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Vol. 26 No. 7 (2014): Vol 26 Issue 7

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Adsorption Behaviour of Co(II) from Aqueous Solutions onto D113-III Resin

https://doi.org/10.14233/ajchem.2014.15627
Xinlong Jiang
College of Biology and Environmental Engineering, Zhejiang Shuren University, Hangzhou 310015, P.R. China
Liqun Yang
Department of Applied Chemistry, Zhejiang Gongshang University, Hangzhou 310012 P.R. China
Qing Yang
Department of Chemical Engineering, University of Minnesota, Duluth 55812, USA
Chunhua Xiong
Department of Applied Chemistry, Zhejiang Gongshang University, Hangzhou 310012 P.R. China
Jianxiong Jiang
Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 310036, P.R. China
Qian Jia
Department of Applied Chemistry, Zhejiang Gongshang University, Hangzhou 310012 P.R. China
Qing Chen
Department of Applied Chemistry, Zhejiang Gongshang University, Hangzhou 310012 P.R. China

Corresponding Author(s) : Chunhua Xiong

xiongch@163.com

Asian Journal of Chemistry, Vol. 26 No. 7 (2014): Vol 26 Issue 7

Abstract

In this study, the adsorption and desorption properties of Co(II) on D113-III resin have been studied. The different variables affecting the adsorption capacity such as pH of the solution, temperature and contact time have been investigated, which indicate that D113-III resin could adsorb Co(II) effectively from aqueous solution. The results show that the optimal adsorption condition of D113-III resin for Co(II) is achieved at pH = 6.5. The maximum saturated adsorption capacity of Co(II) is 192.1 mg g-1 D113-III resin at 298 K. The thermodynamic parameters such as DGo which were all negative and DHo which was positive, indicated that the adsorption of Co(II) ion onto D113-III resin was spontaneous and endothermic, respectively. Positive DSo value of Co(II) adsorption process indicates an irregular increase of the randomness at the D113-III resin-solution interface during adsorption. Adsorption isotherms correlated well with the Langmuir model. Experimental data were also evaluated to find out kinetic characteristics of the adsorption process. Desorption studies revealed that Co(II) ion could be eluted effectively by using the 0.25-1.0 mol L-1 HCl solution. Thomas model was applied to experimental data to predict the breakthrough curves and to determine the characteristics parameters of the column useful for process design.

Keywords

D113-III resin Co(II) Adsorption Thermodynamics Adsorption isotherm
Jiang, X., Yang, L., Yang, Q., Xiong, C., Jiang, J., Jia, Q., & Chen, Q. (2014). Adsorption Behaviour of Co(II) from Aqueous Solutions onto D113-III Resin. Asian Journal of Chemistry, 26(7), 2022–2026. https://doi.org/10.14233/ajchem.2014.15627
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