Kinetics, Thermodynamics and Mechanism of Lead Ion Removal in Presence of Surfactants

Hisham A. Abo-El-Dahab

doi:10.14233/ajchem.2015.18908

Issue

Vol. 27 No. 10 (2015): Vol 27 Issue 10

Issue Published : June 22, 2015

This work is licensed under a Creative Commons Attribution 4.0 International License.

Kinetics, Thermodynamics and Mechanism of Lead Ion Removal in Presence of Surfactants

https://doi.org/10.14233/ajchem.2015.18908

Hisham A. Abo-El-Dahab

Department of Chemistry, Faculty of Science, University of Alexandria, Alexandria, Egypt; Department of Chemistry, University College, Umm Al-Qura University, Makka, Kingdom of Saudi Arabia

Corresponding Author(s) : Hisham A. Abo-El-Dahab

hdahab-41@hotmail.com

Asian Journal of Chemistry, Vol. 27 No. 10 (2015): Vol 27 Issue 10
Article Published : June 22, 2015

Abstract

Cementation of lead by zinc in lead nitrate solution was shown to be a feasible treatment process to achieve a high degree of lead removal over a broad operational range. The rate of lead removal was studied as a function of temperatures and the addition of certain surface active substance (SAS), at different concentrations of lead nitrate. The reaction of lead cementation was carried out with or without the anionic sodium dodecyl sulphate (SDS), the non-ionic Triton X-100 and the cationic cetyltrimethylammonium bromide (CTAB) which follows first-order reaction kinetics. Viscosity, percentage of inhibition and thermodynamic parameters DH*, DS* and DG* were calculated and discussed. Cementation process was successfully applied to recover Pb²⁺ spiked to industrial wastewater sample.

Keywords

Kinetics Thermodynamics Viscosity Cementation Surfactants

A. Abo-El-Dahab, H. (2015). Kinetics, Thermodynamics and Mechanism of Lead Ion Removal in Presence of Surfactants. Asian Journal of Chemistry, 27(10), 3658–3662. https://doi.org/10.14233/ajchem.2015.18908

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References

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O.K. Shcherbakov and I. A. Karovskii, Isvert Metally, (1967) 40, (2).
L.I. Antropov and T.V. Saenko, Sov. Electrochem., 23, 153 (1987).
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References

R.B. Clark, Analysis of Marine Macrobenthic Community Structure in Relation, Marine Pollution, Oxford University Press (1993).

B. Venugopal and T.P. Luckey, in eds.: T.D. Luckey, B. Venugopal and D. Hutcheson, Toxicology of Non-Radioactive Heavy Metals and their Salts: In Heavy Metal Toxicity, Safety, and Hormology, George Thieme, Stuttgart (1975).

J. Szpunar and R. Łobiński, J. Anal. Chem., 363, 550 (1999); doi:10.1007/s002160051245.

M. Kersten and U. Fostenes, in ed.: U. Davison, Chemical Specification in Environment, Blacki, Glasgow (1995).

I.K. Krull, Trace Metal Analysis Specification, Elsevier, Amsterdam (1991).

M.U. Iberoi, Environ. Technol., 9, 47 (1999).

U. Forstner and G.T. Wittmans, Metal Pollution in Aquatic Environment, Springer Verlag, New York, edn 2, p. 37 (1983).

A.K. Biswas and W.G. Davenport, Extractive Metallurgy of Copper, Pergamon Press, New York, edn 2, p. 254 (1979).

V. Ettel, Comprehensive Treatise in Electrochemistry, in ed.: O’M. Bochris, Plenum, New York, vol. 2 (1999).

G.P. Power and I.M. Ritchie, Metal displacement reaction, In: Modern Aspect of Electrochemistry, Plenum Press, London, vol. II, p. 190 (1999).

A.K. Biswas and J.G. Reid, Inst. Min. Metall. Trans., 82, 127 (1973).

L.I. Antropov and M.I. Donchenko, Zh. Prikl. Kim. (Leningrad), 45, 275 (1972).

M. El Batouti, J. Colloid Interf. Sci., 268, 425 (2003); doi:10.1016/S0021-9797(03)00421-1.

M. El Batouti, J. Colloid Interf. Sci., 263, 548 (2003); doi:10.1016/S0021-9797(03)00295-9.

M. El Batouti, Anti Corrosion Methods Mater., 46, 189 (1999); doi:10.1108/00035599910273188.

A.A. Zaghloul, G.M. El Subruiti and A.M. Ahmed, J. Mater Sci. Technol., 12, 41 (1996).

Th.H. Mahmoud, G.M. El Subruiti, Sh. El-Shazly and N.A. Shaltout, Bull. Nat. Inst. of Oceanogr. Fish., 26, 93 (2002).

I.J. Bear, R.C.A. Flann and R. Woods, Aust. J. Chem., 41, 1875 (1988); doi:10.1071/CH9881875.

I.J. Bear, R.C.A. Flann, R. Woods and J.R. Gardner, Aust. J. Chem., 41, 1897 (1988); doi:10.1071/CH9881897.

Y. Ku and C.-S. Lee, J. Chin. Inst. Eng., 20, 295 (1997); doi:10.1080/02533839.1997.9741833.

I.J. Bear, I.E. Grey, I.C. Madsen, I.E. Newnham and L.J. Rogers, Acta Crystallogr. B, 42, 32 (1986); doi:10.1107/S0108768186098622.

I.J. Bear, I.E. Grey, I.E. Newnham and L.J. Rogers, Aust. J. Chem., 40, 539 (1987); doi:10.1071/CH9870539.

O.K. Shcherbakov and I. A. Karovskii, Isvert Metally, (1967) 40, (2).

L.I. Antropov and T.V. Saenko, Sov. Electrochem., 23, 153 (1987).

I.M. Issa, M.M. Ghoneim, A.A. El-Samahy and M. Tharwat, Electrochim. Acta, 17, 1251 (1972); doi:10.1016/0013-4686(72)80012-4.

A.M. Ahmed, E.A. Hamed, A.A. El Bardan and E.F. Saad, Alex. Engl. J., 26, 578 (1989).

N.M. El-Mallah, S. A. Sallam, E.A. Hamed, H.M. Abd El Fattah and A.M. Ahmed, Physical Sci., 6, 202 (1994).

A.M. Ahmed and G.B. Mohamed, J. Chin. Chem. Soc. (Taiwan), 42, 78 (1989).

A.M. Abdel-Gaber, E. Khamis, H. Abo-ElDahab and Sh. Adeel, J. Mater. Chem. Phys., 109, 297 (2008); doi:10.1016/j.matchemphys.2007.11.038.

A.M. Abdel-Gaber, E. Khamis, H. Abo-ElDahab and Sh. Adeel, Mater. Chem. Phys., 124, 773 (2010); doi:10.1016/j.matchemphys.2010.07.059.

Issue

Vol. 27 No. 10 (2015): Vol 27 Issue 10

Kinetics, Thermodynamics and Mechanism of Lead Ion Removal in Presence of Surfactants

Corresponding Author(s) : Hisham A. Abo-El-Dahab

Abstract

Keywords

Full Article

Download Citation

References

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