Development of Novel Method for Detection of 38 Pesticides

A. Harinatha Reddy; D. Ravindranath; N.B.L. Prasad; K. Lakshmidevi

doi:10.14233/ajchem.2014.16237

Issue

Vol. 26 No. 7 (2014): Vol 26 Issue 7

Issue Published : March 22, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Development of Novel Method for Detection of 38 Pesticides

https://doi.org/10.14233/ajchem.2014.16237

A. Harinatha Reddy

Jawaharlal Nehru Technological University Anantapur, Anantapur-515 002, India

D. Ravindranath

Acharya N.G. Ranga Agricultural University, Hyderabad-500 030, India

N.B.L. Prasad

OTRI, Jawaharlal Nehru Technological University Anantapur, Anantapur-515 002, India

K. Lakshmidevi

Department of Biochemistry, Sri Krishna Devaraya University, Anantapur-515 003, India

Corresponding Author(s) : N.B.L. Prasad

prasadotri@gmail.com

Asian Journal of Chemistry, Vol. 26 No. 7 (2014): Vol 26 Issue 7
Article Published : March 31, 2014

Abstract

Developed multi residue method for 38 pesticides on GC-ECD Shimadzu 2010. Organochlorines, organo phosphates, synthetic pyrethroids mixtures of standards supplied by Ehrensortfer were prepared in (1:1) hexane:toluene. Eight different concentrations of standards i.e., 0.005, 0.01, 0.025, 0.050, 0.075, 0.1, 0.25 and 0.50 ppm were prepared and injected six replications into GC-ECD. Linearity curve was drawn for each pesticide and regression values were calculated. The regression values for organo-chlorines were found from 0.940 to 0.990 and % RSD values were in permissible range from 0.57 to 10.4. For organophosphates regression values were found from 0.992 to 0.998 range % RSD values were ranged from 0.66 to 14.02. For synthetic pyrethroids, regression values were ranged from 0.956 to 0.999 and % RSD values ranged from 1.1 to 8.9. For all the pesticides linearity curve with all the regression values ³ 0.940 and % RSD values in permissible range from 5.7 to 14.02.

Keywords

GC-ECD Multi residue method Pesticides Organochlorines Organophosphates Synthetic pyrethroids

Harinatha Reddy, A., Ravindranath, D., Prasad, N., & Lakshmidevi, K. (2014). Development of Novel Method for Detection of 38 Pesticides. Asian Journal of Chemistry, 26(7), 2105–2109. https://doi.org/10.14233/ajchem.2014.16237

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References

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References

M.W. Stimman, J.S. Bailey and A.S. Deal, Study Guide for Agricultural Pest Control Advisers on Insects, Mites and Other Invertebrates and their control in Califonia, pp: 69-70 (1985).

H. Bouwman, S. Afr. J. Sci., 100, 323 (2004).

L. Fleming, J.B. Mann, J. Bean, T. Briggle and J.R. Sanchez-Ramos, Ann. Neurol., 36, 100 (1994); doi:10.1002/ana.410360119.

D.H. Garabrant, J. Held, B. Langholz, J.M. Peters and T.M. Mack, J. Natl. Cancer Inst., 84, 764 (1992); doi:10.1093/jnci/84.10.764.

H. Lars, in ed.: M. Lennart, Environmental Exposure to Persistent Organo-halogen and Health Risks. In: Environmental Medicine, Ch: 12, (2000); Retrieved from: www.envimed.com.

J.D. McKinney and C.L. Waller, Environ. Health Perspect., 102, 290 (1994); doi:10.1289/ehp.94102290.

C.D.S. Tomlin, The Pesticide Manual, British Crop Protection Council, Surrey, edn. 11 (1997).

J. Chen, C.F. Duan and Y.F. Guan, J. Chromatogr. B Analyt. Technol. Biomed. Life Sci., 878, 1216 (2010); doi:10.1016/j.jchromb.2010.02.031.

K. Buonasera, G. D’Orazio, S. Fanali, P. Dugo and L. Mondello, J. Chromatogr. A, 1216, 3970 (2009); doi:10.1016/j.chroma.2009.03.005.

Q. Li, N. Nagahara, H. Takahashi, K. Takeda and K. Okumura, Toxicology, 172, 181 (2002); doi:10.1016/S0300-483X(02)00004-5.

S. Bosgra, H.V.D. Voet, P.E. Boon and W. Slob, Regul. Toxicol. Pharmacol., 54, 124 (2009); doi:10.1016/j.yrtph.2009.03.004.

S.-X. Guan, Z.-G. Yu, H.-N. Yu, C.-H. Song, Z.-Q. Song and Z. Qin, Chromatographia, 73, 33 (2011); doi:10.1007/s10337-010-1840-2.

M.I. Cervera, C. Medina, T. Portolés, E. Pitarch, J. Beltrán, E. Serrahima, L. Pineda, G. Muñoz, F. Centrich and F. Hernández, Anal. Bioanal. Chem., 397, 2873 (2010); doi:10.1007/s00216-010-3597-8.

B.M. Keikotlhaile and P. Spanoghe, in ed.: M. Stoytcheva, Pesticide Residues in Fruits and Vegetables, In: Pesticides-Formulations, Effects, Fate, Ch. 13, ISBN: 978-953-307-532-7, InTech (2011).

U. Koesukwiwat, S.J. Lehotay and N. Leepipatpiboon, J. Chromatogr. A, 1218, 7039 (2011); doi:10.1016/j.chroma.2011.07.094.

S.J. Lehotay and K.I. Eller, J. AOAC Int., 78, 821 (1995).

K. Adou, W.R. Bontoyan and P.J. Sweeney, J. Agric. Food Chem., 49, 4153 (2001); doi:10.1021/jf001528q.

B.B. Gökçen and F. Akçada, Determination of Organochlorine Pesticides in Tomato and Evaluation of Proficiency Testing Results, XIX IMEKO World Congress Fundamental and Applied Metrology, September 6-11, Lisbon, Portugal, pp. 2595-2597 (2009).

M.A. Presta, D.I. Ströher Kolberg, C. Wickert, I.R. Pizzutti, M.B. Adaime and R. Zanella, Chromatographia, 69, 237 (2009); doi:10.1365/s10337-008-0896-8.

Issue

Vol. 26 No. 7 (2014): Vol 26 Issue 7

Development of Novel Method for Detection of 38 Pesticides

Corresponding Author(s) : N.B.L. Prasad

Abstract

Keywords

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