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Studies on Pectin-Tin(IV) Phosphate: A New Biopolymer Doped Hybrid Ion Exchanger, An Efficacious Ion Exchanger in Water Purification Process
Corresponding Author(s) : Amita Somya
Asian Journal of Chemistry,
Vol. 35 No. 5 (2023): Vol 35 Issue 5, 2023
Abstract
Pectin doped tin(IV) phosphate was prepared as novel class of hybrid ion exchanger i.e. biopolymer based hybrid ion exchanger, which has been characterized by few physico-chemical characterization techniques such as FTIR analysis, SEM study, UV-vis spectrophotometry and elemental analysis. The characteristic parameters of novel ion exchange such as ion exchange capacity, concentration study, elution study, thermal stability, etc. were also reported. Adsorption study has been explored for few alkaline earths and some heavy or transition metal ions in several acidic media. Based on adsorption study, it has been found that the reported ion exchanger has shown enantioselectivity for cadmium(II) ions, being one among toxic metal ions. The antimicrobial activity of pectin based tin(IV) phosphate on few microorganisms has also been studied to prove the antimicrobial nature of the synthesized ion-exchange material.
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- G.D. Gebreeyessus, Appl. Water Sci., 9, 135 (2019); https://doi.org/10.1007/s13201-019-1006-9
- A. Somya, eds.: R.K. Gupta, Metal Phosphates: Their role as Ion Exchangers in Water Purification, In: Metal Phosphates and Phosphonates. Engineering Materials, Springer, Cham (2023).
- K.M.L. Taylor-Pashow, T.C. Shehee and D.T. Hobbs, Solvent Extr. Ion Exchange, 31, 122 (2013); https://doi.org/10.1080/07366299.2012.735510
- A. Somya, eds.: R. Vargas-Bernal, Hybrid Nanomaterials, IntechOpen: London, U.K. (2020); https://doi.org/10.5772/intechopen.92116
- S.C. Mojumdar, K.G. Varshney, P. Gupta and A. Agrawal, Res. J. Chem. Environ., 10, 85 (2006).
- A. Somya, Res. J. Chem. Environ., 23, 96 (2019).
- V. Kumar, B.S. Kaith and R. Jindal, Indus. Eng. Chem. Res., 55, 10492 (2016); https://doi.org/10.1021/acs.iecr.6b01690
- S.K. Swain, S. Mishra, P. Sharma, T. Patnaik, V.K. Singh, U. Jha, R.K. Patel and R.K. Dey, Indus. Eng. Chem. Res., 49, 9846 (2010); https://doi.org/10.1021/ie1012536
- S.A. Nabi and A.H. Shalla, J. Hazard. Mater., 163, 657 (2009); https://doi.org/10.1016/j.jhazmat.2008.07.011
- K.G. Varshney, M.Z.A. Rafiquee, A. Somya and M. Drabik, Indian J. Chem., 45A, 1856 (2006).
- J.M. Kanagaraj, R. Chelladurai, S. Perumal and M. Rajamani, J. Water Environ. Technol., 5, 17 (2020); https://doi.org/10.22090/JWENT.2020.01.002
- K.G. Varshney, N. Tayal, A.A. Khan and R. Niwas, Colloids Surf. A Physicochem. Eng. Asp., 181, 123 (2001); https://doi.org/10.1016/S0927-7757(00)00750-0
- K.G. Varshney, M.Z.A. Rafiquee and A. Somya, Colloids Surf. A Physicochem. Eng. Asp., 301, 69 (2007); https://doi.org/10.1016/j.colsurfa.2006.12.025
- K.G. Varshney, M.Z.A. Rafiquee and A. Somya, Colloids Surf. A Physicochem. Eng. Asp., 301, 224 (2007); https://doi.org/10.1016/j.colsurfa.2006.12.061
- A. Somya, M.Z.A. Rafiquee and V. Upadhyaya, Res. J. Chem. Environ., 22, 45 (2018).
