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Vol. 34 No. 6 (2022): Vol 34 Issue 6

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Catalytic Iodine and Morpholine as Reagent Combination for Hydration of Alkynes via Markovnikov Addition

https://doi.org/10.14233/ajchem.2022.23751
Elangbam Pinky Devi
Department of Chemistry, National Institute of Technology Manipur, Langol, Imphal-795004, India
Dhananjaya Kaldhi
Department of Chemistry, National Institute of Technology Manipur, Langol, Imphal-795004, India
Ragini Sengupta
Department of Chemistry, National Institute of Technology Manipur, Langol, Imphal-795004, India
Anupam Roy
Department of Chemistry, National Institute of Technology Manipur, Langol, Imphal-795004, India
Abhishek Sahoo
Department of Chemistry, National Institute of Technology Manipur, Langol, Imphal-795004, India
Indranil Saha
Department of Physics, Techno India University, Kolkata-700091, India
Chandi C. Malakar
Department of Chemistry, National Institute of Technology Manipur, Langol, Imphal-795004, India

Corresponding Author(s) : Chandi C. Malakar

chdeepm@gmail.com

Asian Journal of Chemistry, Vol. 34 No. 6 (2022): Vol 34 Issue 6

Abstract

This work describes the iodine-catalyzed N-methyl morpholine-promoted hydration of alkynes via Markovnikov type addition. The developed protocol provides a direct approach to synthesize methyl ketones under metal-free condition. A series of aromatic alkynes embedded with electron-donating and electron-withdrawing groups were well-investigated to give the corresponding products in good to high yields.

Keywords

Hydration Terminal alkynes Markovnikov addition Iodine-catalyzed Carbonyl compounds
Pinky Devi, E., Kaldhi, D., Sengupta, R., Roy, A., Sahoo, A., Saha, I., & C. Malakar, C. (2022). Catalytic Iodine and Morpholine as Reagent Combination for Hydration of Alkynes via Markovnikov Addition. Asian Journal of Chemistry, 34(6), 1592–1596. https://doi.org/10.14233/ajchem.2022.23751
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