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Vol. 34 No. 9 (2022): Vol 34 Issue 9

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Coumarinyl(thienyl)thiazole Molecules as Fluorescent Photoswitches

https://doi.org/10.14233/ajchem.2022.23829
Mahesh Kondaparthi
Department of Chemistry, University College of Science, Osmania University, Hyderabad-500007, India
D. Annapurna Padmavathi
Department of Chemistry, University College of Science, Osmania University, Hyderabad-500007, India

Corresponding Author(s) : D. Annapurna Padmavathi

dapadmasai@gmail.com

Asian Journal of Chemistry, Vol. 34 No. 9 (2022): Vol 34 Issue 9

Abstract

Light sensitive coumarinyl(thienyl)thiazole derivatives exhibiting photochromism and fluorescence were synthesized, characterized and their behavior was investigated theoretically using density functional theory (DFT). In presence of UV light, the molecules switch to the bridged cyclic isomeric form and on irradiation with visible light, they revert back to their original molecular form. These molecules are sensitive to both UV and visible light, and switch themselves between open ring isomers and closed ring isomers. The photo-regulated-switching energy (ΔE) from open to closed isomeric form is approximately 6.3 kcal/mol. All the synthesized derivatives exhibit fluorescence only in their open form. Theoretical data is compared with the experimental data and both show similar results.

Keywords

Coumarinyl(thienyl)thiazoles Fluorescence Photochromism Density functional theory
Kondaparthi, M., & Annapurna Padmavathi, D. (2022). Coumarinyl(thienyl)thiazole Molecules as Fluorescent Photoswitches. Asian Journal of Chemistry, 34(9), 2281–2287. https://doi.org/10.14233/ajchem.2022.23829
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