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Vol. 34 No. 12 (2022): Vol 34 Issue 12, 2022

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Synthesis of Ternary CaNiAl-Layered Double Hydroxide as Potential Adsorbent for Congo Red Dye Removal in Aqueous Solution

https://doi.org/10.14233/ajchem.2022.23977
Deepmoni Brahma
Department of Chemistry, Bodoland University, Kokrajhar-783370, India
Kasturi Priyom Nath
Department of Chemistry, Bodoland University, Kokrajhar-783370, India
Madhusmita Patgiri
Department of Chemistry, Bodoland University, Kokrajhar-783370, India
Hemaprobha Saikia
Department of Chemistry, Bodoland University, Kokrajhar-783370, India

Corresponding Author(s) : Hemaprobha Saikia

saikiahemaprobha@gmail.com

Asian Journal of Chemistry, Vol. 34 No. 12 (2022): Vol 34 Issue 12, 2022

Abstract

A hierarchically porous ternary CaNiAl-LDH material was synthesized via a facile urea hydrolysis method and characterized by PXRD, FT-IR, BET, SEM and TGA techniques. The adsorption efficiency of synthesized ternary CaNiAl-layered double hydroxide was also examined using Congo red dye as a model pollutant. Material characteristics affirmed with the formation of circular and flower-like LDH particles with accessible mesopores of 3.85 nm and intermediate surface area of 58.45 m2/g. The synthesized ternary CaNiAl-LDH material exhibited the maximum adsorption capacity of 135.21 mg/g towards the targeted organic pollutant from an aqueous medium. The obtained results in isotherm and kinetic studies demonstrated that sorption of Congo red dye onto CaNiAl-LDH followed Langmuir isotherm and pseudo-second order model, respectively. In addition, the thermodynamic studies also suggested the endothermic and spontaneity of the sorption process. The reusability studies confirmed that CaNiAl-LDH can be reused up to fourth cycle. Therefore, the proposed material CaNiAl-LDH can be advocated as a highly effective low cost adsorbent for the treatment of water contaminants.

Keywords

Layered double hydroxide Congo red dye Adsorption Intercalation
Brahma, D., Priyom Nath, K., Patgiri, M., & Saikia, H. (2022). Synthesis of Ternary CaNiAl-Layered Double Hydroxide as Potential Adsorbent for Congo Red Dye Removal in Aqueous Solution. Asian Journal of Chemistry, 34(12), 3215–3223. https://doi.org/10.14233/ajchem.2022.23977
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