Copyright (c) 2018 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Synergistic Influence of Halide Ions on Corrosion Inhibition Performance of Gum Exudates of Azadirachta indica on Carbon Steel in Sulphuric Acid Medium
Asian Journal of Chemistry,
Vol. 30 No. 8 (2018): Vol 30 Issue 8
Abstract
The effect of halide ions on the inhibitive performance of gum exudates of Azadirachta indica on carbon steel in 1 N sulphuric acid medium was investigated using chemical and electrochemical methods. Effect of temperature and immersion period on mitigation performance was studied. The inhibition efficiency of gum exudates of Azadirachta indica considerably increased with the presence of halide ions at all temperature ranges studied. Synergistic influence of halide ions on gum exudates of Azadirachta indica for carbon steel corrosion was reported. Adsorption of gum exudates of Azadirachta indica as well as the inhibitor mixtures are spontaneous and the process followed Langmuir adsorption isotherm. SEM studies supported the adsorption phenomenon.
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- S.A. Umoren, Cellulose, 15, 751 (2008); https://doi.org/10.1007/s10570-008-9226-4.
- A. Jano, A. Lame and E. Kokalari, Kem. Ind.., 61, 497 (2012).
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- N.O. Eddy, S.E. Abechi, P. Ameh and E.E. Ebenso, Walailak J. Sci. Technol., 10, 247 (2013).
- S.A. Umoren, I.B. Obot, E.E. Ebenso and N.O. Obi-Egbedi, Desalination, 247, 561 (2009); https://doi.org/10.1016/j.desal.2008.09.005.
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- P.O. Ameh, L. Magaji and T. Salihu, Afr. J. Pure Appl. Chem., 6, 100 (2012).
- O.A. Paul, Int. J. Phys. Sci., 9, 184 (2014); https://doi.org/10.5897/IJPS2014.4116.
- N.O. Eddy, P.O. Ameh and A.O. Odiongenyi, Port. Electrochim. Acta, 32, 183 (2014); https://doi.org/10.4152/pea.201403183.
- P.O. Ameh, A.O. Odiongenyi and N.O. Eddy, Port. Electrochim. Acta, 30, 235 (2012); https://doi.org/10.4152/pea.201204235.
- P.O. Ameh and N.O. Eddy, Res. Chem. Intermed., 40, 2641 (2014); https://doi.org/10.1007/s11164-013-1117-0.
- N.O. Eddy, P.O. Ameh and E.E. Ebenso, Int. J. Electrochem. Sci., 7, 5677 (2012).
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- N.O. Eddy, P.O. Ameh, O.O. Anduang and V. Emaikwu, Int. J. Chem. Mater. Environ. Res., 1, 3 (2014).
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- S.A. Umoren and U.F. Ekanem, Chem. Eng. Commun., 197, 1339 (2010); https://doi.org/10.1080/00986441003626086.
- I.B. Obot, N.O. Obi-Egbedi and S.A. Umoren, Corros. Sci., 51, 276 (2009); https://doi.org/10.1016/j.corsci.2008.11.013.
- G.N. Mu, X.M. Li and F. Li, Mater. Chem. Phys., 86, 59 (2004); https://doi.org/10.1016/j.matchemphys.2004.01.041.
- X. Li, S. Deng, H. Fu and G. Mu, Corros. Sci., 52, 1167 (2010); https://doi.org/10.1016/j.corsci.2009.12.017.
- S.A. Umoren, O. Ogbobe, I.O. Igwe and E.E. Ebenso, Corros. Sci., 50, 1998 (2008); https://doi.org/10.1016/j.corsci.2008.04.015.
- A.G. Maitra Singh and B.B. Chakraborty, Trans. Soc. Adv. Electrochem. Sci. Technol., 18, 335 (1983).
- A.I. Onuchukwu, S.P. Trasatti and S. Trasatti, Corros. Sci., 36, 1815 (1994); https://doi.org/10.1016/0010-938X(94)90020-5.
- S.A. Umoren, Y. Li and F.H. Wang, Corros. Sci., 52, 2422 (2010); https://doi.org/10.1016/j.corsci.2010.03.021.
- D.Q. Zhang, L.X. Gao and G.D. Zhou, J. Appl. Electrochem., 33, 361 (2003); https://doi.org/10.1023/A:1024403314993.
- A.Y. Musa, A.B. Mohamad, A.A.H. Kadhum, M.S. Takriff and L.T. Tien, Corros. Sci., 53, 3672 (2011); https://doi.org/10.1016/j.corsci.2011.07.010.
- D. Jayaperumal, Mater. Chem. Phys., 119, 478 (2010); https://doi.org/10.1016/j.matchemphys.2009.09.028.
