Fluorometric Detection of Al3+ Ion in Mixed Aqueous Solvent Based on Simple Schiff-Base Molecular Prob

Sanju Das

doi:10.14233/ajchem.2023.26944

Issue

Vol. 35 No. 2 (2023): Vol 35 Issue 2, 2023

Issue Published : January 30, 2023

This work is licensed under a Creative Commons Attribution 4.0 International License.

Fluorometric Detection of Al3+ Ion in Mixed Aqueous Solvent Based on Simple Schiff-Base Molecular Prob

https://doi.org/10.14233/ajchem.2023.26944

Sanju Das

Department of Chemistry, Maulana Azad College, Kolkata-700013, India

Corresponding Author(s) : Sanju Das

sanjudasju@gmail.com

Asian Journal of Chemistry, Vol. 35 No. 2 (2023): Vol 35 Issue 2, 2023
Article Published : January 30, 2023

Abstract

A simple fluorometric detection for Al³⁺ ion in mixed aqueous medium using a simple Schiff-base molecule through PET mechanism is discussed. The di-phenolic Schiff-base molecule (EAMHM) was synthesized by the condensation reaction of multiple phenolic aldehyde molecules with a diamine containing multiple aldehyde-reacting primary amine moieties. The extremely low fluorescence quantum yield for EAMHM is highly useful for the off-mode of fluorescence sensing purposes. Contrary to various other cations Ni²⁺, Mg²⁺, Co²⁺, Cu²⁺, Zn²⁺, Cr³⁺, Cd²⁺, Fe³⁺, Ba²⁺, Hg²⁺, the selective Al³⁺ ion induced large fluorescence enhancement can be employed to detect Al³⁺ even in the presence other bi- or tri-valent cations. Moreover, linear change in fluorescence intensity with Al³⁺ concentration is highly beneficial for ratiometric detection of unknown Al³⁺ concentrations. As revealed from various spectroscopic and theoretical calculations, EAMHM forms a 1:1 complex with Al³⁺ showing a large increase in fluorescence intensity. It has also been identified that efficient photo-induced electron transfer (PET) in free EAMHM is mainly responsible for its low fluorescence intensity, whereas the removal of such PET process during its complexation with Al³⁺ produces large fluorescence enhancement. The structural and electronic parameters of the free EAMHM and EAMHM-Al³⁺ complex have been analyzed using DFT-based theoretical calculations.

Keywords

Fluorometry Aluminium ion Mixed aqueous solvent Photo-induced electron transfer Schiff base

Das, S. (2023). Fluorometric Detection of Al3+ Ion in Mixed Aqueous Solvent Based on Simple Schiff-Base Molecular Prob. Asian Journal of Chemistry, 35(2), 493–498. https://doi.org/10.14233/ajchem.2023.26944

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References

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References

S. Goswami, S. Paul and A. Manna, RSC Adv., 3, 10639 (2013); https://doi.org/10.1039/c3ra40984h

R.E. Doherty, Environ. Forensics, 1, 83 (2000); https://doi.org/10.1006/enfo.2000.0011

M.S. Golub, J.M. Donald, M.E. Gershwin and C.L. Keen, Neurotoxicol. Teratol., 11, 231 (1989); https://doi.org/10.1016/0892-0362(89)90064-0

N. Fimreite, O.O. Hansen and H.C. Pettersen, Bull. Environ. Contam. Toxicol., 58, 1 (1997); https://doi.org/10.1007/s001289900292

H. Wang, B. Wang, Z. Shi, X. Tang, W. Dou, Q. Han, Y. Zhang and W. Liu, Biosens. Bioelectron., 65, 91 (2015); https://doi.org/10.1016/j.bios.2014.10.018

M. Iniya, D. Jeyanthi, K. Krishnaveni and D. Chellappa, J. Lumin., 157, 383 (2015); https://doi.org/10.1016/j.jlumin.2014.09.018

A. Budimir, Acta Pharm., 61, 1 (2011); https://doi.org/10.2478/v10007-011-0006-6

N.E.W. Alstad, B.M. Kjelsberg, L.A. Vollestad, E. Lydersen and A.B.S. Poleo, Environ. Pollut., 133, 333 (2005); https://doi.org/10.1016/j.envpol.2004.05.030

S. Kim, J.Y. Noh, K.Y. Kim, J.H. Kim, H.K. Kang, S.W. Nam, S.H. Kim, S. Park, C. Kim and J. Kim, Inorg. Chem., 51, 3597 (2012); https://doi.org/10.1021/ic2024583

