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Vol. 34 No. 11 (2022): Vol 34 Issue 11, 2022

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Synthesis and Structure of Polymeric Copper(I) Compound with Single-Stranded Dihelicate Units involving Multiring Nitrogen-Heterocyclic Ligand

https://doi.org/10.14233/ajchem.2022.23988
Tirtha Pada Majhi
Department of Chemistry, Bidhannagar College, EB-2, Sector-I, Salt Lake, Kolkata-700064, India
Nabanita Kundu
Department of Chemistry, Lady Brabourne College, P-1/2, Suhrawardy Avenue, Kolkata-700017, India

Corresponding Author(s) : Nabanita Kundu

nabanita.kundu@ladybrabourne.com

Asian Journal of Chemistry, Vol. 34 No. 11 (2022): Vol 34 Issue 11, 2022

Abstract

The polymeric copper(I) complex [Cu2(L)I2] (1) containing a new biologically relevant heterocyclic bis-bidentate ligand viz. 3,3′-dipyridine-2-yl-[1.1′]bi[imidazo[1,5-a]pyridineyl] (L) was synthesized and characterized by single-crystal X-ray diffraction analysis. The molecule lacks molecular center of symmetry where coordination environments around both Cu(1) and Cu(2) are distorted tetrahedral (Cu···Cu# separation of 3.5 Å). Compound in its solid-state structure shows π-π non-covalent interactions as well as Carene-H---anion non-classical hydrogen bonding interactions that play dominant roles in shaping the extended structure of the molecule.

Keywords

Polymeric complex Dihelicate units N-Heterocyclic ligand Non-covalent interactions Hydrogen bonding
Pada Majhi, T., & Kundu, N. (2022). Synthesis and Structure of Polymeric Copper(I) Compound with Single-Stranded Dihelicate Units involving Multiring Nitrogen-Heterocyclic Ligand. Asian Journal of Chemistry, 34(11), 2965–2968. https://doi.org/10.14233/ajchem.2022.23988
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