Copyright (c) 2014 AJC
This work is licensed under a Creative Commons Attribution 4.0 International License.
Photocatalytic Oxidation of Carbofuran Pesticide Using Zinc Oxide
Corresponding Author(s) : A.M. Fadaei
Asian Journal of Chemistry,
Vol. 26 No. 8 (2014): Vol 26 Issue 8
Abstract
In recent years, the application of ultraviolet irradiation and zinc oxide (UV/ZnO) process water and wastewater treatment has gained removal activity of the persistence organic compounds. The degradation of carbofuran pesticide was investigated under ultraviolet irradiation and zinc oxide (UV/ZnO) process. Likewise, the effect of the operational parameters such as reaction volume, initial concentration of catalyst, initial carbofuran concentration, light intensity and pH were studied. In this study the (UV/ZnO) process at different initial concentrations (50-250 mg/L), 5 different initial pH and 5 different initial concentration of catalyst was investigated. Analyses were performed by gas chromatography mass spectroscopy. Results showed that the carbofuran initial concentration of 50 mg/L, ZnO concentration of 300 mg/L, pH of 8, light intensity of 125 watts and reaction volume of 150 mL, were the optimum condition for degradation of carbofuran by UV /ZnO system. This study demonstrated that carbofuran could be effectively degraded by ultrasonic irradiation.
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- F. Javier Benitez, J.L. Acero and F.J. Real, J. Hazard. Mater., 89, 51 (2002); doi:10.1016/S0304-3894(01)00300-4.
- B. Lopez-Alvarez, R.A. Torres-Palma and G. Peñuela, J. Hazard. Mater., 191, 196 (2011); doi:10.1016/j.jhazmat.2011.04.060.
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- M.H. Dehghani and A.M. Fadaei, Res. J. Chem. Environ., 16, 104 (2012).
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- M.A. Farajzadeh, S.E. Seyedi, M.S. Shalamzari and M. Bamorowat, J. Sep. Sci., 32, 3191 (2009); doi:10.1002/jssc.200900109.
- F. Mendez-Arriaga, S. Esplugas and J. Gimenez, Water Res., 42, 585 (2008); doi:10.1016/j.watres.2007.08.002.
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- P.R. Gogate and A.B. Pandit, Adv. Environ. Res., 8, 501 (2004); doi:10.1016/S1093-0191(03)00032-7.
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- N.A. Mir, A. Khan, M. Muneer and S. Vijayalakhsmi, Sci. Total Environ., 458–460, 388 (2013); doi:10.1016/j.scitotenv.2013.04.041.
- S. Pardeshi and A. Patil, J. Mol. Catal. Chem., 308, 32 (2009); doi:10.1016/j.molcata.2009.03.023.
- W. Bahnemann, M. Muneer and M.M. Haque, Catal. Today, 124, 133 (2007); doi:10.1016/j.cattod.2007.03.031.
- D. Robert and S. Malato, Sci. Total Environ., 291, 85 (2002); doi:10.1016/S0048-9697(01)01094-4.
- L. Davydov and P.G. Smirniotis, J. Catal., 191, 105 (2000); doi:10.1006/jcat.1999.2777.
- P.R. Shukla, S. Wang, H.M. Ang and M. Tadé, Sep. Purif. Technol., 70, 338 (2010); doi:10.1016/j.seppur.2009.10.018.
- V. Pareek, S. Chong, M. Tade and A. Adesina, Asia Pacific J. Chem. Eng., 3, 171 (2008); doi:10.1002/apj.129.
- C.H. Chiou, C.Y. Wu and R.S. Juang, Chem. Eng. J., 139, 322 (2008); doi:10.1016/j.cej.2007.08.002.
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F. Javier Benitez, J.L. Acero and F.J. Real, J. Hazard. Mater., 89, 51 (2002); doi:10.1016/S0304-3894(01)00300-4.
B. Lopez-Alvarez, R.A. Torres-Palma and G. Peñuela, J. Hazard. Mater., 191, 196 (2011); doi:10.1016/j.jhazmat.2011.04.060.
J.M. Salman, V.O. Njoku and B.H. Hameed, Chem. Eng. J., 173, 361 (2011); doi:10.1016/j.cej.2011.07.066.
