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Vol. 34 No. 9 (2022): Vol 34 Issue 9

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Rhodium(III) and Platinum(II) Complexes of Azamacrocycle: Synthesis, Characterization and Antimicrobial Evaluation

https://doi.org/10.14233/ajchem.2022.23893
Saswata Rabi
Department of Chemistry, Faculty of Engineering & Technology, Chittagong University of Engineering & Technology, Chattogram 4349, Bangladesh
Pradip Paul
Department of Chemistry, Jashore University of Science and Technology, Jashore Sadar 7408, Bangladesh
Saroj K.S. Hazari
Department of Chemistry, Faculty of Science, University of Chittagong, Chattogram 4331, Bangladesh
Benu K. Dey
Department of Chemistry, Faculty of Science, University of Chittagong, Chattogram 4331, Bangladesh
Debashis Palit
Department of Chemistry, Faculty of Science, University of Chittagong, Chattogram 4331, Bangladesh
Ismail M.M. Rahman
Institute of Environmental Radioactivity, Fukushima University, 1 Kanayagawa, Fukushima City, Fukushima 960-1296, Japan
Tapashi G. Roy
Department of Chemistry, Faculty of Science, University of Chittagong, Chattogram 4331, Bangladesh

Corresponding Author(s) : Ismail M.M. Rahman

immrahman@ipc.fukushima-u.ac.jp

Asian Journal of Chemistry, Vol. 34 No. 9 (2022): Vol 34 Issue 9

Abstract

A dihydroperchlorate salt of octamethyl derivative of 14-membered tetraazamacrocycle, Me8[14]diene·2HClO4 (L·2HClO4), was formed by the condensation of 1,2-diamino propane with acetone in the presence of a quantitative amount of perchloric acid, which on extraction with chloroform at pH above 12 yielded free ligand (L). The interaction of rhodium(III) trichloride trihydrate and platinum(II) chloride with free ligand L produced six-coordinated octahedral orange-red complex, cis-[RhLCl2]Cl and four-coordinated square-planar yellow complex, [PtL]Cl2, respectively. Axial substitution reactions on [RhLCl2]Cl with KX (X = NO3, Br or I) and NaNO2 afforded six-coordinated deep brown products [RhLY2]Y (Y= NO3, Br, I or NO2). The ligand and metal complexes were characterized based on analytical, molar conductivity, spectroscopic and magnetochemical data. The antimicrobial activities of the concerned ligand and its complexes have been explored against some selected bacteria and fungi.

Keywords

Tetraazamacrocycle Metal complexes Axial substitution reactions Antimicrobial activities
Rabi, S., Paul, P., K.S. Hazari, S., K. Dey, B., Palit, D., M.M. Rahman, I., & G. Roy, T. (2022). Rhodium(III) and Platinum(II) Complexes of Azamacrocycle: Synthesis, Characterization and Antimicrobial Evaluation. Asian Journal of Chemistry, 34(9), 2444–2450. https://doi.org/10.14233/ajchem.2022.23893
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