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Vol. 35 No. 1 (2023): Vol 35 Issue 1

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Electrochemical Investigations on the NO-Releasing Property of Ruthenium Nitrosyl Complex

https://doi.org/10.14233/ajchem.2023.24047
Lyka B. Dela Rosa
Department of Chemistry, Mindanao State University-Iligan Institute of Technology, Iligan City, Lanao del Norte, 9200 Philippines
Joel H. Jorolan
Department of Chemistry, Mindanao State University-Iligan Institute of Technology, Iligan City, Lanao del Norte, 9200 Philippines

Corresponding Author(s) : Joel H. Jorolan

joel.jorolan@g.msuiit.edu.ph

Asian Journal of Chemistry, Vol. 35 No. 1 (2023): Vol 35 Issue 1

Abstract

In this study, the NO-donating property of [Ru(BPG)Cl(NO)]Cl (BPG = N,N-bis(2-pyridylmethyl)glycinato anion) via electrochemical activation was assessed. The synthesized BPG and [Ru(BPG)Cl(NO)]Cl were characterized by UV-Vis and FT-IR spectroscopy. To determine if NO may be released from the compound via one-electron reduction, cyclic voltammetric experiments in aqueous and non-aqueous solutions were performed using a three-electrode cell consisting of glassy carbon working electrode, Pt wire counter electrode and Ag/AgCl or Ag/Ag+ reference electrode. The [Ru(BPG)Cl(NO)]Cl complex showed two one-electron reversible reductions in dimethylformamide, which suggests decreased ability as NO donor. In aqueous solution at pH 2.0, [Ru(BPG)Cl(NO)]Cl exhibited a one-electron irreversible reduction, which could be assigned to a Ru-NO centered reduction. The irreversibility of the reduction could be due to NO labilization and suggests that [Ru(BPG)Cl(NO)]Cl could be a potential NO donor in acidic aqueous medium.

Keywords

Ruthenium nitrosyl NO donor Electrochemical analysis
B. Dela Rosa, L., & H. Jorolan, J. (2022). Electrochemical Investigations on the NO-Releasing Property of Ruthenium Nitrosyl Complex. Asian Journal of Chemistry, 35(1), 52–56. https://doi.org/10.14233/ajchem.2023.24047
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