Copyright (c) 2023 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
An Amino Acid Grafted Graphene Oxide as Promising Material in Poly(urea-formaldehyde)-Epoxy Microcapsules for Enhancing the Interfacial Adhesion of Epoxy Coatings
Corresponding Author(s) : D. Priyanka
Asian Journal of Chemistry,
Vol. 35 No. 3 (2023): Vol 35 Issue 3, 2023
Abstract
Novel microencapsulated materials with superior anti-corrosion properties and improved adhesive strength on the metal substrate were produced by emulsion polymerization and characterized successfully. Initially, serine grafted graphene oxide was prepared and characterized through various sophisticated techniques. Then, MC-GO/epoxy and MC-GO-Ser were individually impregnated into th epoxy system and applied on the mild steel substrates. Corrosion tests were performed to evaluate the non-corrosive nature of MC-GO/epoxy and MC-GO-Ser/epoxy samples. After 7 days of exposure in saline media, MC-GO-Ser microcapsules demonstrated 80.6 % protective efficiency. Furthermore, the peel strength of 2.90 N revealed that the coating loaded with MC-GO-Ser microcapsules had improved adherence to the mild steel surface. Results of urea-formaldehyde GO-Ser microcapsules showed better corrosion protection and greater adhesive strength, which is probably because of the exceptional barrier action of microcapsules against the incursion of corrosion solution onto the mild steel surface.
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- S. Zhou, Y. Wu, W. Zhao, J. Yu, F. Jiang, Y. Wu and L. Ma, Mater. Des., 169, 107694 (2019); https://doi.org/10.1016/j.matdes.2019.107694
- L.M. Calado, M.G. Taryba, M.J. Carmezim and M.F. Montemor, Corros. Sci., 142, 12 (2018); https://doi.org/10.1016/j.corsci.2018.06.013
- S.R. Nayak and K.N.S. Mohana, Surf. Interfaces, 11, 63 (2018); https://doi.org/10.1016/j.surfin.2018.03.002
- M.J. Palimi, M. Rostami, M. Mahdavian and B. Ramezanzadeh, J. Coat. Technol. Res., 12, 277 (2015); https://doi.org/10.1007/s11998-014-9631-6
- B.E. Rani and A. Basu, Int. J. Corros., 2012, 1 (2012); https://doi.org/10.1155/2012/380217
- D. Wang and G.P. Bierwagen, Prog. Org. Coat., 64, 327 (2009); https://doi.org/10.1016/j.porgcoat.2008.08.010
- M.G. Sari, M. Shamshiri and B. Ramezanzadeh, Corros. Sci., 129, 38 (2017); https://doi.org/10.1016/j.corsci.2017.09.024
- S.E. Karekar, U.D. Bagale, S.H. Sonawane, B.A. Bhanvase and D.V. Pinjari, Compos. Interfaces, 25, 85 (2018); https://doi.org/10.1080/09276440.2018.1439631
- J.E. Gray and B. Luan, J. Alloys Compd., 336, 88 (2002); https://doi.org/10.1016/S0925-8388(01)01899-0
- S. Liu, L. Gu, H. Zhao, J. Chen and J. Yu, J. Mater. Sci. Technol., 32, 425 (2016); https://doi.org/10.1016/j.jmst.2015.12.017
- S. Pourhashem, M.R. Vaezi, A. Rashidi and M.R. Bagherzadeh, Prog. Org. Coat., 111, 47 (2017); https://doi.org/10.1016/j.porgcoat.2017.05.008
- F. Zhang, P. Ju, M. Pan, D. Zhang, Y. Huang, G. Li and X. Li, Corros. Sci., 144, 74 (2018); https://doi.org/10.1016/j.corsci.2018.08.005
- G. Kordas, Corros. Mater. Degrad., 3, 376 (2022); https://doi.org/10.3390/cmd3030023
- L. Liu and J. Xu, Vacuum, 85, 687 (2011); https://doi.org/10.1016/j.vacuum.2010.10.009
- S.S. Golru, M. Attar and B. Ramezanzadeh, Prog. Org. Coat., 77, 1391 (2014); https://doi.org/10.1016/j.porgcoat.2014.04.017
- Z. Yu, H. Di, Y. Ma, L. Lv, Y. Pan, C. Zhang and Y. He, Appl. Surf. Sci., 351, 986 (2015); https://doi.org/10.1016/j.apsusc.2015.06.026
- M. Kasaeian, E. Ghasemi, B. Ramezanzadeh and M. Mahdavian, J. Ind. Eng. Chem., 73, 162 (2019); https://doi.org/10.1016/j.jiec.2019.01.019
- J. Chen, B. Yao, C. Li and G. Shi, Carbon, 64, 225 (2013); https://doi.org/10.1016/j.carbon.2013.07.055
- N.I. Zaaba, K.L. Foo, U. Hashim, S.J. Tan, W. Liu and C.H. Voon, Procedia Eng., 184, 469 (2017); https://doi.org/10.1016/j.proeng.2017.04.118
- D.C. Marcano, D.V. Kosynkin, J.M. Berlin, A. Sinitskii, Z. Sun, L.B. Alemany, A. Slesarev, W. Lu and J.M. Tour, ACS Nano, 4, 4806 (2010); https://doi.org/10.1021/nn1006368
- L. Shahriary and A.A. Athawale, Int. J. Renew. Energy Environ. Eng., 2, 58 (2014).
