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Vol. 34 No. 12 (2022): Vol 34 Issue 12, 2022

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Binary Mixture of t(3)-Methyl-r(2),c(6)-diphenyl-piperidin-4-one and Gum Exudates of Astragalus genus as an Green Soldier for Dissolution Control of Mild Steel in HCl

https://doi.org/10.14233/ajchem.2022.23983
T. Brindha
Department of Science and Humanities, Faculty of Engineering, Karpagam Academy of Higher Education (Deemed to be University), Coimbatore-641021, India
R. Rathinam
Department of Science and Humanities, Sri Eshwar College of Engineering, Coimbatore-641202, India
S. Dheenadhayalan
Department of Chemistry, Erode Sengunthar Engineering College, Erode-638057, India
S. Supriya
Department of Chemistry, Jansons Institute of Technology, Coimbatore-641659, India
S. Madhankumar
Department of Chemistry, Erode Sengunthar Engineering College, Erode-638057, India

Corresponding Author(s) : S. Dheenadhayalan

vsdheena@gmail.com

Asian Journal of Chemistry, Vol. 34 No. 12 (2022): Vol 34 Issue 12, 2022

Abstract

The corrosion inhibitive behaviour of t(3)-Methyl-r(2),c(6)-diphenyl-piperidin-4-one (3MDPP) and gum exudates of Astragalus genus (GTP) on mild steel in 1 N HCl were studied using weight loss measurements for 1 h immersion period at 303-323 K. The corrosion rate of mild steel directly varies with temperature whereas it varies inversely with concentration. The synergistic influence of different concentrations of GTP on 3MDPP was analyzed at 303-323 K using weight loss technique. The icorr, Ecorr, Rct and Cdl values were obtained for 3MDPP, GTP and the mixture of GTP and 3MDPP (binary mixture). The calculated values of Ea, ΔH*, ΔS* and ΔG°ads suggests the physical adsorption mechanism and it obeys Langmuir isotherm. The synergistic influence of GTP on 3MDPP is clear from the synergistic parameter value (> 1).

