Synthesis and Characterization of Novel Polymer-Metal Complexes of Cu(II), Ni(II) and Co(II) Derived from Poly(4,5-dihydroxy-2,7-naphthalene Disulfonic Acid)

Mehmet Tuncel

doi:10.14233/ajchem.2014.16604

Issue

Vol. 26 No. 7 (2014): Vol 26 Issue 7

Issue Published : March 22, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Synthesis and Characterization of Novel Polymer-Metal Complexes of Cu(II), Ni(II) and Co(II) Derived from Poly(4,5-dihydroxy-2,7-naphthalene Disulfonic Acid)

https://doi.org/10.14233/ajchem.2014.16604

Mehmet Tuncel

Faculty of Science Education, University of Nigde 51100, Nigde, Turkey

Corresponding Author(s) : Mehmet Tuncel

mtuncel@nigde.edu.tr

Asian Journal of Chemistry, Vol. 26 No. 7 (2014): Vol 26 Issue 7
Article Published : March 31, 2014

Abstract

In this study, poly(4,5-dihydroxy-2,7-naphthalene disulfonic acid) was prepared by means of an oxidative polycondensation reaction of 4,5-dihydroxy-2,7-naphthalenedisulfonic acid disodium salt (monomer) in aqueous alkaline medium with NaOCl as the oxidant at 90 °C. Average molecular weights of the polymer were determined by gel permeation chromatography. The monomer and the polymer were characterized by elemental analyses, gel permeation chromatography, thermogravimetric analyses and UV-visible, FT-IR, ¹H NMR and ¹³C NMR spectroscopic studies. In addition, the new Cu(II), Ni(II) and Co(II) complexes of the polymer were characterized by elemental analyses, UV-visible, FT-IR, and AAS, TGA and magnetic susceptibility measurements. The results suggested that the polymer and metal ions in 2:1 molar ratio produced mononuclear complexes with oxygen donor atoms. All synthesized polymer-metal complexes have dimeric structures formed by the polymeric ligand units. The thermal stability of the polymer-metal complexes is higher than that of the polymer. Magnetic susceptibility studies showed that polymer-metal complexes have various configurations. The metal ion uptake studies were conducted using the batch technique. The barium salt of the polymer was determined to be effective in removing some metal ions via the batch technique.

Keywords

Oxidative polymerization Metal complexes Metal ion uptake

Tuncel, M. (2014). Synthesis and Characterization of Novel Polymer-Metal Complexes of Cu(II), Ni(II) and Co(II) Derived from Poly(4,5-dihydroxy-2,7-naphthalene Disulfonic Acid). Asian Journal of Chemistry, 26(7), 2147–2152. https://doi.org/10.14233/ajchem.2014.16604

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References

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References

S. Thamizharasi, A. Venkata Rami Reddy and S. Balasubramanian, React. Funct. Polym., 40, 143 (1999); doi:10.1016/S1381-5148(98)00021-2.

Ö. Saatçılar, N. Şatiroğlu, S. Bektaş, Ö. Genç and A. Denizli, React. Funct. Polym., 50, 41 (2002); doi:10.1016/S1381-5148(01)00088-8.

S. Destri, M. Pasini, C. Pelizzi, W. Porzio, G. Predieri and C. Vignali, Macromolecules, 32, 353 (1999); doi:10.1021/ma9811932.

I. Kaya, A.R. Vilayetoglu and H. Mart, Polymer, 42, 4859 (2001); doi:10.1016/S0032-3861(00)00883-1.

S. Thamizharasi, J. Vasantha and B.S.R. Reddy, Eur. Polym. J., 38, 551 (2002); doi:10.1016/S0014-3057(01)00196-3.

M. Grigoras and C.O. Catanescu, J. Macromol. Sci. Part C Polym. Rev., 44, 131 (2004); doi:10.1081/MC-120034152.

M.Y. Khuhawar, A.H. Channar and S.W. Shah, Eur. Polym. J., 34, 133 (1998); doi:10.1016/S0014-3057(97)00078-5.

S. Banerjee, P.K. Gutch and C. Saxena, Des. Monomers Polym., 2, 135 (1999); doi:10.1163/156855599X00205.

M.Y. Abdelaal, Int. J. Polym. Mater., 54, 151 (2005); doi:10.1080/00914030390207237.

Y. Sasaki, L.L. Walker, E.L. Hurst and C.U. Pittman Jr, J. Polym. Sci. Polym. Chem., 11, 1213 (1973); doi:10.1002/pol.1973.170110609.

L. Guo, S. Wu, F. Zeng and J. Zhao, Eur. Polym. J., 42, 1670 (2006); doi:10.1016/j.eurpolymj.2006.01.025.

M. Palumbo, A. Cosani and M. Ter bojevich, J. Chem. Soc., 99, 939 (1977).

A.D. Pomogailo and I.E. Uflyand, J. Mol. Catal., 55, 429 (1989); doi:10.1016/0304-5102(89)80277-9.

S. Nanjundan, C.S.J. Selvamalar and R. Jayakumar, Eur. Polym. J., 40, 2313 (2004); doi:10.1016/j.eurpolymj.2004.05.015.

S. Ciofi-Baﬀoni, L. Banci and A. Brandi, J. Chem. Soc., Perkin Trans., 3207 (1998); doi:10.1039/A805027I.

M. Tunçel, H. Kahyaoglu and M. Çakir, Transition Metal Chem., 33, 605 (2008); doi:10.1007/s11243-008-9087-6.

J. Basset, R.C. Denny, G.H. Jeffery and J. Mendham, Vogels Text Book of Qualitative Analysis, edn 4 (1978).

N.M. Rageh, A.M.A. Mawgoud and H.M. Mostafa, Chem. Papers, 53, 107 (1999).

P.P. Dholakiya and M.N. Patel, Synth. React. Inorg. Met.-Org.Nano-Chem., 34, 383 (2004); doi:10.1081/SIM-120028308.

M. Tunçel, H. Kahyaoğlu and M. Çakır, Transition Metal Chem., 33, 605 (2008); doi:10.1007/s11243-008-9087-6.

M. Tunçel, A. Özbülbül and S. Serin, React. Funct. Polym., 68, 292 (2008); doi:10.1016/j.reactfunctpolym.2007.08.012.

P. Singh, R. Ghose and A.K. Ghose, Transition Met. Chem., 13, 50 (1988); doi:10.1007/BF01041499.

G.G. Mohamed, Spectrochim. Acta A, 57, 411 (2001); doi:10.1016/S1386-1425(00)00348-6.

A. Özbülbül, H. Mart, M. Tunçel and S. Serin, Des. Monomer Polym., 9, 169 (2006); doi:10.1163/156855506776382655.

E. Sinn and C.M. Harris, Coord. Chem. Rev., 4, 391 (1969); doi:10.1016/S0010-8545(00)80080-6.

A. Milchev, W. Paul and K. Binder, J. Chem. Phys., 99, 4786 (1993); doi:10.1063/1.466027.

Issue

Vol. 26 No. 7 (2014): Vol 26 Issue 7

Synthesis and Characterization of Novel Polymer-Metal Complexes of Cu(II), Ni(II) and Co(II) Derived from Poly(4,5-dihydroxy-2,7-naphthalene Disulfonic Acid)

Corresponding Author(s) : Mehmet Tuncel

Abstract

Keywords

Full Article

Download Citation

References

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