Issue

Vol. 34 No. 8 (2022): Vol 34 Issue 8, 2022

Copyright (c) 2022 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Zinc Complex of Cyclododecanone Thiosemicarbazone as Single Source Precursor for ZnS Nanoparticles by Polyol Method

https://doi.org/10.14233/ajchem.2022.23742
Jisha George
Department of Chemistry, University College, Thiruvananthapuram-695034, India
G. Rathika Nath
Department of Chemistry, University College, Thiruvananthapuram-695034, India
V.S. Lekha
Department of Chemistry, University College, Thiruvananthapuram-695034, India
K. Rajesh
Department of Chemistry, University College, Thiruvananthapuram-695034, India

Corresponding Author(s) : Jisha George

Asian Journal of Chemistry, Vol. 34 No. 8 (2022): Vol 34 Issue 8, 2022

Abstract

Zn(II) complex of a newly synthesized ligand cyclododecanone thiosemicarbazone (CDDTSC) have been synthesized and characterized by UV-visible spectroscopy, photoluminescence, X-ray diffraction, scanning electron microscopy, EDX and transmission electron microscopy studies. Thermal decomposition properties of the complex also were studied. The complex was subjected to thermal decomposition in a high boiling solvent glycerol to get zinc sulphide nanoparticles. Highly crystalline, mono-dispersed and well defined ZnS nanoparticles were obtained in good quantity, even in the absence of capping agents.

