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Vol. 35 No. 2 (2023): Vol 35 Issue 2, 2023

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Silk Protein Hydrolysate for Corrosion Mitigation of Mild Steel in 1 N H2SO4

https://doi.org/10.14233/ajchem.2023.26879
V. Nijarubini
Department of Chemistry, PSG College of Arts and Science, Coimbatore-641014, India
J. Mallika
Department of Chemistry, PSG College of Arts and Science, Coimbatore-641014, India
M. Mantharasalan
Department of Chemistry, PSG College of Arts and Science, Coimbatore-641014, India

Corresponding Author(s) : J. Mallika

mallika@psgcas.ac.in

Asian Journal of Chemistry, Vol. 35 No. 2 (2023): Vol 35 Issue 2, 2023

Abstract

In view as corrosion inhibitor, silk protein hydrolysate (SPH), a water-soluble hydrolysate obtained from silk protein (biopolymer) exhibits excellent protection to mild steel in 1 N H2SO4, especially at low concentration levels. Weight loss analysis propose a maximum efficiency for 10 ppm SPH at 303 K. Potentiodynamic polarization measurement revealed its functioning as a mixed-type inhibitor with enhanced polarization resistance. The best fits observed with Langmuir isotherm suggested the inhibitor-metal interaction to occur via physisorption mechanism. Surface examination through SEM (EDXS), water contact angle, AFM, FT-IR and Raman spectroscopy confirmed the formation of protective film.

Keywords

Silk protein hydrolysate Corrosion Mild steel Physisorption Protective film
Nijarubini, V., Mallika, J., & Mantharasalan, M. (2023). Silk Protein Hydrolysate for Corrosion Mitigation of Mild Steel in 1 N H2SO4. Asian Journal of Chemistry, 35(2), 352–360. https://doi.org/10.14233/ajchem.2023.26879
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