- E.S. Ferreira, C. Giacomelli, F.C. Giacomelli and A. Spinelli, Mater. Chem. Phys., 83, 129 (2004); https://doi.org/10.1016/j.matchemphys.2003.09.020.
- N. Goudarzi, M. Peikari, M.R. Zahiri and H.R. Mousavi, Arch. Metall. Mater., 57, 845 (2012); https://doi.org/10.2478/v10172-012-0044-1.
- G.T. Xavier, B. Thirumalairaj and M. Jaganathan, Int. J. Corros., Article ID 410120 (2015); https://doi.org/10.1155/2015/410120.
- S.T. Arab and A.M. Al-Turkustani, Port. Electrochim. Acta, 24, 53 (2006); https://doi.org/10.4152/pea.200601053.
- I. Ahamad, R. Prasad and M.A. Quraishi, Corros. Sci., 52, 1472 (2010); https://doi.org/10.1016/j.corsci.2010.01.015.
References
D. Dwivedi, K. Lepkova and T. Becker, RSC Adv., 7, 4580 (2017); https://doi.org/10.1039/C6RA25094G.
S.A. Umoren, Cellulose, 15, 751 (2008); https://doi.org/10.1007/s10570-008-9226-4.
A. Jano, A. Lame and E. Kokalari, Kem. Ind.., 61, 497 (2012).
M. Abdallah, Port. Electrochim. Acta, 22, 161 (2004); https://doi.org/10.4152/pea.200402161.
N.O. Eddy, S.E. Abechi, P. Ameh and E.E. Ebenso, Walailak J. Sci. Technol., 10, 247 (2013).
S.A. Umoren, I.B. Obot, E.E. Ebenso and N.O. Obi-Egbedi, Desalination, 247, 561 (2009); https://doi.org/10.1016/j.desal.2008.09.005.
S.A. Umorena, I.B. Obota, E.E. Ebensob and N. Obi-Egbedi, Port. Electrochim. Acta, 26, 199 (2008); https://doi.org/10.4152/pea.200802199.
P.O. Ameh, L. Magaji and T. Salihu, Afr. J. Pure Appl. Chem., 6, 100 (2012).
O.A. Paul, Int. J. Phys. Sci., 9, 184 (2014); https://doi.org/10.5897/IJPS2014.4116.
N.O. Eddy, P.O. Ameh and A.O. Odiongenyi, Port. Electrochim. Acta, 32, 183 (2014); https://doi.org/10.4152/pea.201403183.
P.O. Ameh, A.O. Odiongenyi and N.O. Eddy, Port. Electrochim. Acta, 30, 235 (2012); https://doi.org/10.4152/pea.201204235.
P.O. Ameh and N.O. Eddy, Res. Chem. Intermed., 40, 2641 (2014); https://doi.org/10.1007/s11164-013-1117-0.
N.O. Eddy, P.O. Ameh and E.E. Ebenso, Int. J. Electrochem. Sci., 7, 5677 (2012).
N.O. Eddy, P.O. Ameh, M.Y. Gwarzo, I.J. Okop and S.N. Dodo, Port. Electrochim. Acta, 31, 79 (2013); https://doi.org/10.4152/pea.201302079.
N.O. Eddy, U.J. Ibok, P.O. Ameh, N.O. Alobi and M.M. Sambo, Chem. Eng. Commun., 201, 1360 (2014); https://doi.org/10.1080/00986445.2013.809000.
P.O. Ameh, Int. J. Modern Chem., 2, 28 (2012).
N.O. Eddy, P.O. Ameh, O.O. Anduang and V. Emaikwu, Int. J. Chem. Mater. Environ. Res., 1, 3 (2014).
N.O. Eddy, P.O. Ameh, O.O. Anduang and E.E. Ebenso, Int. J. Electrochem. Sci., 7, 7425 (2012).
Q. Qu, Z. Hao, S. Jiang, L. Li and W. Bai, Mater. Corros., 59, 883 (2008); https://doi.org/10.1002/maco.200804176.
N.O. Eddy, S.A. Odoemelam and A.O. Odiongenyi, J. Appl. Electrochem., 39, 849 (2009); https://doi.org/10.1007/s10800-008-9731-z.
S.A. Umoren, M.M. Solomon, I.I. Udosoro and A.P. Udoh, Cellulose, 17, 635 (2010); https://doi.org/10.1007/s10570-010-9409-7.
M. Manickam, D. Sivakumar, B. Thirumalairaj and M. Jaganathan, Adv. Phys. Chem., Article ID 5987528 (2016); https://doi.org/10.1155/2016/5987528.
S. Mukherjee and H.C. Srivastava, J. Am. Chem. Soc., 77, 422 (1955); https://doi.org/10.1021/ja01607a059.
D.M.W. Anderson and A. Hendrie, Carbohydr. Res., 20, 259 (1971); https://doi.org/10.1016/S0008-6215(00)81379-8.