Keywords

Molecular precursors Cyclododecanone thiosemicarbazone Thiosemicarbazone Zinc sulphide nanoparticles
George, J., Rathika Nath, G., Lekha, V., & Rajesh, K. (2022). Zinc Complex of Cyclododecanone Thiosemicarbazone as Single Source Precursor for ZnS Nanoparticles by Polyol Method. Asian Journal of Chemistry, 34(8), 2055–2060. https://doi.org/10.14233/ajchem.2022.23742
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. T. Trindade, P. O’Brien and N.L. Pickett, Chem. Mater., 13, 3843 (2001); https://doi.org/10.1021/cm000843p
  2. S.K. Ghosh and T. Pal, Chem. Rev., 107, 4797 (2007); https://doi.org/10.1021/cr0680282
  3. M.V. Kovalenko, L. Manna, A. Cabot, Z. Hens, D.V. Talapin, C.R. Kagan, V.I. Klimov, A.L. Rogach, P. Reiss, D.J. Milliron, P. GuyotSionnnest, G. Konstantatos, W.J. Parak, T. Hyeon, B.A. Korgel, C.B. Murray and W. Heiss, ACS Nano, 9, 1012 (2015); https://doi.org/10.1021/nn506223h
  4. S.Z. Butler, S.M. Hollen, L. Cao, Y. Cui, J.A. Gupta, H.R. Gutiérrez, T.F. Heinz, S.S. Hong, J. Huang, A.F. Ismach, E. Johnston-Halperin, M. Kuno, V.V. Plashnitsa, R.D. Robinson, R.S. Ruoff, S. Salahuddin, J. Shan, L. Shi, M.G. Spencer, M. Terrones, W. Windl and J.E. Goldberger, ACS Nano, 7, 2898 (2013); https://doi.org/10.1021/nn400280c
  5. Z. Li, J. Zhang, J. Du, T. Mu, Z. Liu, J. Chen and B. Han, J. Appl. Polym. Sci., 94, 1643 (2004); https://doi.org/10.1002/app.21042
  6. J.G. Brennan, T. Siegrist, P.J. Carroll, S.M. Stuczynski, L.E. Brus and M.L. Steigerwald, J. Am. Chem. Soc., 111, 4141 (1989); https://doi.org/10.1021/ja00193a079
  7. C.I. Pearce, R.A.D. Pattrick and D.J. Vaughan, Rev. Mineral. Geochem., 61, 127 (2006); https://doi.org/10.2138/rmg.2006.61.3
  8. M.A. Malik, M. Afzaal and P. O’Brien, Chem. Rev., 110, 4417 (2010); https://doi.org/10.1021/cr900406f
  9. G. Kedarnath, Eds.: A.K. Tyagi and R.S. Ningthoujam, Synthesis of Advanced Inorganic Materials through Molecular Precursors, Handbook on Synthesis Strategies for Advanced Materials, Indian Institute of Metals Series. Springer, Singapore (2021).
  10. M. Grzelczak, J. Vermant, E.M. Furst and L.M. Liz-Marzán, ACS Nano, 4, 3591 (2010); https://doi.org/10.1021/nn100869j
  11. B. Dong, T. Zhou, H. Zhang and C.Y. Li, ACS Nano, 7, 5192 (2013); https://doi.org/10.1021/nn400925q
  12. K. Sooklal, B.S. Cullum, S.M. Angel and C.J. Murphy, J. Phys. Chem., 100, 4551 (1996); https://doi.org/10.1021/jp952377a
  13. C. Falcony, M. Garcia, A. Ortiz and J.C. Alonso, J. Appl. Phys., 72, 1525 (1992); https://doi.org/10.1063/1.351720
  14. W. Tang and D.C. Cameron, Thin Solid Films, 280, 221 (1996); https://doi.org/10.1016/0040-6090(95)08198-4
  15. R.K. Agarwal, L. Singh and D.K. Sharma, Bioinorg. Chem. Appl., 2006, 59509 (2006); https://doi.org/10.1155/BCA/2006/59509
  16. P. Rapheal, E. Manoj and M.R.P. Kurup, Polyhedron, 26, 5088 (2007); https://doi.org/10.1016/j.poly.2007.07.028
  17. A.S. Reddy, L.S. Krishna, H.K. Rashmi, P.U.M. Devi, Y. Sarala and A.V. Reddy, J. Appl. Pharm. Sci., 6, 107 (2016); https://doi.org/10.7324/JAPS.2016.601015
  18. D. Kovala-Demertzi, A. Papageorgiou, L. Papathanasis, A. Alexandratos, P. Dalezis, J.R. Miller and M.A. Demertzis, Eur. J. Med. Chem., 44, 1296 (2009); https://doi.org/10.1016/j.ejmech.2008.08.007
  19. R. Manikandan, P. Vijayan, P. Anitha, G. Prakash, P. Viswanathamurthi, R.J. Butcher, K. Velmurugan and R. Nandhakumar, Inorg. Chim. Acta, 421, 80 (2014); https://doi.org/10.1016/j.ica.2014.05.035
  20. M. Joseph, V. Suni, M.R. Prathapachandra Kurup, M. Nethaji, A. Kishore and S.G. Bhat, Polyhedron, 23, 3069 (2004); https://doi.org/10.1016/j.poly.2004.09.026
  21. S. Chandra and Y. Kumar, Proc. Indian Acad. Sci. Chem. Sci., 92, 249 (1983); https://doi.org/10.1007/BF02841242
  22. V.B. Rana, P.C. Jain, M.P. Swami and A.K. Srivastava, J. Inorg. Nucl. Chem., 37, 1826 (1975); https://doi.org/10.1016/0022-1902(75)80336-8
  23. M.J.M. Campbell, R. Grzeskowiak, R. Thomas and M. Goldstein, Spectrochim. Acta A, 32, 553 (1976); https://doi.org/10.1016/0584-8539(76)80116-X
  24. S. Chandra and M. Tyagi, J. Serb. Chem. Soc., 73, 727 (2008); https://doi.org/10.2298/JSC0807727C
  25. M.S. Hossain, M.A. Mannan and M. Kudrat-E -Zahan, Int. J. Chem. Stud., 4, 17 (2020).
  26. T. Xaba, B. W. Masinga and M.J. Moloto, Digest J. Nanomater. Biostruct., 11, 1231 (2016).
  27. B.S. Rao, B.R. Kumar, G.V. Chalapathi, V.R. Reddy and T.S. Rao, J. Nano- Electr. Phys., 3, 620 (2011).
  28. Z. Zhang, J. Wang, H. Yuan, Y. Gao, D. Liu, L. Song, Y. Xiang, X. Zhao, L. Liu, S. Luo, X. Dou, S. Mou, W. Zhou and S. Xie, J. Phys. Chem. B, 109, 18352 (2005); https://doi.org/10.1021/jp052199d
  29. A. Goudarzi, G.M. Aval, S.S. Park, M.C. Choi, R. Sahraei, M.H. Ullah, A. Avane and C.S. Ha, Chem. Mater., 21, 2375 (2009); https://doi.org/10.1021/cm803329w
  30. Q. Wu, H. Cao, S. Zhang, X. Zhang and D. Rabinovich, Inorg. Chem., 45, 7316 (2006); https://doi.org/10.1021/ic060936u
  31. S. Biswas, S. Kar, S. Santra, Y. Jompol, M. Arif and S.I. Khondaker, J. Phys. Chem. C, 113, 3617 (2009); https://doi.org/10.1021/jp810177a
  32. P.S. Nair, T. Radhakrishnan, N. Revaprasadu, G. Kolawole and P. O’Brien, J. Mater. Chem., 12, 2722 (2002); https://doi.org/10.1039/b202072f
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 0 Download : 0