Copyright (c) 2022 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Production of Biodiesel from Soybean Oil in Less Time and at Low Temperature
Corresponding Author(s) : Sasikumar Swamiappan
Asian Journal of Chemistry,
Vol. 34 No. 8 (2022): Vol 34 Issue 8, 2022
Abstract
The heterogeneous catalyst plays an important role in the production of biodiesel at industrial level. In present work, the utilization of wollastonite as a heterogeneous catalyst is attempted to explore its non-biomedical application. Wollastonite was synthesized by using the auto combustion method and L-alanine was used as a fuel for combustion. The X-ray diffraction pattern reveals the phase purity of wollastonite. The Fourier transform infrared spectra of the calcined precursor show the presence of characteristics functional groups in wollastonite. To evaluate the catalytic ability of the prepared wollastonite, transesterification reaction of soybean oil with methanol was performed. Following the reaction, the biodiesel, glycerol and the catalyst were separated by centrifugation. Optimization of the percentage of catalyst used in biodiesel production was done by using various quantities of catalyst during the transesterification reaction and subjecting the produced biodiesel to gas chromatography. It can be concluded that combined alkali metal oxide and silica in wollastonite has assisted in production of biodiesel (82.6%) in a less time and at a low temperature.
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- F. Storti, M.A.L. Nobre and S. Lanfredi, Mater. Sci. Forum, 912, 207 (2018); https://doi.org/10.4028/www.scientific.net/MSF.912.207
References
M. Ghiaci, B. Aghabarari and A. Gil, Fuel, 90, 3382 (2011); https://doi.org/10.1016/j.fuel.2011.04.008
A. Ghaderi, J. Petrol. Sci. Eng., 98-99, 19 (2012); https://doi.org/10.1016/j.petrol.2012.08.016
A.P.S. Chouhan and A.K. Sarma, Renew. Sustain. Energy Rev., 15, 4378 (2011); https://doi.org/10.1016/j.rser.2011.07.112
N. Tippayawong, A. Promwungkwa and P. Rerkkriangkrai, Iran. J. Sci. Technol. Tran. B, 34, 167 (2010).
J.X. Wang, K.T. Chen, J.S. Wu, P.H. Wang, S.T. Huang and C.C. Chen, Fuel Process. Technol., 104, 167 (2012); https://doi.org/10.1016/j.fuproc.2012.05.009
M. Kouzu and J. Hidaka, Fuel, 93, 1 (2012); https://doi.org/10.1016/j.fuel.2011.09.015
J. Otera, Chem. Rev., 93, 1449 (1993); https://doi.org/10.1021/cr00020a004
J.M. Marchetti and A.F. Errazu, Biomass Bioener., 32, 892 (2008); https://doi.org/10.1016/j.biombioe.2008.01.001
B. Freedman, R.O. Butterfield and E.H. Pryde, J. Am. Oil Chem. Soc., 63, 1375 (1986); https://doi.org/10.1007/BF02679606
J. Schmidt, D. Reusch, K. Elgeti and R. Schomacker, Chem. Ingen. Tech., 71, 704 (1999); https://doi.org/10.1002/cite.330710711
S. Gryglewicz, Appl. Catal. A Gen., 192, 23 (2000); https://doi.org/10.1016/S0926-860X(99)00337-3
A. Corma, S. Iborra, S. Miquel and J. Primo, J. Catal., 173, 315 (1998); https://doi.org/10.1006/jcat.1997.1930
K.G. Georgogianni, A.P. Katsoulidis, P.J. Pomonis and M.G. Kontominas, Fuel Process. Technol., 90, 671 (2009); https://doi.org/10.1016/j.fuproc.2008.12.004
S. Semwal, A.K. Arora, R.P. Badoni and D.K. Tuli, Bioresour. Technol., 102, 2151 (2011); https://doi.org/10.1016/j.biortech.2010.10.080