- A.S. Hicyilmaz and A.C. Bedeloglu, Mater. Sci. Res. India, 16, 07 (2019); https://doi.org/10.13005/msri/160103
- B. Qian, J. Ren, Z. Song and Y. Zhou, J. Mater. Sci., 53, 14204 (2018); https://doi.org/10.1007/s10853-018-2615-7
- N. Parhizkar, T. Shahrabi and B. Ramezanzadeh, Corros. Sci., 123, 55 (2017); https://doi.org/10.1016/j.corsci.2017.04.011
- M.S. Eluyemi, M.A. Eleruja, A.V. Adedeji, B. Olofinjana, O. Fasakin, O.O. Akinwunmi, O. O. Ilori, A.T. Famojuro, S.A. Ayinde and E.O.B. Ajayi, Graphene, 5, 143 (2016); https://doi.org/10.4236/graphene.2016.53012
- J. Li, J. Cui, J. Yang, Y. Ma, H. Qiu and J. Yang, Prog. Org. Coat., 99, 443 (2016);
- https://doi.org/10.1016/j.porgcoat.2016.07.008
- D. Li and A.W Neumann, J. Colloid Interf. Sci., 137, 304 (1990); https://doi.org/10.1016/0021-9797(90)90067-X
- Y. Zhang, D.W. Hazelton, A.R. Knoll, J.M. Duval, P. Brownsey, S. Repnoy, S. Soloveichik, A. Sundaram, R.B. McClure, G. Majkic and V. Selvamanickam, Physica C, 473, 41 (2012); https://doi.org/10.1016/j.physc.2011.11.013
- M. Fadil, D.S. Chauhan and M.A. Quraishi, Russ. J. Appl. Chem., 91, 1721 (2018); https://doi.org/10.1134/S107042721810021X
References
S. Zhou, Y. Wu, W. Zhao, J. Yu, F. Jiang, Y. Wu and L. Ma, Mater. Des., 169, 107694 (2019); https://doi.org/10.1016/j.matdes.2019.107694
L.M. Calado, M.G. Taryba, M.J. Carmezim and M.F. Montemor, Corros. Sci., 142, 12 (2018); https://doi.org/10.1016/j.corsci.2018.06.013
S.R. Nayak and K.N.S. Mohana, Surf. Interfaces, 11, 63 (2018); https://doi.org/10.1016/j.surfin.2018.03.002
M.J. Palimi, M. Rostami, M. Mahdavian and B. Ramezanzadeh, J. Coat. Technol. Res., 12, 277 (2015); https://doi.org/10.1007/s11998-014-9631-6
B.E. Rani and A. Basu, Int. J. Corros., 2012, 1 (2012); https://doi.org/10.1155/2012/380217
D. Wang and G.P. Bierwagen, Prog. Org. Coat., 64, 327 (2009); https://doi.org/10.1016/j.porgcoat.2008.08.010
M.G. Sari, M. Shamshiri and B. Ramezanzadeh, Corros. Sci., 129, 38 (2017); https://doi.org/10.1016/j.corsci.2017.09.024
S.E. Karekar, U.D. Bagale, S.H. Sonawane, B.A. Bhanvase and D.V. Pinjari, Compos. Interfaces, 25, 85 (2018); https://doi.org/10.1080/09276440.2018.1439631
J.E. Gray and B. Luan, J. Alloys Compd., 336, 88 (2002); https://doi.org/10.1016/S0925-8388(01)01899-0
S. Liu, L. Gu, H. Zhao, J. Chen and J. Yu, J. Mater. Sci. Technol., 32, 425 (2016); https://doi.org/10.1016/j.jmst.2015.12.017
