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Synthesis and Characterization of New Azo Ligand and Its Co(II), Cu(II), Zn(II) and Ni(II) Complexes
Corresponding Author(s) : Mehmet Tuncel
Asian Journal of Chemistry,
Vol. 26 No. 7 (2014): Vol 26 Issue 7
Abstract
This study describe the synthesis and characterization of new azo ligand, 5-hydroxy-4-(2,4-dihydroxyphenylazo)-2,7-naphthalene disulfonic acid disodium salt (L). The Cu(II), Zn(II), Ni(II) and Co(II) complexes of the azo ligand were prepared and characterized by infrared, UV-visible, 1H and 13C NMR spectra, atomic absorption spectroscopy, mass spectrometry, elemental analyses, thermogravimetric analysis, conductivity and magnetic measurements. The results suggest that the complexes have a 1:1 (metal:ligand) molar ratio, involving mononuclear azo ligand with an ONO donor set. Metal ion uptake studies were conducted with a batch technique. The results indicate that the azo ligand has high thermal stability and good metal extraction capacity.
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- F. Huang, Y. Wu, D. Gu and F. Gan, Dyes Pigments, 66, 77 (2005); doi:10.1016/j.dyepig.2004.08.013.
- N. Kabay, E. Erdem, E.Y. Kilincarslan and E.Y. Sari, Transition Met. Chem., 32, 1068 (2007); doi:10.1007/s11243-007-0283-6.
- G.A. Ibañez and G.M. Escandar, Polyhedron, 17, 4433 (1998); doi:10.1016/S0277-5387(98)00249-6.
- H. Zollinger, Colour Chemistry, Wiley-VCH: Weinheim, edn 3, p. 544 (2003).
- G.G. Mohamed and M.A.M. Gad-Elkareem, Spectrochim. Acta A, 68, 1382 (2007); doi:10.1016/j.saa.2007.01.034.
- J.Y. Park, Y. Hirata and K. Hamada, Dyes Pigments, 95, 502 (2012); doi:10.1016/j.dyepig.2012.04.019.
- R.N. Sah and P.H. Brown, Microchem. J., 56, 285 (1997); doi:10.1006/mchj.1997.1428.
- S. Motomizu, M. Oshima and Z. Jun, Analyst, 115, 389 (1990); doi:10.1039/an9901500389.
- H. Zollinger, Diazo Chemistry I, Wiley-VCH: Weinheim, p. 306 (1994).
- M. Tuncel and S. Serin, Transition Met. Chem., 31, 805 (2006); doi:10.1007/s11243-006-0074-5.
- C.J. Tredwell and C.M. Keary, Chem. Phys., 43, 307 (1979); doi:10.1016/0301-0104(79)85199-X.
- N.M. Rageh, A. Mawgoud and H.M. Mostafa, Chem. Papers, 53, 107 (1998).
- A. Gruger, A. Novak, A. Regis and Ph. Colomban, J. Mol. Struct., 328, 153 (1994); doi:10.1016/0022-2860(94)08368-1.
- P.W. Selwood, Magnetochemistry, Interscience Publishers, New York, p. 78 (1956).
- H. Lampert, W. Mikenda and A. Karpfen, J. Phys. Chem., 100, 7418 (1996); doi:10.1021/jp953527k.
- M. Tuncel and S. Serin, Synth. React. Inorg. Met. Org. Nano-Met. Chem., 35, 203 (2005); doi:10.1081/SIM-200037841.
- C. Anitha, C.D. Sheela, P. Tharmaraj and S. Johnson Raja, Spectrochim. Acta A, 98, 35 (2012); doi:10.1016/j.saa.2012.08.022.
- S. Pinchas, B.L. Silver and I. Laulicht, J. Chem. Phys., 46, 1506 (1967); doi:10.1063/1.1840881.
- A. Lycka and J. Jirman, Dyes Pigments, 8, 315 (1987); doi:10.1016/0143-7208(87)85021-0.
- M. Ilczyszyn, Z. Latajka and H. Ratajczak, Magn. Reson. Chem., 13, 132 (1980); doi:10.1002/mrc.1270130215.
- S. Alghool, H.F. Abd El-Halim and A. Dahshan, J. Mol. Struct., 983, 32 (2010); doi:10.1016/j.molstruc.2010.08.025.
References
F. Huang, Y. Wu, D. Gu and F. Gan, Dyes Pigments, 66, 77 (2005); doi:10.1016/j.dyepig.2004.08.013.
N. Kabay, E. Erdem, E.Y. Kilincarslan and E.Y. Sari, Transition Met. Chem., 32, 1068 (2007); doi:10.1007/s11243-007-0283-6.
G.A. Ibañez and G.M. Escandar, Polyhedron, 17, 4433 (1998); doi:10.1016/S0277-5387(98)00249-6.
H. Zollinger, Colour Chemistry, Wiley-VCH: Weinheim, edn 3, p. 544 (2003).
G.G. Mohamed and M.A.M. Gad-Elkareem, Spectrochim. Acta A, 68, 1382 (2007); doi:10.1016/j.saa.2007.01.034.
J.Y. Park, Y. Hirata and K. Hamada, Dyes Pigments, 95, 502 (2012); doi:10.1016/j.dyepig.2012.04.019.
R.N. Sah and P.H. Brown, Microchem. J., 56, 285 (1997); doi:10.1006/mchj.1997.1428.
S. Motomizu, M. Oshima and Z. Jun, Analyst, 115, 389 (1990); doi:10.1039/an9901500389.
H. Zollinger, Diazo Chemistry I, Wiley-VCH: Weinheim, p. 306 (1994).
M. Tuncel and S. Serin, Transition Met. Chem., 31, 805 (2006); doi:10.1007/s11243-006-0074-5.
C.J. Tredwell and C.M. Keary, Chem. Phys., 43, 307 (1979); doi:10.1016/0301-0104(79)85199-X.
N.M. Rageh, A. Mawgoud and H.M. Mostafa, Chem. Papers, 53, 107 (1998).
A. Gruger, A. Novak, A. Regis and Ph. Colomban, J. Mol. Struct., 328, 153 (1994); doi:10.1016/0022-2860(94)08368-1.
P.W. Selwood, Magnetochemistry, Interscience Publishers, New York, p. 78 (1956).
H. Lampert, W. Mikenda and A. Karpfen, J. Phys. Chem., 100, 7418 (1996); doi:10.1021/jp953527k.
M. Tuncel and S. Serin, Synth. React. Inorg. Met. Org. Nano-Met. Chem., 35, 203 (2005); doi:10.1081/SIM-200037841.
C. Anitha, C.D. Sheela, P. Tharmaraj and S. Johnson Raja, Spectrochim. Acta A, 98, 35 (2012); doi:10.1016/j.saa.2012.08.022.
S. Pinchas, B.L. Silver and I. Laulicht, J. Chem. Phys., 46, 1506 (1967); doi:10.1063/1.1840881.
A. Lycka and J. Jirman, Dyes Pigments, 8, 315 (1987); doi:10.1016/0143-7208(87)85021-0.
M. Ilczyszyn, Z. Latajka and H. Ratajczak, Magn. Reson. Chem., 13, 132 (1980); doi:10.1002/mrc.1270130215.
S. Alghool, H.F. Abd El-Halim and A. Dahshan, J. Mol. Struct., 983, 32 (2010); doi:10.1016/j.molstruc.2010.08.025.