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Vol. 34 No. 8 (2022): Vol 34 Issue 8, 2022

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Externally Silylated RH-MCM-48 from Rice Husk Silica with Superparamagnetic Iron Oxide for Multifunctional Applications

https://doi.org/10.14233/ajchem.2022.23486
S. Suyanta
Department of Chemistry, Universitas Gadjah Mada, Yogyakarta, Indonesia
M. Mudasir
Department of Chemistry, Universitas Gadjah Mada, Yogyakarta, Indonesia
W. Nugroho
Department of Chemistry, Universitas Gadjah Mada, Yogyakarta, Indonesia
K. Fajariatri
Department of Chemistry, Universitas Gadjah Mada, Yogyakarta, Indonesia

Corresponding Author(s) : S. Suyanta

suyanta_mipa@ugm.ac.id

Asian Journal of Chemistry, Vol. 34 No. 8 (2022): Vol 34 Issue 8, 2022

Abstract

Rice husk silica has been used as a raw material for the sonochemical synthesis of MCM-48 (RH-MCM-48). Silylation on the outer surface of RH-MCM-48 using trimethylchlorosilane before removal of the template to prevent the formation of iron oxide in the outer of RH-MCM-48. The impregnation of Fe3+ into the externally silylated-RH-MCM-48 porous system was done by optimizing the concentration of Fe3+, contact time and temperature. The XRD pattern, N2 adsorption/desorption isotherms and TEM images showed that RH-MCM-48 has an ordered Ia3d cubic mesostructure with high specific surface area and narrow porous size distribution. FTIR spectra confirmed the successful implementation of external silylation. Moreover, DR-UV-vis spectra, EPR spectra and magnetization curve show that the impregnation of Fe3+ into the externally silylated-RH-MCM-48 pores produce a superparamagnetic iron oxide nanoparticles formed inside the pores and induces partial isomorphic substitution of Si4+ by Fe3+ on the wall pores.

Keywords

Iron oxide nanoparticles MCM-48 Silylation Impregnation Superparamagnetic Isomorphic substitution
Suyanta, S., Mudasir, M., Nugroho, W., & Fajariatri, K. (2022). Externally Silylated RH-MCM-48 from Rice Husk Silica with Superparamagnetic Iron Oxide for Multifunctional Applications. Asian Journal of Chemistry, 34(8), 1997–2007. https://doi.org/10.14233/ajchem.2022.23486
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