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Vol. 35 No. 2 (2023): Vol 35 Issue 2, 2023

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Nickel(II) Complexes of Octamethyl Tetraazamacrocycle and its N-Pendent Derivative: Syntheses, Characterization, Electrolytic Behaviour and Antimicrobial Activities

https://doi.org/10.14233/ajchem.2023.26929
Ruhul Amin
Department of Chemistry, Faculty of Science, University of Chittagong, Chattogram 4331, Bangladesh ; Institute of Nuclear Science and Technology, Atomic Energy Research Establishment, Ganakbari, Savar, Dhaka 1349, Bangladesh
Saswata Rabi
Department of Chemistry, Faculty of Engineering & Technology, Chittagong University of Engineering & Technology, Chattogram 4349, Bangladesh
Lira Barua
Department of Chemistry, Faculty of Science, University of Chittagong, Chattogram 4331, Bangladesh
M. Nasir Uddin
Department of Chemistry, Faculty of Science, University of Chittagong, Chattogram 4331, Bangladesh
M. Imtiaz Morshed
Department of Chemistry, Faculty of Science, University of Chittagong, Chattogram 4331, Bangladesh
Ismail M.M. Rahman
Institute of Environmental Radioactivity, Fukushima University, 1 Kanayagawa, Fukushima City, Fukushima 960-1296, Japan
Tapashi Ghosh Roy
Department of Chemistry, Faculty of Science, University of Chittagong, Chattogram 4331, Bangladesh

Corresponding Author(s) : Ismail M.M. Rahman

immrahman@ipc.fukushima-u.ac.jp

Asian Journal of Chemistry, Vol. 35 No. 2 (2023): Vol 35 Issue 2, 2023

Abstract

Octamethyl tetraazamacrocycle, Me8[14]diene·2HClO4 and its three isomeric ligands (LA, LB and LC) were synthesized and characterized using analytical and spectroscopic data, and the antibacterial activities were evaluated against selected bacteria and yeast. Interaction of LC with excess acrylonitrile resulted in an N-pendent derivative (LCX). Square planar nickel(II) diperchlorate complex of LC, [NiLCα](ClO4)2, underwent axial addition reactions with KI and NaNO2 to yield six coordinated octahedral species, [NiLCαI2]·2H2O and [NiLCα(NO2)(ClO4)]. Five coordinated square pyramidal Ni(II) complexes, [NiLCXCl](ClO4), [NiLCX(NCS)](NO3) and [NiLCXI](NO3), were synthesized from Ni(II) salts and tetraazamacrocyclic ligand LCX. Among the complexes, [NiLCXCl](ClO4) was synthesized through the direct interaction of NiCl2 with LCX, followed by the subsequent addition of NaClO4·6H2O. On the other hand, [NiLCX(NCS)](NO3) and [NiLCXI](NO3) as well as octahedral [NiLCXBr2] and [NiLCX(NO2)(NO3)] were synthesized by the interaction of LCX with different Ni(II) salts.

Keywords

Azamacrocyclic ligands N-Pendent derivative Ni(II) complexes Spectroscopic studies Antibacterial activities
Amin, R., Rabi, S., Barua, L., Nasir Uddin, M., Imtiaz Morshed, M., M.M. Rahman, I., & Ghosh Roy, T. (2023). Nickel(II) Complexes of Octamethyl Tetraazamacrocycle and its N-Pendent Derivative: Syntheses, Characterization, Electrolytic Behaviour and Antimicrobial Activities. Asian Journal of Chemistry, 35(2), 447–454. https://doi.org/10.14233/ajchem.2023.26929
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