Y. Lu, S. Huang, Y. Liu, S. He, L. Zhao and X. Zeng, Org. Lett., 13, 5274 (2011); https://doi.org/10.1021/ol202054v

M. Venturini-Soriano and G. Berthon, J. Inorg. Biochem., 85, 143 (2001); https://doi.org/10.1016/S0162-0134(01)00206-9

C. Pan, K. Wang, S. Ji, H. Wang, Z. Li, H. He and Y. Huo, RSC Adv., 7, 36007 (2017); https://doi.org/10.1039/C7RA05064J

S. Muthusamy, K. Rajalakshmi, D. Zhu, W. Zhu, S. Wang, K.-B. Lee H. Xue and L. Zhao, Sens. Actuators B: Chem., 346, 130534 (2021); https://doi.org/10.1016/j.snb.2021.130534

J. Ma, Y. Dong, Z. Yu, Y. Wu and Z. Zhao, New J. Chem., 46, 3348 (2022); https://doi.org/10.1039/D1NJ05919J

E. Lambert, B. Chabut, S. Chardon-Noblat, A. Deronzier, G. Chottard, A. Bousseksou, J.-P. Tuchagues, J. Laugier, M. Bardet and J.-M. Latour, J. Am. Chem. Soc., 119, 9424 (1997); https://doi.org/10.1021/ja970345q

J.V. Morris, M.A. Mahaney and J.R. Huber, J. Phys. Chem., 80, 969 (1976); https://doi.org/10.1021/j100550a010

M.J. Frisch, G.W. Trucks, H.B. Schlegel, G.E. Scuseria, M.A. Robb, J.R. Cheeseman, G. Scalmani, V. Barone, B. Mennucci, G.A. Petersson, H. Nakatsuji, M. Caricato, X. Li, H.P. Hratchian, A.F. Izmaylov, J. Bloino, G. Zheng, J.L. Sonnenberg, M. Hada, M. Ehara, K. Toyota, R. Fukuda, J. Hasegawa, M. Ishida, T. Nakajima, Y. Honda, O. Kitao, H. Nakai, T. Vreven, J.A. Montgomery, Jr., J.E. Peralta, F. Ogliaro, M. Bearpark, J.J. Heyd, E. Brothers, K.N. Kudin, V.N. Staroverov, R. Kobayashi, J. Normand, K. Raghavachari, A. Rendell, J.C. Burant, S.S. Iyengar, J. Tomasi, M. Cossi, N. Rega, J.M. Millam, M. Klene, J.E. Knox, J.B. Cross, V. Bakken, C. Adamo, J. Jaramillo, R. Gomperts, R.E. Stratmann, O. Yazyev, A.J. Austin, C. Pomelli, J.W. Ochterski, R.L. Martin, K. Morokuma, R. Cammi, V.G. Zakrzewski, G.A. Voth, P. Salvador, J.J. Dannenberg, S. Dapprich, A.D. Daniels, Ö. Farkas, J.B. Foresman, J. Cioslowski, J.V. Ortiz and D.J. Fox, Gaussian, Inc., Wallingford CT, , Gaussian 09 Rev. A.1 (2009).

Y. Sarkar, S. Das, A. Ray, S.K. Jewrajka, S. Hirota and P.P. Parui, Analyst, 141, 2030 (2016); https://doi.org/10.1039/C5AN02128F

S. Biswas, S. Mukherjee, J. Bandyopadhyay, S. Samanta, I. Bhowmick, S. Das, D.K. Hazra, A. Ray and P.P. Parui, RSC Adv., 4, 9656 (2014); https://doi.org/10.1039/C4RA00069B

D. Maity and T. Govindaraju, Eur. J. Inorg. Chem., 2011, 5479 (2011); https://doi.org/10.1002/ejic.201100772

H.A. Benesi and J.H. Hildebrand, J. Am. Chem. Soc., 71, 2703 (1949); https://doi.org/10.1021/ja01176a030

Issue

Vol. 35 No. 2 (2023): Vol 35 Issue 2, 2023

Fluorometric Detection of Al3+ Ion in Mixed Aqueous Solvent Based on Simple Schiff-Base Molecular Prob

Corresponding Author(s) : Sanju Das

Abstract

Keywords

Full Article

Download Citation

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