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Vol. 34 No. 12 (2022): Vol 34 Issue 12, 2022

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Synthesis of Molecularly Imprinted Polymer Nanoparticles for Removal of Sudan III Dye

https://doi.org/10.14233/ajchem.2022.24052
Showkat Ahmad Bhawani
Faculty of Resource Science and Technology, Universiti Malaysia Sarawak (UNIMAS), Kuching 94300, Malaysia
Nur'Izzah Binti Juarah
Faculty of Resource Science and Technology, Universiti Malaysia Sarawak (UNIMAS), Kuching 94300, Malaysia
Salma Bakhtiar
Faculty of Resource Science and Technology, Universiti Malaysia Sarawak (UNIMAS), Kuching 94300, Malaysia
Rachel Marcella Rol
1Faculty of Resource Science and Technology, Universiti Malaysia Sarawak (UNIMAS), Kuching 94300, Malaysia 2School of Chemical Sciences, Universiti Sains Malaysia, 11800 Gelugor, Penang, Malaysia 3Department of Chemistry, College of Science, King Saud University, Riyadh-11451, Kingdom of Saudi Arabia 4Department of Chemistry, Gandhi Faiz-E-Aam College, Shahjahanpur-242001, India *Corresponding author: E-mail: sabhawani@gmail.com
Mohamad Nasir Mohamad Ibrahim
School of Chemical Sciences, Universiti Sains Malaysia, 11800 Gelugor, Penang, Malaysia
Khalid Mohammed Alotaibi
Department of Chemistry, College of Science, King Saud University, Riyadh-11451, Kingdom of Saudi Arabia
Abdul Moheman
Department of Chemistry, Gandhi Faiz-E-Aam College, Shahjahanpur-242001, India

Corresponding Author(s) : Showkat Ahmad Bhawani

sabhawani@gmail.com

Asian Journal of Chemistry, Vol. 34 No. 12 (2022): Vol 34 Issue 12, 2022

Abstract

Molecularly imprinted polymer (MIP) nanoparticles of Sudan III dye as template were synthesized by using non-covalent approach. The molecularly imprinted polymers were synthesized in a microemulsion contained Sudan III as a template, acrylic acid (AA) as a monomer, 1,4-butanediol dimethacrylate as a cross-linker and 2,2-azo-bisisobutyronitrile (AIBN) as an initiator. The synthesized beads were characterized by TEM and FTIR. The TEM results revealed the nanosize beads of polymers were produced. The efficiency of imprinted and non-imprinted polymers was evaluated by batch binding studies. The results showed that the MIP 3 (0.1: 6: 10, Sudan III: AA: 1,4-butanediol dimethacrylate) was best among all polymers with highest rebinding efficiency. The removal efficiency of selected MIP 3 in the spiked Sudan III dye river water sample was about 80%. This study was conducted to produce nanosized molecularly imprinted polymers by using microemulsion polymerization technique.

Keywords

Sudan III Template Molecular imprinting polymer Emulsion polymerization
Ahmad Bhawani, S., Binti Juarah, N., Bakhtiar, S., Marcella Rol, R., Nasir Mohamad Ibrahim, M., Mohammed Alotaibi, K., & Moheman, A. (2022). Synthesis of Molecularly Imprinted Polymer Nanoparticles for Removal of Sudan III Dye. Asian Journal of Chemistry, 34(12), 3269–3274. https://doi.org/10.14233/ajchem.2022.24052
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