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Vol. 35 No. 1 (2023): Vol 35 Issue 1

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Enhancement in Activity and Reusability of Dry Amberlyst-15 Catalyst by Thermal Treatment for Production of Biodiesel from Karanja Oil

https://doi.org/10.14233/ajchem.2023.24026
Arun Kumar Gupta
Department of Chemical Engineering, University Institute of Engineering and Technology, C.S.J.M. University, Kanpur-208024, India
Goutam Deo
Department of Chemical Engineering, University Institute of Engineering and Technology, C.S.J.M. University, Kanpur-208024, India

Corresponding Author(s) : Arun Kumar Gupta

arunkgupta@csjmu.ac.in

Asian Journal of Chemistry, Vol. 35 No. 1 (2023): Vol 35 Issue 1

Abstract

The effect of preheating Amberlyst-15 catalyst used for the biodiesel production reaction of Karanja oil was studied. The preheated Amberlyst-15 samples were characterized for their surface area and pore volume and by SEM, TGA and FTIR spectroscopy. A preheat temperature of 473 K was found to optimum. At this temperature, the surface area had increased and the sulfonic acid groups of Amberlyst-15 were retained. At 473 K preheated Amberlyst-15 gradually deactivated with reuse from a biodiesel yield of 85% to 27% in four runs at a reaction temperature of 393 K and methanol to oil ratio of 60:1. For the power-law model, the reaction order was 0.65, the rate constant at 373 K was 0.027 h-1 and activation energy was 86.98 kJ/mol.

Keywords

Biodiesel Karanja oil Amberlyst-15 Reusability Kinetic parameter
Kumar Gupta, A., & Deo, G. (2022). Enhancement in Activity and Reusability of Dry Amberlyst-15 Catalyst by Thermal Treatment for Production of Biodiesel from Karanja Oil. Asian Journal of Chemistry, 35(1), 62–68. https://doi.org/10.14233/ajchem.2023.24026
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