Copyright (c) 2022 AJC
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Fabrication of Pyromellitic Acid Polymer Modified Electrochemical Sensor for the Determination of Tryptophan
Corresponding Author(s) : R. Rejithamol
Asian Journal of Chemistry,
Vol. 34 No. 6 (2022): Vol 34 Issue 6
Abstract
Herein reporting a sensitive electrochemical strategy for the quantification of tryptophan on indium tin oxide electrode with an electropolymerized pyromellitic acid. In all perspectives, the characteristic features of the developed electrode were consistent with the requirements of a sensor. The morphological and functional identification of the modified electrode were done by scanning electron microscopy and infrared spectroscopy. The proposed electrode material has long-term stability and is easy to handle for real-life sample analysis. The fabricated electrode has a linear range of 10 to 300 μM with a limit of detection of 1.15 μM. The calculated sensitivity of the electrode was 1.3 μM/μA/cm2.
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M. Yuqing, C. Jianrong and W. Xiaohua, Trends Biotechnol., 22, 227 (2004); https://doi.org/10.1016/j.tibtech.2004.03.004
P.S. Sharma, A. Pietrzyk-Le, F. D’Souza and W. Kutner, Anal. Bioanal. Chem., 402, 3177 (2012); https://doi.org/10.1007/s00216-011-5696-6
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T. Alizadeh and S. Amjadi, New J. Chem., 41, 4493 (2017); https://doi.org/10.1039/C6NJ04108F
Z. Peng, Z. Jiang, X. Huang and Y. Li, RSC Adv., 6, 13742 (2016); https://doi.org/10.1039/C5RA25251B
R.N. Goyal, S. Bishnoi, H. Chasta, M.A. Aziz and M. Oyama, Talanta, 85, 2626 (2011); https://doi.org/10.1016/j.talanta.2011.08.031
F. Zhao, X. Li, W. Xu, W. Zhang and X. Ying, Anal. Lett., 47, 1712 (2014); https://doi.org/10.1080/00032719.2014.880172
J.R. Martin, C.S. Mellor and F.C. Fraser, Clin. Genet., 47, 180 (1995); https://doi.org/10.1111/j.1399-0004.1995.tb03956.x
W. Snedden, C.S. Mellor and J.R. Martin, Clin. Chim. Acta, 131, 247 (1983); https://doi.org/10.1016/0009-8981(83)90094-3
Z. Li, H. Xu, D. Wu, J. Zhang, X. Liu, S. Gao and Y. Kong, A.C.S. Appl. Mater., 11, 2840 (2019); https://doi.org/10.1021/acsami.8b19399
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P. Deng, Z. Xu and Y. Feng, Mater. Sci. Eng. C, 35, 54 (2014); https://doi.org/10.1016/j.msec.2013.10.019
N.F. Atta, A. Galal and Y.M. Ahmed, J. Electrochem. Soc., 167, 027505 (2020); https://doi.org/10.1149/1945-7111/ab61e7
J. Gautam, M. Raj and R.N. Goyal, J. Electrochem. Soc., 167, 066504 (2020); https://doi.org/10.1149/1945-7111/ab7e88
M.R. Akhgar, M. Salari and H. Zamani, J. Solid State Electrochem., 15, 845 (2011); https://doi.org/10.1007/s10008-010-1158-x
R.P. Deo, N.S. Lawrence and J. Wang, Analyst, 129, 1076 (2004); https://doi.org/10.1039/B407418A
J.-G. Lin, S.-Q. Zang, Z.-F. Tian, Y.-Z. Li, Y.-Y. Xu, H.-Z. Zhu and Q.-J. Meng, CrystEngComm, 9, 915 (2007); https://doi.org/10.1039/b708389k
K. Biradha and M.J. Zaworotko, Cryst. Eng., 1, 67 (1998); https://doi.org/10.1016/S0025-5408(98)00036-1
Y.Y. Karabach, A.M. Kirillov, M. Haukka, M.N. Kopylovich and A.J.L. Pombeiro, J. Inorg. Biochem., 102, 1190 (2008); https://doi.org/10.1016/j.jinorgbio.2007.11.007
S. Manafi, S. Tazikeh and S. Joughehdoust, Mater. Sci. Pol., 35, 799 (2017); https://doi.org/10.1515/msp-2018-0008
M. Moradi-Haji Jafan, M.-R. Zamani-Meymian, R. Rahimi and M. Rabbani, J. Nanostruct. Chem., 4, 89 (2014); https://doi.org/10.1007/s40097-014-0089-y
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F. Li, Q. Zhang, D. Pan, M. Lin and Q. Kang, Ionics, 21, 1711 (2015); https://doi.org/10.1007/s11581-014-1312-z