- N. Iqbal, M. Mobin, M.Z.A. Rafiquee and H.A. Al-Lohedan, Desalin. Water Treat., 57, 19926 (2016); https://doi.org/10.1080/19443994.2015.1109556
- A. Somya and V. Upadhayaya, Res. J. Chem. Environ., 24, 107 (2020).
- A. Somya and V. Upadhyaya, Res. J. Chem. Environ., 21, 18 (2017).
- A. Somya and M. Singh, Curr. Anal. Chem., 18, 383 (2021); https://doi.org/10.2174/1573411017666210804102748
- A. Somya and K. Maheria, Bull. Mater. Sci., 43, 163 (2020); https://doi.org/10.1007/s12034-020-02153-z
- A. Somya, M.Z.A. Rafiquee, K.G. Varshney and H.A. Al-Lohedan, Desalination Water Treat., 56, 638 (2015); https://doi.org/10.1080/19443994.2014.940388
- A. Somya, M.Z.A. Rafiquee and K.G. Varshney, Colloids Surf. A Physicochem. Eng. Asp., 336, 142 (2009); https://doi.org/10.1016/j.colsurfa.2008.11.036
- K.G. Varshney, M.Z.A. Rafiquee and A. Somya, Colloids Surf. A Physicochem. Eng. Asp., 317, 400 (2008); https://doi.org/10.1016/j.colsurfa.2007.11.012
- K.G. Varshney, M.Z.A. Rafiquee and A. Somya, J. Therm. Anal. Calorim., 90, 663 (2007); https://doi.org/10.1007/s10973-007-8519-4
- N. Johri, G. Jacquillet and R. Unwin, Biometals, 23, 783 (2010); https://doi.org/10.1007/s10534-010-9328-y
- I. Anastopoulos, A. Bhatnagar and E.C. Lima, J. Mol. Liq., 221, 954 (2016); https://doi.org/10.1016/j.molliq.2016.06.076
- D. Liu, X. Wan, W. Li, M. Peng and J. Luo, Ind. Eng. Chem. Res., 61, 8177 (2022); https://doi.org/10.1021/acs.iecr.2c00175
- N. Kohila and P. Subramaniam, React. Funct. Polym., 144, 104341 (2019); https://doi.org/10.1016/j.reactfunctpolym.2019.104341
- D. Pathania, G. Sharma, M. Naushad and V. Priya, Desalin. Water Treat., 57, 468 (2016); https://doi.org/10.1080/19443994.2014.967731
- C.N.R. Rao, Chemical Applications of Infrared Spectroscopy, Academy Press, New York (1963).
- P.S. Kalsi, Spectroscopy of Organic Compounds, Edn. 5 (2002).
References
G.D. Gebreeyessus, Appl. Water Sci., 9, 135 (2019); https://doi.org/10.1007/s13201-019-1006-9
A. Somya, eds.: R.K. Gupta, Metal Phosphates: Their role as Ion Exchangers in Water Purification, In: Metal Phosphates and Phosphonates. Engineering Materials, Springer, Cham (2023).
K.M.L. Taylor-Pashow, T.C. Shehee and D.T. Hobbs, Solvent Extr. Ion Exchange, 31, 122 (2013); https://doi.org/10.1080/07366299.2012.735510
A. Somya, eds.: R. Vargas-Bernal, Hybrid Nanomaterials, IntechOpen: London, U.K. (2020); https://doi.org/10.5772/intechopen.92116
S.C. Mojumdar, K.G. Varshney, P. Gupta and A. Agrawal, Res. J. Chem. Environ., 10, 85 (2006).
A. Somya, Res. J. Chem. Environ., 23, 96 (2019).
V. Kumar, B.S. Kaith and R. Jindal, Indus. Eng. Chem. Res., 55, 10492 (2016); https://doi.org/10.1021/acs.iecr.6b01690
S.K. Swain, S. Mishra, P. Sharma, T. Patnaik, V.K. Singh, U. Jha, R.K. Patel and R.K. Dey, Indus. Eng. Chem. Res., 49, 9846 (2010); https://doi.org/10.1021/ie1012536
S.A. Nabi and A.H. Shalla, J. Hazard. Mater., 163, 657 (2009); https://doi.org/10.1016/j.jhazmat.2008.07.011
K.G. Varshney, M.Z.A. Rafiquee, A. Somya and M. Drabik, Indian J. Chem., 45A, 1856 (2006).
