Effect of Sm3+ on the Spectroscopic Properties of Poly(N-vinylisobutyramide)

Zhidu Chen; Shoufu Yu; Shaofen Guo

doi:10.14233/ajchem.2014.15590

Issue

Vol. 26 No. 7 (2014): Vol 26 Issue 7

Issue Published : March 22, 2014

This work is licensed under a Creative Commons Attribution 4.0 International License.

Effect of Sm3+ on the Spectroscopic Properties of Poly(N-vinylisobutyramide)

https://doi.org/10.14233/ajchem.2014.15590

Zhidu Chen

Shandong Provincial Key Laboratory of Water and Soil Conservation & Environmental Protection, Linyi University, Linyi 276005, P.R. China

Shoufu Yu

Shandong Provincial Key Laboratory of Water and Soil Conservation & Environmental Protection, Linyi University, Linyi 276005, P.R. China

Shaofen Guo

Shandong Provincial Key Laboratory of Water and Soil Conservation & Environmental Protection, Linyi University, Linyi 276005, P.R. China

Corresponding Author(s) : Shaofen Guo

guoshaofen@lyu.edu.cn

Asian Journal of Chemistry, Vol. 26 No. 7 (2014): Vol 26 Issue 7
Article Published : March 31, 2014

Abstract

In this paper, the effect of Sm³⁺ on the spectroscopic properties of poly(N-vinylisobutyramide) (PNVIBA) polymer was investigated by using ultraviolet-visible, FT-IR and fluorescent spectroscopy techniques. It was found that Sm³⁺ might coordinate with N atoms in the PNVIBA side chain and form the Sm³⁺-PNVIBA complex. After forming the Sm³⁺-PNVIBA complex, the fluorescence emission intensity at 315 nm was significantly enhanced 1.73 times comparing with that of the PNVIBA polymer, in which the efficient intramolecular energy transfer from Sm³⁺ to PNVIBA might be occurred. The Sm³⁺-PNVIBA complex could transform the short ultraviolet radiation to longer wavelength UV-B band radiation. However, the low critical solution temperature (LCST) of PNVIBA was not obviously changed after the addition of a small amount of Sm³⁺. This thermosensitive complex might be a potential functional material in many fields.

Keywords

Sm3 Poly(N-vinylisobutyramide) Fluorescence property Low critical solution temperature

Chen, Z., Yu, S., & Guo, S. (2014). Effect of Sm3+ on the Spectroscopic Properties of Poly(N-vinylisobutyramide). Asian Journal of Chemistry, 26(7), 1965–1968. https://doi.org/10.14233/ajchem.2014.15590

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References

M. Akashi, S. Nakano and A. Kishida, J. Polym. Sci. A: Polym. Chem., 34, 301 (1996); doi:10.1002/(SICI)1099-0518(19960130)34:2<301::AID-POLA16>3.0.CO;2-U.
K. Suwa, Y. Wada, Y. Kikunaga, K. Morishita, A. Kishida and M. Akashi, J. Polym. Sci. A: Polym. Chem., 35, 1763 (1997); doi:10.1002/(SICI)1099-0518(19970715)35:9<1763::AID-POLA17>3.0.CO;2-3.
S. Kunugi, T. Tada, Y. Yamazaki, K. Yamamoto and M. Akashi, Langmuir, 16, 2042 (2000); doi:10.1021/la991041f.
M. Heskins and J.E. Guillet, J. Macromol. Sci.- Chem. Anal., 2, 1441 (1968); doi:10.1080/10601326808051910.
S. Kunugi, T. Tada, N. Tanaka, K. Yamamoto and M. Akashi, Polym. J., 34, 383 (2002); doi:10.1295/polymj.34.383.
W. Yin, M. Chen, T. Lu, M. Akashi and X. Huang, Eur. Polym. J., 42, 1305 (2006); doi:10.1016/j.eurpolymj.2005.12.014.
W. Yin, M. Chen, T. Lu, M. Akashi and X. Huang, J. Alloys Comp., 432, L18 (2007); doi:10.1016/j.jallcom.2006.06.017.
Y. Cai, M. Chen, X. Huang and J. Shen, Acta Polym. Sin., 4, 599 (2003).
Y. Cai, M. Chen and X. Huang, J. Rare Earths, 23, 230 (2005).
S. Guo, M. Chen, T. Lu, M. Akashi, Q. Zhou and X. Huang, Chin. J. Inorg. Chem., 21, 633 (2005).
M.Z. Liu, F.L. Bian and F.L. Sheng, Eur. Polym. J., 41, 283 (2005); doi:10.1016/j.eurpolymj.2004.09.008.
H.-Y. Feng, S.-H. Jian, Y.-P. Wang, Z.-Q. Lei and R.-M. Wang, J. Appl. Polym. Sci., 68, 1605 (1998); doi:10.1002/(SICI)1097-4628(19980606)68:10<1605::AID-APP9>3.0.CO;2-L.
V. Bekiari, G. Pistolis and P. Lianos, Mater. Chem., 11, 3189 (1999); doi:10.1021/cm991059b.

