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Vol. 35 No. 3 (2023): Vol 35 Issue 3, 2023

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Synthesis of New Degradable AB-Type Polyesters with 1,2,3-Triazole Rings in the Backbone via “Click” Step-Growth Polymerization

https://doi.org/10.14233/ajchem.2023.27283
Tengiz Kantaria
Institute of Chemistry and Molecular Engineering, Agricultural University of Georgia, Kakha Bendukidze University Campus, # 240 David Aghmashenebeli Alley, 0159 Tbilisi, Georgia
Temur Kantaria
Institute of Chemistry and Molecular Engineering, Agricultural University of Georgia, Kakha Bendukidze University Campus, # 240 David Aghmashenebeli Alley, 0159 Tbilisi, Georgia
A. Vanishvili
G. Tsulukidze Mining Institute, 7 Elizbar Mindeli St., 0186 Tbilisi, Georgia
S. Kvinikadze
G. Tsulukidze Mining Institute, 7 Elizbar Mindeli St., 0186 Tbilisi, Georgia
D. Klinger
Institute of Pharmacy, Freie Universität Berlin, Königin-Luise-Straße 2-4, 14195 Berlin, Germany
R. Katsarava
Institute of Chemistry and Molecular Engineering, Agricultural University of Georgia, Kakha Bendukidze University Campus, # 240 David Aghmashenebeli Alley, 0159 Tbilisi, Georgia

Corresponding Author(s) : R. Katsarava

r.katsarava@agruni.edu.ge

Asian Journal of Chemistry, Vol. 35 No. 3 (2023): Vol 35 Issue 3, 2023

Abstract

A series of new aliphatic AB-type polyesters (PEs) and co-polyesters (co-PEs) with 1,2,3-triazole rings in the backbone were successfully synthesized via Cu(I)-catalyzed click step-growth polymerization (SGP) following the efficient one pot/two step synthetic strategy. The structure of the click polymers was confirmed by FT-IR and NMR spectroscopy and the new materials were characterized in terms of yield, solubility, film-forming properties, molecular weights and molecular weight distribution by gel permeation chromatography (GPC) and degradation ability by total organic carbon (TOC) technique. The obtained hydrolytically degradable AB-type polyesters and co-polyesters with a rather high degree of polymerization, film-forming properties and solubility behaviour increase a library of available degradable click polymers promising for wide range of biomedical applications and also confirm the suitability of the present synthetic strategy for designing different types of triazole main chain degradable click polymers.

Keywords

Polyester Copper(I) catalyzed azide-alkyne cycloaddition Step-growth polymerization Degradation 1,2,3-Triazole ring
Kantaria, T., Kantaria, T., Vanishvili, A., Kvinikadze, S., Klinger, D., & Katsarava, R. (2023). Synthesis of New Degradable AB-Type Polyesters with 1,2,3-Triazole Rings in the Backbone via “Click” Step-Growth Polymerization. Asian Journal of Chemistry, 35(3), 649–654. https://doi.org/10.14233/ajchem.2023.27283
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