J.M. Kanagaraj, R. Chelladurai, S. Perumal and M. Rajamani, J. Water Environ. Technol., 5, 17 (2020); https://doi.org/10.22090/JWENT.2020.01.002
K.G. Varshney, N. Tayal, A.A. Khan and R. Niwas, Colloids Surf. A Physicochem. Eng. Asp., 181, 123 (2001); https://doi.org/10.1016/S0927-7757(00)00750-0
K.G. Varshney, M.Z.A. Rafiquee and A. Somya, Colloids Surf. A Physicochem. Eng. Asp., 301, 69 (2007); https://doi.org/10.1016/j.colsurfa.2006.12.025
K.G. Varshney, M.Z.A. Rafiquee and A. Somya, Colloids Surf. A Physicochem. Eng. Asp., 301, 224 (2007); https://doi.org/10.1016/j.colsurfa.2006.12.061
A. Somya, M.Z.A. Rafiquee and V. Upadhyaya, Res. J. Chem. Environ., 22, 45 (2018).
N. Iqbal, M. Mobin, M.Z.A. Rafiquee and H.A. Al-Lohedan, Desalin. Water Treat., 57, 19926 (2016); https://doi.org/10.1080/19443994.2015.1109556
A. Somya and V. Upadhayaya, Res. J. Chem. Environ., 24, 107 (2020).
A. Somya and V. Upadhyaya, Res. J. Chem. Environ., 21, 18 (2017).
A. Somya and M. Singh, Curr. Anal. Chem., 18, 383 (2021); https://doi.org/10.2174/1573411017666210804102748
A. Somya and K. Maheria, Bull. Mater. Sci., 43, 163 (2020); https://doi.org/10.1007/s12034-020-02153-z
A. Somya, M.Z.A. Rafiquee, K.G. Varshney and H.A. Al-Lohedan, Desalination Water Treat., 56, 638 (2015); https://doi.org/10.1080/19443994.2014.940388
A. Somya, M.Z.A. Rafiquee and K.G. Varshney, Colloids Surf. A Physicochem. Eng. Asp., 336, 142 (2009); https://doi.org/10.1016/j.colsurfa.2008.11.036
K.G. Varshney, M.Z.A. Rafiquee and A. Somya, Colloids Surf. A Physicochem. Eng. Asp., 317, 400 (2008); https://doi.org/10.1016/j.colsurfa.2007.11.012
K.G. Varshney, M.Z.A. Rafiquee and A. Somya, J. Therm. Anal. Calorim., 90, 663 (2007); https://doi.org/10.1007/s10973-007-8519-4
N. Johri, G. Jacquillet and R. Unwin, Biometals, 23, 783 (2010); https://doi.org/10.1007/s10534-010-9328-y
I. Anastopoulos, A. Bhatnagar and E.C. Lima, J. Mol. Liq., 221, 954 (2016); https://doi.org/10.1016/j.molliq.2016.06.076
D. Liu, X. Wan, W. Li, M. Peng and J. Luo, Ind. Eng. Chem. Res., 61, 8177 (2022); https://doi.org/10.1021/acs.iecr.2c00175
N. Kohila and P. Subramaniam, React. Funct. Polym., 144, 104341 (2019); https://doi.org/10.1016/j.reactfunctpolym.2019.104341
D. Pathania, G. Sharma, M. Naushad and V. Priya, Desalin. Water Treat., 57, 468 (2016); https://doi.org/10.1080/19443994.2014.967731
C.N.R. Rao, Chemical Applications of Infrared Spectroscopy, Academy Press, New York (1963).
P.S. Kalsi, Spectroscopy of Organic Compounds, Edn. 5 (2002).