A.M. Fadaei, M.H. Dehghani, A.R. Foroushani and M. Sadeghi, Asian J. Chem., 25, 7517 (2013); doi:10.14233/ajchem.2013.14971.
A.M. Fadaei, M. H. Dehghani, N. Rastkari, S. Nasseri, A.H. Mahvi and M. Shayeghi, E-J Chem., 9, 2015 (2012); doi:10.1155/2012/958750.
S. Ahmed, M. Rasul, R. Brown and M. Hashib, J. Environ. Manage., 92, 311 (2011); doi:10.1016/j.jenvman.2010.08.028.
H. Katsumata, T. Okada, S. Kaneco, T. Suzuki and K. Ohta, Ultrason. Sonochem., 17, 200 (2010); doi:10.1016/j.ultsonch.2009.06.011.
Q. Wang and A.T. Lemley, J. Hazard. Mater., 98, 241 (2003); doi:10.1016/S0304-3894(03)00007-4.
R. Doong and W. Chang, J. Photochem. Photobiol A., 107, 239 (1997); doi:10.1016/S1010-6030(96)04579-0.
M.H. Dehghani and A.M. Fadaei, Res. J. Chem. Environ., 16, 104 (2012).
J. Madhavan, P.S. Sathish Kumar, S. Anandan, F. Grieser and M. Ashok Kumar, J. Hazard. Mater., 177, 944 (2010); doi:10.1016/j.jhazmat.2010.01.009.
J. Senthilnathan and L. Philip, Chem. Eng. J., 172, 678 (2011); doi:10.1016/j.cej.2011.06.035.
C. Wu and K.G. Linden, Water Res., 42, 4780 (2008); doi:10.1016/j.watres.2008.08.023.
J. Fenoll, E. Ruiz, P. Hellín, P. Flores and S. Navarro, Chemosphere, 85, 1262 (2011); doi:10.1016/j.chemosphere.2011.07.022.
B. Pare, S.B. Jonnalagadda, H. Tomar, P. Singh and V.W. Bhagwat, Desalination, 232, 80 (2008); doi:10.1016/j.desal.2008.01.007.
M.A. Farajzadeh, S.E. Seyedi, M.S. Shalamzari and M. Bamorowat, J. Sep. Sci., 32, 3191 (2009); doi:10.1002/jssc.200900109.
F. Mendez-Arriaga, S. Esplugas and J. Gimenez, Water Res., 42, 585 (2008); doi:10.1016/j.watres.2007.08.002.
R. Comparelli, E. Fanizza, M.L. Curri, P.D. Cozzoli, G. Mascolo and A. Agostiano, Appl. Catal. B, 60, 1 (2005); doi:10.1016/j.apcatb.2005.02.013.
P.R. Gogate and A.B. Pandit, Adv. Environ. Res., 8, 501 (2004); doi:10.1016/S1093-0191(03)00032-7.
L. Wei, C. Shifu, Z. Wei and Z. Sujuan, J. Hazard. Mater., 164, 154 (2009); doi:10.1016/j.jhazmat.2008.07.140.
N.A. Mir, A. Khan, M. Muneer and S. Vijayalakhsmi, Sci. Total Environ., 458–460, 388 (2013); doi:10.1016/j.scitotenv.2013.04.041.
S. Pardeshi and A. Patil, J. Mol. Catal. Chem., 308, 32 (2009); doi:10.1016/j.molcata.2009.03.023.
W. Bahnemann, M. Muneer and M.M. Haque, Catal. Today, 124, 133 (2007); doi:10.1016/j.cattod.2007.03.031.
D. Robert and S. Malato, Sci. Total Environ., 291, 85 (2002); doi:10.1016/S0048-9697(01)01094-4.
L. Davydov and P.G. Smirniotis, J. Catal., 191, 105 (2000); doi:10.1006/jcat.1999.2777.
P.R. Shukla, S. Wang, H.M. Ang and M. Tadé, Sep. Purif. Technol., 70, 338 (2010); doi:10.1016/j.seppur.2009.10.018.
V. Pareek, S. Chong, M. Tade and A. Adesina, Asia Pacific J. Chem. Eng., 3, 171 (2008); doi:10.1002/apj.129.
C.H. Chiou, C.Y. Wu and R.S. Juang, Chem. Eng. J., 139, 322 (2008); doi:10.1016/j.cej.2007.08.002.