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Photocatalytic Degradation Study of Rhodamine-B by Green Synthesized Nano TiO2
Asian Journal of Chemistry,
Vol. 29 No. 1 (2017): Vol 29 Issue 1
Abstract
In present investigation, TiO2 nano particles synthesized by green route using titanium isopropoxide precursor and Azardica indica leaf extract were used for the photocatalytic degradation of Rhodamine-B. The green synthesized nano TiO2 were characterized by X-ray diffraction spectroscopy, particle size distribution, Fourier transform infrared and scanning electron microscopy. Photocatalytic degradation was conducted in batch experiments, wherein the effect of process parameters such as photo catalyst concentration, pH and contact time on dye degradation rate under UV irradiation was studied. The extent of degradation was quantized by measuring the absorbance of samples by UV-visible spectrophotometer. The nano TiO2 synthesized showed the effective degradation of Rhodamine-B. The degradation kinetics was also studied.
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- C. Galindo, P. Jacques and A. Kalt, Chemosphere, 45, 997 (2001).
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References
C. Galindo, P. Jacques and A. Kalt, Chemosphere, 45, 997 (2001).
Y.C. Wong, Y.S. Szeto, W.H. Cheung and G. McKay, Langmuir, 19, 7888 (2003).
C.A.K. Gouvea, F. Wypych, S.G. Moraes, N. Duran, N. Nagata and P. Peralta-Zamora, Chemosphere, 40, 433 (2000).
C. Domínguez, J. García, M.A. Pedraz, A. Torres and M.A. Galán, Catal. Today, 40, 85 (1998).
S. Pattapu, S. Saha, S. Jana and A. Pal, Novel Resin Bound MnO2 Nanocomposite for the Degradation of Crystal Violet Dye in Aqueous Medium, World J. Engineering International Conference on Composite/Nano Engineering (ICCE-16), Kunming, China (2012).
K. Yu, S. Yang, H. He, C. Sun, C. Gu and Y. Ju, J. Phys. Chem. A, 113, 10024 (2009).
P. Mukherjee, A. Ahmad, D. Mandal, S. Senapati, S.R. Sainkar, M.I. Khan, R. Ramani, R. Parischa, P.V. Ajayakumar, M. Alam, M. Sastry and R. Kumar, Angew. Chem. Int. Ed. Engl., 40, 3585 (2001).
A.K. Jha, K. Prasad and A.R. Kulkarni, Colloids Surf. B, 71, 226 (2009).
S.S. Shankar, A. Rai, A. Ahmad and M. Sastry, J. Colloid Interface Sci., 275, 496 (2004).
S.S. Gowri, Chalcogenide Lett., 8, 447 (2011).
K. Velayutham, A.A. Rahuman, G. Rajakumar, T. Santhoshkumar, S. Marimuthu, C. Jayaseelan, A. Bagavan, A.V. Kirthi, C. Kamaraj, A.A. Zahir and G. Elango, Parasitol. Res., 111, 2329 (2012).
M. Hudlikar, S. Joglekar, M. Dhaygude and K. Kodam, Mater. Lett., 75, 196 (2012).
S.M. Roopan, A. Bharathi, A. Prabhakarn, A.A. Rahuman, K. Velayutham, G. Rajakumar, R.D. Padmaja, M. Lekshmi and G. Madhumitha, Spectrochim. Acta A Mol. Biomol. Spectrosc., 98, 86 (2012).
Y. Ma and J.N. Yao, J. Photochem. Photobiol. Chem., 116, 167 (1998).
Y. Ma and J.N. Yao, Chemosphere, 38, 2407 (1999).
Y. Ma, J.B. Qiu, Y.A. Cao, Z.S. Guan and J.N. Yao, Chemosphere, 44, 1087 (2001).
J.M. Wu and T.W. Zhang, J. Photochem. Photobiol. Chem., 162, 171 (2004).
R.W. Matthews, Water Res., 25, 1169 (1991).
M. Asiltürk, F. Sayilkan, S. Erdemoglu, M. Akarsu, H. Sayilkan, M. Erdemoglu and E. Arpac, J. Hazard. Mater., 129, 164 (2006).
P. Wilhelm and D. Stephan, J. Photochem. Photobiol. Chem., 185, 19 (2007).
D.S. Kim and Y.S. Park, Chem. Eng. J., 116, 133 (2006).