ASTM Practice Standard G-31, Standard Practice for Laboratory Immersion Corrosion Testing of Metals, ASTM International (2004).
K.O. Orubite and N.C. Oforka, J. Mater. Lett., 58, 1768 (2004); https://doi.org/10.1016/j.matlet.2003.11.030.
A.Y. El-Etre, J. Appl. Surf. Sci., 252, 8521 (2006); https://doi.org/10.1016/j.apsusc.2005.11.066.
E.E. Mola, Electrochim. Acta, 26, 1209 (1981); https://doi.org/10.1016/0013-4686(81)85101-8.
M. Dahmani, A. Et-Touhami, S.S. Al-Deyab, B. Hammouti and A. Bouyanzer, Int. J. Electrochem. Sci., 5, 1060 (2010).
V. Ramesh Saliyan and A.V. Adhikari, Bull. Mater. Sci., 31, 699 (2007); https://doi.org/10.1007/s12034-008-0111-4.
L. Bammou, M. Belkhaouda, R. Salghi, O. Benali, A. Zarrouk, H. Zarrok and B. Hammouti, J. Assoc. Arab. Univ. Basic Appl. Sci., 16, 83 (2014); https://doi.org/10.1016/j.jaubas.2013.11.001.
M. Lebrini, F. Robert and C. Roos, Int. J. Electrochem. Sci., 5, 1698 (2010).
S.A. Ali, M.T. Saeed and S.U. Rahman, Corros. Sci., 45, 253 (2003); https://doi.org/10.1016/S0010-938X(02)00099-9.
E.E. Ebenso, Mater. Chem. Phys., 79, 58 (2003); https://doi.org/10.1016/S0254-0584(02)00446-7.
S.A. Umoren and U.F. Ekanem, Chem. Eng. Commun., 197, 1339 (2010); https://doi.org/10.1080/00986441003626086.
I.B. Obot, N.O. Obi-Egbedi and S.A. Umoren, Corros. Sci., 51, 276 (2009); https://doi.org/10.1016/j.corsci.2008.11.013.
G.N. Mu, X.M. Li and F. Li, Mater. Chem. Phys., 86, 59 (2004); https://doi.org/10.1016/j.matchemphys.2004.01.041.
X. Li, S. Deng, H. Fu and G. Mu, Corros. Sci., 52, 1167 (2010); https://doi.org/10.1016/j.corsci.2009.12.017.
S.A. Umoren, O. Ogbobe, I.O. Igwe and E.E. Ebenso, Corros. Sci., 50, 1998 (2008); https://doi.org/10.1016/j.corsci.2008.04.015.
A.G. Maitra Singh and B.B. Chakraborty, Trans. Soc. Adv. Electrochem. Sci. Technol., 18, 335 (1983).
A.I. Onuchukwu, S.P. Trasatti and S. Trasatti, Corros. Sci., 36, 1815 (1994); https://doi.org/10.1016/0010-938X(94)90020-5.
S.A. Umoren, Y. Li and F.H. Wang, Corros. Sci., 52, 2422 (2010); https://doi.org/10.1016/j.corsci.2010.03.021.
D.Q. Zhang, L.X. Gao and G.D. Zhou, J. Appl. Electrochem., 33, 361 (2003); https://doi.org/10.1023/A:1024403314993.
A.Y. Musa, A.B. Mohamad, A.A.H. Kadhum, M.S. Takriff and L.T. Tien, Corros. Sci., 53, 3672 (2011); https://doi.org/10.1016/j.corsci.2011.07.010.
D. Jayaperumal, Mater. Chem. Phys., 119, 478 (2010); https://doi.org/10.1016/j.matchemphys.2009.09.028.
E.S. Ferreira, C. Giacomelli, F.C. Giacomelli and A. Spinelli, Mater. Chem. Phys., 83, 129 (2004); https://doi.org/10.1016/j.matchemphys.2003.09.020.
N. Goudarzi, M. Peikari, M.R. Zahiri and H.R. Mousavi, Arch. Metall. Mater., 57, 845 (2012); https://doi.org/10.2478/v10172-012-0044-1.
G.T. Xavier, B. Thirumalairaj and M. Jaganathan, Int. J. Corros., Article ID 410120 (2015); https://doi.org/10.1155/2015/410120.
S.T. Arab and A.M. Al-Turkustani, Port. Electrochim. Acta, 24, 53 (2006); https://doi.org/10.4152/pea.200601053.
I. Ahamad, R. Prasad and M.A. Quraishi, Corros. Sci., 52, 1472 (2010); https://doi.org/10.1016/j.corsci.2010.01.015.