S. Pourhashem, M.R. Vaezi, A. Rashidi and M.R. Bagherzadeh, Prog. Org. Coat., 111, 47 (2017); https://doi.org/10.1016/j.porgcoat.2017.05.008
F. Zhang, P. Ju, M. Pan, D. Zhang, Y. Huang, G. Li and X. Li, Corros. Sci., 144, 74 (2018); https://doi.org/10.1016/j.corsci.2018.08.005
G. Kordas, Corros. Mater. Degrad., 3, 376 (2022); https://doi.org/10.3390/cmd3030023
L. Liu and J. Xu, Vacuum, 85, 687 (2011); https://doi.org/10.1016/j.vacuum.2010.10.009
S.S. Golru, M. Attar and B. Ramezanzadeh, Prog. Org. Coat., 77, 1391 (2014); https://doi.org/10.1016/j.porgcoat.2014.04.017
Z. Yu, H. Di, Y. Ma, L. Lv, Y. Pan, C. Zhang and Y. He, Appl. Surf. Sci., 351, 986 (2015); https://doi.org/10.1016/j.apsusc.2015.06.026
M. Kasaeian, E. Ghasemi, B. Ramezanzadeh and M. Mahdavian, J. Ind. Eng. Chem., 73, 162 (2019); https://doi.org/10.1016/j.jiec.2019.01.019
J. Chen, B. Yao, C. Li and G. Shi, Carbon, 64, 225 (2013); https://doi.org/10.1016/j.carbon.2013.07.055
N.I. Zaaba, K.L. Foo, U. Hashim, S.J. Tan, W. Liu and C.H. Voon, Procedia Eng., 184, 469 (2017); https://doi.org/10.1016/j.proeng.2017.04.118
D.C. Marcano, D.V. Kosynkin, J.M. Berlin, A. Sinitskii, Z. Sun, L.B. Alemany, A. Slesarev, W. Lu and J.M. Tour, ACS Nano, 4, 4806 (2010); https://doi.org/10.1021/nn1006368
L. Shahriary and A.A. Athawale, Int. J. Renew. Energy Environ. Eng., 2, 58 (2014).
A.S. Hicyilmaz and A.C. Bedeloglu, Mater. Sci. Res. India, 16, 07 (2019); https://doi.org/10.13005/msri/160103
B. Qian, J. Ren, Z. Song and Y. Zhou, J. Mater. Sci., 53, 14204 (2018); https://doi.org/10.1007/s10853-018-2615-7
N. Parhizkar, T. Shahrabi and B. Ramezanzadeh, Corros. Sci., 123, 55 (2017); https://doi.org/10.1016/j.corsci.2017.04.011
M.S. Eluyemi, M.A. Eleruja, A.V. Adedeji, B. Olofinjana, O. Fasakin, O.O. Akinwunmi, O. O. Ilori, A.T. Famojuro, S.A. Ayinde and E.O.B. Ajayi, Graphene, 5, 143 (2016); https://doi.org/10.4236/graphene.2016.53012
J. Li, J. Cui, J. Yang, Y. Ma, H. Qiu and J. Yang, Prog. Org. Coat., 99, 443 (2016);
https://doi.org/10.1016/j.porgcoat.2016.07.008
D. Li and A.W Neumann, J. Colloid Interf. Sci., 137, 304 (1990); https://doi.org/10.1016/0021-9797(90)90067-X
Y. Zhang, D.W. Hazelton, A.R. Knoll, J.M. Duval, P. Brownsey, S. Repnoy, S. Soloveichik, A. Sundaram, R.B. McClure, G. Majkic and V. Selvamanickam, Physica C, 473, 41 (2012); https://doi.org/10.1016/j.physc.2011.11.013
M. Fadil, D.S. Chauhan and M.A. Quraishi, Russ. J. Appl. Chem., 91, 1721 (2018); https://doi.org/10.1134/S107042721810021X