References

M. Akashi, S. Nakano and A. Kishida, J. Polym. Sci. A: Polym. Chem., 34, 301 (1996); doi:10.1002/(SICI)1099-0518(19960130)34:2<301::AID-POLA16>3.0.CO;2-U.

K. Suwa, Y. Wada, Y. Kikunaga, K. Morishita, A. Kishida and M. Akashi, J. Polym. Sci. A: Polym. Chem., 35, 1763 (1997); doi:10.1002/(SICI)1099-0518(19970715)35:9<1763::AID-POLA17>3.0.CO;2-3.

S. Kunugi, T. Tada, Y. Yamazaki, K. Yamamoto and M. Akashi, Langmuir, 16, 2042 (2000); doi:10.1021/la991041f.

M. Heskins and J.E. Guillet, J. Macromol. Sci.- Chem. Anal., 2, 1441 (1968); doi:10.1080/10601326808051910.

S. Kunugi, T. Tada, N. Tanaka, K. Yamamoto and M. Akashi, Polym. J., 34, 383 (2002); doi:10.1295/polymj.34.383.

W. Yin, M. Chen, T. Lu, M. Akashi and X. Huang, Eur. Polym. J., 42, 1305 (2006); doi:10.1016/j.eurpolymj.2005.12.014.

W. Yin, M. Chen, T. Lu, M. Akashi and X. Huang, J. Alloys Comp., 432, L18 (2007); doi:10.1016/j.jallcom.2006.06.017.

Y. Cai, M. Chen, X. Huang and J. Shen, Acta Polym. Sin., 4, 599 (2003).

Y. Cai, M. Chen and X. Huang, J. Rare Earths, 23, 230 (2005).

S. Guo, M. Chen, T. Lu, M. Akashi, Q. Zhou and X. Huang, Chin. J. Inorg. Chem., 21, 633 (2005).

M.Z. Liu, F.L. Bian and F.L. Sheng, Eur. Polym. J., 41, 283 (2005); doi:10.1016/j.eurpolymj.2004.09.008.

H.-Y. Feng, S.-H. Jian, Y.-P. Wang, Z.-Q. Lei and R.-M. Wang, J. Appl. Polym. Sci., 68, 1605 (1998); doi:10.1002/(SICI)1097-4628(19980606)68:10<1605::AID-APP9>3.0.CO;2-L.

V. Bekiari, G. Pistolis and P. Lianos, Mater. Chem., 11, 3189 (1999); doi:10.1021/cm991059b.

Issue

Vol. 26 No. 7 (2014): Vol 26 Issue 7

Effect of Sm3+ on the Spectroscopic Properties of Poly(N-vinylisobutyramide)

Corresponding Author(s) : Shaofen Guo

Abstract

Keywords

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