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Vol. 30 No. 8 (2018): Vol 30 Issue 8

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Ultrasonically Assisted Halogenation of Aromatic Compounds using Isoquinolinium Bound Hypervalent Chromium and Tetrabutylammonium Halides in PEG-600 Solutions under Acid Free and Solvent-Free Conditions

https://doi.org/10.14233/ajchem.2018.21413
A. Sambashiva Rao1
1Department of Chemistry, Rayalaseema University, Kurnool-518002, India 2Department of Chemistry, Maturi Venkata Subba Rao Engineering College, Hyderabad-501 510, India   3Department of Chemistry, Osmania University, Hyderabad-500 007, India   *Corresponding author: E-mail: kcrajannaou@yahoo.com
Kola Ramesh2
1Department of Chemistry, Rayalaseema University, Kurnool-518002, India 2Department of Chemistry, Maturi Venkata Subba Rao Engineering College, Hyderabad-501 510, India   3Department of Chemistry, Osmania University, Hyderabad-500 007, India   *Corresponding author: E-mail: kcrajannaou@yahoo.com
K.C. Rajanna3
1Department of Chemistry, Rayalaseema University, Kurnool-518002, India 2Department of Chemistry, Maturi Venkata Subba Rao Engineering College, Hyderabad-501 510, India   3Department of Chemistry, Osmania University, Hyderabad-500 007, India   *Corresponding author: E-mail: kcrajannaou@yahoo.com
I. Chakrvarthi1 
1Department of Chemistry, Rayalaseema University, Kurnool-518002, India 2Department of Chemistry, Maturi Venkata Subba Rao Engineering College, Hyderabad-501 510, India   3Department of Chemistry, Osmania University, Hyderabad-500 007, India   *Corresponding author: E-mail: kcrajannaou@yahoo.com

Asian Journal of Chemistry, Vol. 30 No. 8 (2018): Vol 30 Issue 8

Abstract

Isoquinolinium bound Cr(VI) reagents like isoquinolinium dichromate (IQDC) and isoquinolinium chlorochromate (IQCC) have been successfully accomplished as efficient reagents for oxidative halogenation of aromatic compounds using tetrabutylammonium halide (TBAX) as halogenating agents in aqueous polyethylene glycol (PEG-600) under acid free conditions. Tetrabutylammonium bromide (TBAB) has been used for bromination and tetrabutylammonium iodide (TBAI) for iodination. The halogenation reactions that occurred smoothly in 2 to 7 h under conventional conditions are accelerated magnificently under sonication with few minutes (25 to 70 min) of reaction time and fairly good yields. The reactions occurred at moderate temperature under mild and environmentally safe conditions with simple work up.

Keywords

Isoquinolinium dichromate Isoquinolinium chlorochromate Bromination Tetrabutylammonium iodide PEG-600.
Sambashiva Rao1, A., Ramesh2, K., Rajanna3, K., & Chakrvarthi1 , I. (2018). Ultrasonically Assisted Halogenation of Aromatic Compounds using Isoquinolinium Bound Hypervalent Chromium and Tetrabutylammonium Halides in PEG-600 Solutions under Acid Free and Solvent-Free Conditions. Asian Journal of Chemistry, 30(8), 1892–1896. https://doi.org/10.14233/ajchem.2018.21413
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