Keywords

Mild steel Astragalus genus Gum Binary mixture Synergism t(3)-Methyl-r(2),c(6)-diphenyl-piperidin-4-one
Brindha, T., Rathinam, R., Dheenadhayalan, S., Supriya, S., & Madhankumar, S. (2022). Binary Mixture of t(3)-Methyl-r(2),c(6)-diphenyl-piperidin-4-one and Gum Exudates of Astragalus genus as an Green Soldier for Dissolution Control of Mild Steel in HCl. Asian Journal of Chemistry, 34(12), 3320–3326. https://doi.org/10.14233/ajchem.2022.23983
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References
  1. Y. Xu, Y. Xu, Y. Zhang, Y. Shu, H. Song, X. Shu, Y. Ma, L. Hao, X. Zhang, X. Ren, Z. Wang and X. Zhang, ACS Omega, 7, 13826 (2022); https://doi.org/10.1021/acsomega.2c00121
  2. C. Verma, E.E. Ebenso, M.A. Quraishi and C.M. Hussain, Mater. Adv., 2, 3806 (2021); https://doi.org/10.1039/D0MA00681E
  3. A.I. Muñoz, J. García-Antón, J.L. Guiñón and V. Pérez-Herranz, Electrochim. Acta, 50, 957 (2004); https://doi.org/10.1016/j.electacta.2004.07.048
  4. P.B. Raja, M. Ismail, S. Ghoreishiamiri, J. Mirza, M.C. Ismail, S. Kakooei and A.A. Rahim, Chem. Eng. Commun., 203, 1145 (2016); https://doi.org/10.1080/00986445.2016.1172485
  5. S.K. Ahmed, W.B. Ali and A.A. Khadom, Int. J. Indus. Chem., 10, 159 (2019); https://doi.org/10.1007/s40090-019-0181-8
  6. K. Parameswari, S. Rekha, S. Chitra and E. Kayalvizhy, Port. Electrochim. Acta, 28, 189 (2010); https://doi.org/10.4152/pea.201003189
  7. A.C. Bastos, M.G. Ferreira and A.M. Simões, Corros. Sci., 48, 1500 (2006); https://doi.org/10.1016/j.corsci.2005.05.021
  8. S.A. Umoren, I.B. Obot, E.E. Ebenso and N. Obi-Egbedi, Desalination, 247, 561 (2009); https://doi.org/10.1016/j.desal.2008.09.005
  9. H.-M. Yang, Molecules, 26, 3473 (2021); https://doi.org/10.3390/molecules26113473
  10. L.T. Popoola, Corros. Rev., 37, 71 (2019); https://doi.org/10.1515/corrrev-2018-0058
  11. S.A. Umorena, I.B. Obota, E.E. Ebenso and N. Obi-Egbedi, Port. Electrochim. Acta, 26, 199 (2008); https://doi.org/10.4152/pea.200802199
  12. S. Marzorati, L. Verotta and S.P. Trasatti, Molecules, 24, 48 (2019); https://doi.org/10.3390/molecules24010048
  13. S.A. Umoren and U.M. Eduok, Carbohydr. Polym., 140, 314 (2016); https://doi.org/10.1016/j.carbpol.2015.12.038
  14. M.B. Balasubramanian and N. Padma, Tetrahedron, 19, 2135 (1963); https://doi.org/10.1016/0040-4020(63)85028-0
  15. C.R. Noller and V. Baliah, J. Am. Chem. Soc., 70, 3853 (1948); https://doi.org/10.1021/ja01191a092
  16. ASTM Practice Standard G-31, Standard Practice for Laboratory Immersion Corrosion Testing of Metals, ASTM International (2004).
  17. S. Muralidharan, R. Chandrasekar and S.V.K. Iyer, Proc. Indian Acad. Sci., 112, 127 (2000); https://doi.org/10.1007/BF02704314
  18. A.N. Senthilkumar, K. Tharini and M.G. Sethuraman, J. Mater. Eng. Perform., 20, 969 (2011); https://doi.org/10.1007/s11665-010-9719-9
  19. S. Sankarapapavinasam, F. Pushpanaden and M.F. Ahmed, Corros. Sci., 32, 193 (1991); https://doi.org/10.1016/0010-938X(91)90043-O
  20. A.N. Senthilkumar, K. Tharini and M.G. Sethuraman, Surf. Rev. Lett., 16, 141 (2009); https://doi.org/10.1142/S0218625X09012408
  21. K. Selvaraj, M. Narasimhan and J. Mallika, Transition Met. Chem., 26, 224 (2001); https://doi.org/10.1023/A:1007144601982
  22. S.A. Umoren, Y. Li and F.H. Wang, Corros. Sci., 52, 1777 (2010); https://doi.org/10.1016/j.corsci.2010.01.026
  23. A.M. Ridhwan, A.A. Rahim and A.M. Shah, Int. J. Electrochem. Sci., 7, 8091 (2012).
  24. Q. Hu, Y. Qiu, G. Zhang and X. Guo, Open Mater. Sci. J., 8, 31 (2014); https://doi.org/10.2174/1874088X01408010031
  25. G. Tharial Xavier, B. Thirumalairaj and M. Jaganathan, Int. J. Corros., 2015, 410120 (2015); https://doi.org/10.1155/2015/410120
  26. B. Thirumalairaj and M. Jaganathan, Egypt. J. Petrol., 25, 423 (2016); https://doi.org/10.1016/j.ejpe.2015.09.002
  27. K. Aramaki, M. Hagiwara and H. Nishihara, Corros. Sci., 27, 487 (1987); https://doi.org/10.1016/0010-938X(87)90092-8
  28. M. Mobin and S. Masoor, Int. J. Electrochem. Sci., 7, 6920 (2012).
  29. S.A. Umoren, Port. Electrochem. Acta, 27, 565 (2009); https://doi.org/10.4152/pea.20090556
  30. N.O. Eddy and E.E. Ebenso, Afr. J. Pure Appl. Chem., 2, 46 (2008).
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