-5387(99)00380-0.
A.A. Khandar, Z. Rezvani and K.I. Nejati, Acta Chim. Slov., 49, 733 (2002).
L. Nejati and Z. Rezvani, New J. Chem., 27, 1665 (2003); doi:10.1039/b305278h.
A.A. Khandar, K. Nejati and Z. Rezvani, Molecules, 10, 302 (2005); doi:10.3390/10010302.
M. Badea, R. Olar, E. Cristurean, D. Marinescu, A. Emandi, P. Budrugeac and E. Segal, J. Therm. Anal. Calorim., 77, 815 (2004); doi:10.1023/B:JTAN.0000041660.12310.c7.
Y. Geng, D. Gu and F. Gan, Opt. Mater., 27, 193 (2004); doi:10.1016/j.optmat.2004.03.006.
H. Kocaokutgen, M. Gur, M. Serkansoylu and P. Lonnecke, Dyes Pigments, 67, 99 (2005); doi:10.1016/j.dyepig.2004.09.021.
S. Ren, R. Wang, K. Komatsu, P. Bonaz-Krause, Y. Zyrianov, C.E. McKenna, C. Csipke, Z.A. Tokes and E.J. Lien, J. Med. Chem., 45, 410 (2002); doi:10.1021/jm010252q.
M.T.H. Tarafder, M.A. Ali, N. Saravanan, W.Y. Weng, S. Kumar, N. Umar-Tsafe and K.A. Crouse, Transition Met. Chem., 25, 295 (2000); doi:10.1023/A:1007044910814.
H. Nishihara, Bull. Chem. Soc. Jpn., 77, 407 (2004); doi:10.1246/bcsj.77.407.
P. Román, C. Guzmán-Miralles, A. Luque, J.I. Beitia, J. Cano, F. Lloret, M. Julve and S. Alvarez, Inorg. Chem., 35, 3741 (1996); doi:10.1021/ic951081g.
J. Glerup, P.A. Goodson, D.J. Hodgson and K. Michelsen, Inorg. Chem., 34, 6255 (1995); doi:10.1021/ic00129a009.
J. Suárez-Varela, J.M. Dominguez-Vera, E. Colacio, J.C. Avila-Rosón, M.A. Hidalgo and D. Martín-Ramos, J. Chem. Soc., Dalton Trans., 2143 (1995); doi:10.1039/DT9950002143.
J.J. Girerd, O. Kahn and M. Verdaguer, Inorg. Chem., 19, 274 (1980); doi:10.1021/ic50203a060.
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Y. Pei, Y. Journaux and O. Kahn, Inorg. Chem., 28, 100 (1989); doi:10.1021/ic00300a023.
B. Bag, N. Mondal, S. Mitra, V. Gramlich, J. Ribas and M.S. El-Fallah, Polyhedron, 20, 2113 (2001); doi:10.1016/S0277-5387(01)00707-0.
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Z. Rezvani, M.A. Ghanea, K. Nejati and S.A. Baghaei, Polyhedron, 28, 2913 (2009); doi:10.1016/j.poly.2009.06.089.
M.B. Ferrari, S. Capacchi, G. Pelosi, G. Reffo, P. Tarasconi, R. Albertini, S. Pinelli and P. Lunghi, Inorg. Chim. Acta, 286, 134 (1999); doi:10.1016/S0020-1693(98)00383-1.
Z.H. Chohan and S.K.A. Sherazi, Synth. React. Inorg. Met.-Org. Chem, 29, 105 (1999); doi:10.1080/00945719909349437.
C. Jayabalakrishnan and K. Natarajan, Synth. React. Inorg. Met.-Org. Chem., 31, 983 (2001); doi:10.1081/SIM-100105255.
T. Jeewoth, H. Li Kam Wah, M.G. Bhowon, D. Ghoorohoo and K. Babooram, Synth. React. Inorg. Met.-Org. Chem., 30, 1023 (2000); doi:10.1080/00945710009351817.
N. Dharmaraj, P. Viswanathamurthi and K. Natarajan, Transition Met. Chem., 26, 105 (2001); doi:10.1023/A:1007132408648.
C.H. Colins and P.M. Lyne, Microbial Methods, University Park Press Baltimore, p. 422 (1970).
B. Jacquelyn, Microbiology, Prentice Hall, pp. 334 (1993).
F.I. Abdullah, M.M. Elajaily, R.A. Ockasha, M.S. Suliman and A.A. Maihub, Int. J. Adv. Pharm. Bio. Chem., 3, 2277 (2014).
A.A. Khandar and Z. Rezvani, Polyhedron, 18, 129 (1998); doi:10.1016/S0277-5387(98)00275-7.
Z. Rezvani, L. Ahar, K. Nejati and S.M. Seyedahmadian, Acta Chim. Slov., 51, 675 (2004).
E. Erdem, E.Y. Sari, R. Kilinçarslan and N. Kabay, Transition Met. Chem., 34, 167 (2009); doi:10.1007/s11243-008-9173-9.
E. Canpolat and M. Kaya, Russ. J. Coord. Chem., 31, 790 (2005); doi:10.1007/s11173-005-0170-7.
A.B.P. Lever, Coord. Chem. Rev., 3, 119 (1968); doi:10.1016/S0010-8545(00)80107-1.