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Vol. 34 No. 8 (2022): Vol 34 Issue 8, 2022

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Thermal Studies of Aqueous Free-base Porphyrin and Metalloporphyrins of Trivalent and Tetravalent Metal Ions

https://doi.org/10.14233/ajchem.2022.23736
S.D. Gokakakar
P.E.S.’s R.S.N. College of Arts and Science, Farmagudi, Ponda-403401, India
A.V. Salker
School of Chemical Sciences, Goa University, Goa-403206, India

Corresponding Author(s) : S.D. Gokakakar

sdgokakakar@gmail.com

Asian Journal of Chemistry, Vol. 34 No. 8 (2022): Vol 34 Issue 8, 2022

Abstract

The free-base porphyrin and metalloporphyrins of Fe (monomer), Fe (dimer) and Sn (tin) were synthesized and purified by dry column chromatography. Aqueous free-base porphyrin and metalloporphyrins were characterized by UV-visible spectroscopy, IR spectroscopy and high-resolution mass spectrometry. Further, these synthesized porphyrins were subjected to TG-DSC anlysis from room temperature to 800 ºC. It was observed that each porphyrin has a characteristic first decomposition temperature and their thermal stabilities varied from 360-432 ºC. Since, these aqueous porphyrins are highly hygroscopic in nature, their number of waters of crystallization were determined.

Keywords

Aqueous-porphyrins Differential scanning calorimetry Thermogravimetry Residue analysis Water of crystallization
Gokakakar, S., & Salker, A. (2022). Thermal Studies of Aqueous Free-base Porphyrin and Metalloporphyrins of Trivalent and Tetravalent Metal Ions. Asian Journal of Chemistry, 34(8), 2049–2054. https://doi.org/10.14233/ajchem.2022.23736
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