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Vol. 29 No. 1 (2017): Vol 29 Issue 1

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Solvothermal Magnetic Graphene Oxide for Efficient and Fast Remediation of p-Nitroaniline from Industrial Wastewaters

https://doi.org/10.14233/ajchem.2017.20183
Amr A. Yakout1
1Chemistry Department, Faculty of Science, University of Jeddah, Jeddah, Saudi Arabia 2Chemistry Department, Faculty of Science, Alexandria University, Alexandria, Egypt 3Chemistry Department, Faculty of Science, Assiut University, Assiut, Egypt 4Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia 5Chemistry Department, Faculty of Science, Damanhour University, Damanhour, Egypt 6Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt *Corresponding author: Tel: +966 565484044; E-mail: aayhussain@uj0edu.sa; Amryakout157@gmail.com
Deia Abd El-Hady1
1Chemistry Department, Faculty of Science, University of Jeddah, Jeddah, Saudi Arabia 2Chemistry Department, Faculty of Science, Alexandria University, Alexandria, Egypt 3Chemistry Department, Faculty of Science, Assiut University, Assiut, Egypt 4Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia 5Chemistry Department, Faculty of Science, Damanhour University, Damanhour, Egypt 6Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt *Corresponding author: Tel: +966 565484044; E-mail: aayhussain@uj0edu.sa; Amryakout157@gmail.com
Hassan M. Albishri4
1Chemistry Department, Faculty of Science, University of Jeddah, Jeddah, Saudi Arabia 2Chemistry Department, Faculty of Science, Alexandria University, Alexandria, Egypt 3Chemistry Department, Faculty of Science, Assiut University, Assiut, Egypt 4Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia 5Chemistry Department, Faculty of Science, Damanhour University, Damanhour, Egypt 6Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt *Corresponding author: Tel: +966 565484044; E-mail: aayhussain@uj0edu.sa; Amryakout157@gmail.com
Medhat A. Shaker1
1Chemistry Department, Faculty of Science, University of Jeddah, Jeddah, Saudi Arabia 2Chemistry Department, Faculty of Science, Alexandria University, Alexandria, Egypt 3Chemistry Department, Faculty of Science, Assiut University, Assiut, Egypt 4Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia 5Chemistry Department, Faculty of Science, Damanhour University, Damanhour, Egypt 6Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt *Corresponding author: Tel: +966 565484044; E-mail: aayhussain@uj0edu.sa; Amryakout157@gmail.com
Ahmed H. Abdel-Salam1
1Chemistry Department, Faculty of Science, University of Jeddah, Jeddah, Saudi Arabia 2Chemistry Department, Faculty of Science, Alexandria University, Alexandria, Egypt 3Chemistry Department, Faculty of Science, Assiut University, Assiut, Egypt 4Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia 5Chemistry Department, Faculty of Science, Damanhour University, Damanhour, Egypt 6Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt *Corresponding author: Tel: +966 565484044; E-mail: aayhussain@uj0edu.sa; Amryakout157@gmail.com
Abdelaziz S. El-Ahl1
1Chemistry Department, Faculty of Science, University of Jeddah, Jeddah, Saudi Arabia 2Chemistry Department, Faculty of Science, Alexandria University, Alexandria, Egypt 3Chemistry Department, Faculty of Science, Assiut University, Assiut, Egypt 4Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia 5Chemistry Department, Faculty of Science, Damanhour University, Damanhour, Egypt 6Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt *Corresponding author: Tel: +966 565484044; E-mail: aayhussain@uj0edu.sa; Amryakout157@gmail.com
Mohamed E. Saber Ali1
1Chemistry Department, Faculty of Science, University of Jeddah, Jeddah, Saudi Arabia 2Chemistry Department, Faculty of Science, Alexandria University, Alexandria, Egypt 3Chemistry Department, Faculty of Science, Assiut University, Assiut, Egypt 4Chemistry Department, Faculty of Science, King Abdulaziz University, Jeddah, Saudi Arabia 5Chemistry Department, Faculty of Science, Damanhour University, Damanhour, Egypt 6Chemistry Department, Faculty of Science, Mansoura University, Mansoura, Egypt *Corresponding author: Tel: +966 565484044; E-mail: aayhussain@uj0edu.sa; Amryakout157@gmail.com

Asian Journal of Chemistry, Vol. 29 No. 1 (2017): Vol 29 Issue 1

Abstract

Pollution by aromatic compounds such as p-nitroaniline in ecosystem has raised significant concerns. A fast and effective removal of p-nitroaniline can be carried out by magnetic graphene oxide as a potential sorbent. Different mechanisms including p–p interaction, ion-ion and cation–p bonding interactions have been proposed to describe the strong deposition of p-nitroaniline onto magnetic graphene oxide surface. The % removal of p-nitroaniline was found to be pH-dependent and attained a maximum value at pH 7.2. The adsorption was best described by Langmuir model with a theoretically estimated maximum adsorption capacity of 482.7 mg g-1, which was very close to the measured value. The adsorption kinetics followed the pseudo-second-order equations very well. The applicability of magnetic graphene oxide for the adsorption of p-nitroaniline from industrial wastewater samples was successfully accomplished.

Keywords

Magnetic solid phase extraction Graphene oxide Nanosorbent p-Nitroaniline Industrial wastewaters.
A. Yakout1, A., Abd El-Hady1, D., M. Albishri4, H., A. Shaker1, M., H. Abdel-Salam1, A., S. El-Ahl1, A., & E. Saber Ali1, M. (2016). Solvothermal Magnetic Graphene Oxide for Efficient and Fast Remediation of p-Nitroaniline from Industrial Wastewaters. Asian Journal of Chemistry, 29(1), 175–180. https://doi.org/10.14233/ajchem.2017.20183
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