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Kinetic Modeling of Peroxydisulfate Pre-Treatment of Algae Slurry (Pasir Gudang, Malaysia) for Increasing Methane Generation from Anaerobic Digestion: Fertilizer Recovery
Corresponding Author(s) : Md. Nurul Islam Siddique
Asian Journal of Chemistry,
Vol. 34 No. 10 (2022): Vol 34 Issue 10, 2022
Abstract
This study looked into the possibility of using peroxydisulfate pretreatment to enhance biogas production from anaerobic fermentation of algal slurry. The results demonstrate that a peroxydisulfate added system with a dose of 0.02 g peroxydisulfate/g algal sludge TSS produces the most accumulative methane after 61 days of fermentation. At 0.02, 0.03, 0.06, 0.2, 0.3, 0.6, and 1.2 g peroxydisulfate/g algal sludge TSS cumulative methane generation was 1.16, 1.09, 1.15, 1.14, 1.09, 0.77, and 0.16 times higher than control. After 120 minutes of pre-treatment, the SCOD in the system continued to rise when the peroxydisulfate dosage was enhanced. To simulate the methane yield, a one-substrate model might be utilized. After dosing with peroxydisulfate, the hydrolysis rate reduced, and the maximum resultant and anticipated cumulative methane output was achieved with 0.02 g peroxydisulfate/g algal sludge TSS. After digestion, microcystin-LR in algae slurry was mostly eliminated. Heavy metals could be released from algae cells into the effluent as a result of the greater peroxydisulfate dosage. From the fermented effluent, sludge recapture was 0.09 m3 sludge/m3. The supplementation of peroxydisulfate to algae slurry may boost cumulative methane generation while also lowering microcystin-LR levels.
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A.J. Ward, D.M. Lewis and F.B. Green, Algal Res., 5, 204 (2014); https://doi.org/10.1016/j.algal.2014.02.001
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M.N.I. Siddique and Z.A. Wahid, Water Environ. Res., 90, 835 (2018); https://doi.org/10.2175/106143017X15131012153031
S. Bleakley and M. Hayes, Foods, 6, 33 (2017); https://doi.org/10.3390/foods6050033
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T. Garoma and R.E. Yazdi, BMC Plant Biol., 19, 18 (2019);https://doi.org/10.1186/s12870-018-1614-9
Z.B. Khalid, M.N.I. Siddique, A. Nayeem, T.M. Adyel, S.B. Ismail and M.Z. Ibrahim, J. Environ. Chem. Eng., 9, 105489 (2021); https://doi.org/10.1016/j.jece.2021.105489
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