Issue

Vol. 34 No. 6 (2022): Vol 34 Issue 6

Copyright (c) 2022 AJC

Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

Copper(II)-Nickel(II) Induced Cyanide Bridged 2D Heterometallic Coordination Polymer: Synthesis, X-ray Structure and Magnetic Study

https://doi.org/10.14233/ajchem.2022.23678
Habibar Chowdhury
Department of Chemistry, Kabi Nazrul College, Murarai, Birbhum-731219, India
Chandan Adhikary
Department of Education, The University of Burdwan, Golapbag, Burdwan-713104, India

Corresponding Author(s) : Chandan Adhikary

cadhikary@edu.buruniv.ac.in

Asian Journal of Chemistry, Vol. 34 No. 6 (2022): Vol 34 Issue 6

Abstract

One new two-dimensional heterometallic coordination polymer [Cu3Ni(L)2(CN)6]n (1) [L = 2-methylethylenediamine, CN– = cyanide ion] was synthesized and characterized by X-ray crystallography. Compound 1 crystallizes in the monoclinic C2/c space group. The single crystal X-ray structure of compound 1 indicated that it is a 2D coordination polymer with three copper(II) ion embedded with [Ni(CN)4]2- molecular ion in architecture through μ-CN/μ-NC bridges results heterometallic polymer. In compound 1, each Cu1 center with a CuN5 chromophore is encompassed by four N atoms of the two different bidentate amine (L) and one N atom of μ-NC ion, while both Cu2 and Cu3 centres are connected by three N atoms of μ-NC ions having CuN3 chromosphere and Ni1 are coordinated by three μ-CN and one terminal CN ions with NiC4 chromophore. Three copper centers and one nickel center are interlinked through μ-CN/μ-NC forming {-Cu1(L)2(μ-NC)Ni1(CN)(μ-CN)2Cu2(μ-NC)Cu3(μ-NC)-} unit to fabricate a 2D hetero metallic polymer. In the crystalline state of compound 1, each 2D polymer is further propagated through intermolecular N-H···N hydrogen bonds corroborant a supramolecular 2D network structure. Variable temperature magnetic susceptibility study displayed a weak antiferromagnetic spin coupling presumably due to the diamagnetic tetracyanonickellate bridging among the CuII ions.