J. Ji, J. Wang, Y. Li, Y. Yu and Z. Xu, Ultrasonics, 44, 411 (2006); https://doi.org/10.1016/j.ultras.2006.05.020
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M. Zabeti, W.M.A. Wan Daud and M.K. Aroua, Fuel Process. Technol., 90, 770 (2009); https://doi.org/10.1016/j.fuproc.2009.03.010
J.S. Lee and S. Saka, Bioresour. Technol., 101, 7191 (2010); https://doi.org/10.1016/j.biortech.2010.04.071
A.K. Sarma, J.K. Sarmah, L. Barbora, P. Kalita, S. Chatterjee, P. Mahanta and P. Goswami, Recent Pat. Eng., 2, 47 (2008); https://doi.org/10.2174/187221208783478552
J.M. Marchetti and A.F. Errazu, Fuel, 87, 3477 (2008); https://doi.org/10.1016/j.fuel.2008.05.011
A. West, D. Posarac and N. Ellis, Bioresour. Technol., 99, 6587 (2008); https://doi.org/10.1016/j.biortech.2007.11.046
T. Sakai, A. Kawashima and T. Koshikawa, Bioresour. Technol., 100, 3268 (2009); https://doi.org/10.1016/j.biortech.2009.02.010
Y.M. Park, S. Chung, H.J. Eom, K. Lee and K.-Y. Lee, Bioresour. Technol., 101, 6589 (2010); https://doi.org/10.1016/j.biortech.2010.03.109
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R.A. Holser, K.M. Doll and S.Z. Erhan, Fuel, 85, 393 (2006); https://doi.org/10.1016/j.fuel.2005.07.018
S. Baroutian, M.K. Aroua, A.A.A. Raman and N.M.N. Sulaiman, Fuel Process. Technol., 91, 1378 (2010); https://doi.org/10.1016/j.fuproc.2010.05.009
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W. Xie, H. Peng and L. Chen, J. Mol. Catal. Chem., 246, 24 (2006); https://doi.org/10.1016/j.molcata.2005.10.008
D. Fabbri, V. Bevoni, M. Notari and F. Rivetti, Fuel, 86, 690 (2007); https://doi.org/10.1016/j.fuel.2006.09.003
G. Arzamendi, I. Campo, E. Arguiñarena, M. Sánchez, M. Montes and L.M. Gandía, Chem. Eng. J., 134, 123 (2007); https://doi.org/10.1016/j.cej.2007.03.049
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D.J. Vujicic, D. Comic, A. Zarubica, R. Micic and G. Boskovic, Fuel, 89, 2054 (2010); https://doi.org/10.1016/j.fuel.2009.11.043
S.J. Yoo, H. Lee, B. Veriansyah, J. Kim, J.-D. Kim and Y.-W. Lee, Bioresour. Technol., 101, 8686 (2010); https://doi.org/10.1016/j.biortech.2010.06.073
A. Sutka and G. Mezinskis, Front. Mater. Sci., 6, 128 (2012); https://doi.org/10.1007/s11706-012-0167-3
R. Choudhary, S.K. Venkatraman, I. Bulygina, F. Senatov, S. Kaloshkin, N. Anisimova, M. Kiselevskiy, M. Knyazeva, D. Kukui, F. Walther and S. Swamiappan, Mater. Sci. Eng. C, 118, 111456 (2021); https://doi.org/10.1016/j.msec.2020.111456
X. Liu, H. He, Y. Wang, S. Zhu and X. Piao, Fuel, 87, 216 (2008); https://doi.org/10.1016/j.fuel.2007.04.013
M. Kouzu, T. Kasuno, M. Tajika, S. Yamanaka and J. Hidaka, Appl. Catal. A Gen., 334, 357 (2008); https://doi.org/10.1016/j.apcata.2007.10.023
X. Liang, S. Gao, H. Wu and J. Yang, Fuel Process. Technol., 90, 701 (2009); https://doi.org/10.1016/j.fuproc.2008.12.012
C. Samart, P. Sreetongkittikul and C. Sookman, Fuel Process. Technol., 90, 922 (2009); https://doi.org/10.1016/j.fuproc.2009.03.017
E.A. Faria, H.F. Ramalho, J.S. Marques, P.A.Z. Suarez and A.G.S. Prado, Appl. Catal. A Gen., 338, 72 (2008); https://doi.org/10.1016/j.apcata.2007.12.021
D. Celante, J.V.D. Schenkel and F. de Castilhos, Fuel, 212, 101 (2018); https://doi.org/10.1016/j.fuel.2017.10.040
F. Storti, M.A.L. Nobre and S. Lanfredi, Mater. Sci. Forum, 912, 207 (2018); https://doi.org/10.4028/www.scientific.net/MSF.912.207