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Vol. 27 No. 10 (2015): Vol 27 Issue 10

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Investigation of Properties of Fluorine Containing Hybrid Coatings Intended for Use in Printing

https://doi.org/10.14233/ajchem.2015.19033
Hüseyin Beytut
Faculty of Technical Education, Marmara University, Göztepe, Istanbul 34722, Turkey
Mustafa Cakir
Faculty of Technology, Marmara University, Göztepe, Istanbul 34722, Turkey
Ilyas Kartal
Faculty of Technology, Marmara University, Göztepe, Istanbul 34722, Turkey
Muharrem Sengul
Faculty of Technical Education, Marmara University, Göztepe, Istanbul 34722, Turkey
Dogan Tutak
Faculty of Technical Education, Marmara University, Göztepe, Istanbul 34722, Turkey

Corresponding Author(s) : Mustafa Cakir

mcakir@marmara.edu.tr

Asian Journal of Chemistry, Vol. 27 No. 10 (2015): Vol 27 Issue 10

Abstract

The aim of this study is to investigate the effect of fluoro-silane content on a UV curable hybrid polymer applied on unsealed test charts. Silane terminated oligomer was obtained by the reaction of diethylene glycol and 3-isocyanatopropyltrimethoxysilane. Inorganic part was obtained by hydrolysis and condensation reaction of silane-terminated diethylene glycol, 1H,1H,2H,2H-perfluorooctyltriethoxysilane and 3-(trimethoxysilyl)-propylmethacrylate. Organic part consists of UV curableres in and 1,6-hexanedioldiacrylate. Hybrid coating formulations were prepared by adding previously prepared inorganic part into organic part in predetermined ratios. The abrasion resistance, static-kinetic friction coefficient, gloss and tape adhesion properties were characterized. It was found that fluoro-silane content has the main effect on the tested parameters. The resultant coatings have a high gloss endurance and high abrasion resistance and therefore they would keep the visual appearance of printed surfaces in the original condition during long periods of time.

Keywords

Organic-inorganic hybrids UV curable Sol-gel Fluoropolymer
Beytut, H., Cakir, M., Kartal, I., Sengul, M., & Tutak, D. (2015). Investigation of Properties of Fluorine Containing Hybrid Coatings Intended for Use in Printing. Asian Journal of Chemistry, 27(10), 3854–3860. https://doi.org/10.14233/ajchem.2015.19033
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