Keywords

Heterometallic Coordination polymer Terminal cyanide Bridging cyanide X-ray structure Magnetic behaviour
Chowdhury, H., & Adhikary, C. (2022). Copper(II)-Nickel(II) Induced Cyanide Bridged 2D Heterometallic Coordination Polymer: Synthesis, X-ray Structure and Magnetic Study. Asian Journal of Chemistry, 34(6), 1472–1476. https://doi.org/10.14233/ajchem.2022.23678
Download Citation
Endnote/Zotero/Mendeley (RIS)
BibTeX
References
  1. M.J. Zaworotko, J. Am. Chem. Soc., 132, 7821 (2010); https://doi.org/10.1021/ja103305p
  2. B. Moulton and M.J. Zaworotko, Chem. Rev., 101, 1629 (2001); https://doi.org/10.1021/cr9900432
  3. J.S. Miller and M. Drillon, Magnetism: Molecules to Materials V, WileyVCH: Weinheim (2006).
  4. O.R. Evans and W. Lin, Acc. Chem. Res., 35, 511 (2002); https://doi.org/10.1021/ar0001012
  5. D.T. McQuade, A.E. Pullen and T.M. Swager, Chem. Rev., 100, 2537 (2000); https://doi.org/10.1021/cr9801014
  6. B. Cornils, W.A. Herrmann and R. Schlogl, Catalysis from A to Z: A Concise Encyclopedia, John Wiley & Sons: New York (2000).
  7. D. Demus, J.W. Goodby, G.W. Gray, H.-W. Spiess and V. Vill, eds., Handbbook of Liquid Crystals, Wiley-VCH: Weinheim (1998).
  8. J.R. Farraro and J.M. Williams, Introduction to Synthetic Electrical Conductors, Academic Press: New York (1987).
  9. S.T. Hyde, B. Ninham, S. Anderson, Z. Blum, T. Landh, K. Larsson and S. Liddin, The Language of Shape, Elsevier: Amsterdam (1997).
  10. P. Comba and T.W. Hambley, Molecular Modelling of Inorganic and Coordination Compounds, VCH: Weinheim, Ed.: 2 (2001).
  11. C. Janiak, J. Chem. Soc., Dalton Trans., 2781 (2003); https://doi.org/10.1039/b305705b
  12. O. Almarsson and M.J. Zaworotko, Chem. Commun., 1889 (2004); https://doi.org/10.1039/b402150a
  13. H.-B. Yang, K. Ghosh, Y. Zhao, B.H. Northrop, M.M. Lyndon, D.C. Muddiman, H.S. White and P.J. Stang, J. Am. Chem. Soc., 130, 839 (2008); https://doi.org/10.1021/ja710349j
  14. J.R. Sheats and P. Barbara, Acc. Chem. Res., 32, 191 (1999); https://doi.org/10.1021/ar990033n
  15. M. Zbiri, S. Saha, C. Adhikary, S. Chaudhuri, C. Daul and S. Koner, Inorg. Chim. Acta, 359, 1193 (2006); https://doi.org/10.1016/j.ica.2005.09.005
  16. P.A. Vigato and S. Tamburini, Coord. Chem. Rev., 252, 1871 (2008); https://doi.org/10.1016/j.ccr.2007.10.030
  17. M.S. El Fallah, E. Rentschler, A. Caneschi, R. Sessoli and D. Gatteschi, Angew. Chem. Int. Ed. Engl., 35, 1947 (1996); https://doi.org/10.1002/anie.199619471
  18. H. Miyasaka, H. Ieda, N. Re, R. Crescenzi and C. Floriani, Inorg. Chem., 37, 255 (1998); https://doi.org/10.1021/ic9709640
  19. M. Ohba, N. Usuki, N. Fukita and H. Okawa, Inorg. Chem., 37, 3349 (1998); https://doi.org/10.1021/ic9704748
  20. T. Lu, H. Xiang, C. Su, P. Cheng, Z. Mao and L. Ji, New J. Chem., 25, 216 (2001); https://doi.org/10.1039/b007406n
  21. R.J. Parker, L. Spiccia, S.R. Batten, J.D. Cashion and G.D. Fallon, Inorg. Chem., 40, 4696 (2001); https://doi.org/10.1021/ic001452f
  22. H. Chowdhury, C. Rizzoli and C. Adhikary, J. Coord. Chem., 74, 663 (2021); https://doi.org/10.1080/00958972.2020.1861445
  23. M. Ohba and H. Okawa, Coord. Chem. Rev., 198, 313 (2000); https://doi.org/10.1016/S0010-8545(00)00233-2
  24. S. Sen, S. Mitra, D.I. Hughes, G. Rosair and C. Desplanches, Polyhedron, 261, 740 (2007); https://doi.org/10.1016/j.poly.2006.12.015
  25. C. Adhikary and S. Koner, Coord. Chem. Rev., 254, 2933 (2010); https://doi.org/10.1016/j.ccr.2010.06.001
  26. S. Saha, D. Mal, S. Koner, A. Bhattacherjee, P. Gütlich, S. Mondal, M. Mukherjee and K.-I. Okamoto, Polyhedron, 23, 1811 (2004); https://doi.org/10.1016/j.poly.2004.04.007
  27. A. Escuer and G. Aromí, Eur. J. Inorg. Chem., 2006, 4721 (2006); https://doi.org/10.1002/ejic.200600552
  28. E.A. Boudreaux and L.N. Mulay, Theory and Applications of Molecular Paramagnetism, Wiley-Interscience: New York (1976).
  29. Bruker APEX2, (Version 2008.1-0), SAINT (Version 7.51A) and SADABS (Version 2007/4) Bruker AXS Inc: Madison, Wisconsin, USA (2008).
  30. A. Altomare, M.C. Burla, M. Camalli, G.L. Cascarano, C. Giacovazzo, A. Guagliardi, A.G.G. Moliterni, G. Polidori and R. Spagna, J. Appl. Cryst., 32, 115 (1999); https://doi.org/10.1107/S0021889898007717
  31. G.M. Sheldrick, ActaCryst., C71, 3 (2015); https://doi.org/10.1107/S2053229614024218
  32. E. Colacio, J.M. Dominguez-Vera, F. Lloret, J.M. Moreno Sanchez, R. Kivekas, A. Rodriguez and R. Sillanpaa, Inorg. Chem., 42, 4209 (2003); https://doi.org/10.1021/ic034155u
  33. K. Nakamoto, Infrared and Raman spectra of Inorganic and Coordination Compounds, Part A and B, Ed. 5: Wiley: New York (1997).
  34. S.S. Massoud, F.A. Mautner, R. Vicente and H.N. Sweeney, Inorg. Chim. Acta, 359, 1489 (2006); https://doi.org/10.1016/j.ica.2005.10.047
Read More
Author biographies is not available.
Download
PDF
Statistic
Read Counter : 1 Download : 1