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Assembly of ZSM-5 Zeolite on Natural Fiber
Corresponding Author(s) : Seung Kyu Park
Asian Journal of Chemistry,
Vol. 26 No. 6 (2014): Vol 26 Issue 6
Abstract
Some materials such as nano silver and nano transition metals impregnated zeolite materials may have extraordinary properties such as antibacterial and antivirus. But they might cause the inhalation toxicity, since the size and surface area are recognized as important determinants for toxicity to human. We report the ZSM-5 zeolite anchored kapok fiber synthesized by hydrothermal reaction. We suggest that self assembly of such functional materials to natural fiber can reduce the inhalation risk and maximize the functionality of nano materials. To get the clear and smooth surface of the hollow fiber, solvent and acid treatment process had been adopted to remove the lignin and wax layer. The hollow kapok fibers were applied as a template in the hydrothermal reaction for preparation of ZSM-5 zeolite anchored Kapok fiber. The Kapok-ZSM-5 composites were confirmed and characterized by SEM, XRD, TG-DTA and FTIR analysis.
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- C.T. Kresge, M.E. Leonowicz, W.J. Roth, J.C. Vartuli and J.S. Beck, Nature, 359, 710 (1992); doi:10.1038/359710a0.
- D. Zhao, J. Feng, Q. Huo, N. Melosh, G.H. Fredrickson, B.F. Chmelka and G.D. Stucky, Science, 279, 548 (1998); doi:10.1126/science.279.5350.548.
- G. Stucky, Y. Sakamoto, M. Kaneda, O. Terasaki, D.Y. Zhao, J.M. Kim, H.J. Shin and R. Ryoo, Nature, 408, 449 (2000); doi:10.1038/35044040.
- S.B. Yoon, K. Sohn, J.Y. Kim, C.-H. Shin, J.-S. Yu and T. Hyeon, Adv. Mater., 14, 19 (2002); doi:10.1002/1521-4095(20020104)14:1<19::AID-ADMA19>3.0.CO;2-X.
- S.B. Yoon, J.-Y. Kim, J.H. Kim, Y.J. Park, K.R. Yoon, S.-K. Park and J.-S. Yu, J. Mater. Chem., 17, 1758 (2007); doi:10.1039/b617471j.
- W. Zhang, Z. Huang, Z. Guo, C. Li and F. Kang, Mater. Lett., 64, 1868 (2010); doi:10.1016/j.matlet.2010.06.007.
- Y. Xia, B. Gates, Y. Yin and Y. Lu, Adv. Mater., 12, 693 (2000); doi:10.1002/(SICI)1521-4095(200005)12:10<693::AID-ADMA693>3.0.CO;2-J.
- D. Cao, P. Feng and J. Wu, Nano Lett., 4, 1489 (2004); doi:10.1021/nl0491475.
- D.W. Breck, Zeolite Molecular Sieves; Wiley: New York, Ch.1-7 (1974).
- R. Szostak, Molecular Sieves: Principles of Synthesis and Identification; Van Nostrand Reinhold: New York, 1989; Chapters 1 and 2.
- A. Dyer, An Introduction to Zeolite Molecular Sieves, Wiley: New York (1988).
- S. Bhatia, Zeolite Catalysis: Principles and Application; CRC: Boca Raton, FL, Ch. 1-5 and 10 (1996).
- J.P. Kim, I.-H. Cho, I.-T. Kim, C.-U. Kim, N.H. Heo and S.-H. Suh, Rev. Roum. Chim., 51, 1121 (2006).
- S. Galdiero, A. Falanga, M. Vitiello, M. Cantisani, V. Marra and M. Galdiero, Molecules, 16, 8894 (2011); doi:10.3390/molecules16108894.
- S.N. Luoma, Y.B. Ho and G.W. Bryan, Mar. Pollut. Bull., 31, 44 (1995); doi:10.1016/0025-326X(95)00081-W.
- J.V. Rogers, C.V. Parkinson, Y.W. Choi, J.L. Speshock and S.M. Hussain, Nanoscale Res. Lett., 3, 129 (2008); doi:10.1007/s11671-008-9128-2.
- N.R. Panyala, E.M.P. Mendez and J. Havel, J. Appl. Biomed., 6, 117 (2008).
- J.S. Lee, Y.-J. Lee, E.L. Tae, Y.S. Park and K.B. Yoon, Science, 301, 818 (2003); doi:10.1126/science.1086441.
- R. Malkapuram, V. Kumar and Y.S. Negi, Reinf. Plast. Comp., 28, 1169 (2009); doi:10.1177/0731684407087759.
- X.Y. Zhang, C. Duan, N. Zhao, H. Xiao, M. Shi, X. Zhang and J. Xu, Chinese J. Polym. Sci., 28, 841 (2010); doi:10.1007/s10118-010-0044-4.
- S.-K. Park, V. Kurshev, Z. Luan, C. Wee Lee and L. Kevan, Micropor. Mesopor. Mater., 38, 255 (2000); doi:10.1016/S1387-1811(00)00145-1.
- T.-T. Lim and X. Huang, Ind. Crops Prod., 26, 125 (2007); doi:10.1016/j.indcrop.2007.02.007.
- H.J. Kim, C.H. Kwak, T.S. Suh and S.S. Suhr, Hwahak Konghak, 40, 377 (2000).
References
C.T. Kresge, M.E. Leonowicz, W.J. Roth, J.C. Vartuli and J.S. Beck, Nature, 359, 710 (1992); doi:10.1038/359710a0.
D. Zhao, J. Feng, Q. Huo, N. Melosh, G.H. Fredrickson, B.F. Chmelka and G.D. Stucky, Science, 279, 548 (1998); doi:10.1126/science.279.5350.548.
G. Stucky, Y. Sakamoto, M. Kaneda, O. Terasaki, D.Y. Zhao, J.M. Kim, H.J. Shin and R. Ryoo, Nature, 408, 449 (2000); doi:10.1038/35044040.
S.B. Yoon, K. Sohn, J.Y. Kim, C.-H. Shin, J.-S. Yu and T. Hyeon, Adv. Mater., 14, 19 (2002); doi:10.1002/1521-4095(20020104)14:1<19::AID-ADMA19>3.0.CO;2-X.
S.B. Yoon, J.-Y. Kim, J.H. Kim, Y.J. Park, K.R. Yoon, S.-K. Park and J.-S. Yu, J. Mater. Chem., 17, 1758 (2007); doi:10.1039/b617471j.
W. Zhang, Z. Huang, Z. Guo, C. Li and F. Kang, Mater. Lett., 64, 1868 (2010); doi:10.1016/j.matlet.2010.06.007.
Y. Xia, B. Gates, Y. Yin and Y. Lu, Adv. Mater., 12, 693 (2000); doi:10.1002/(SICI)1521-4095(200005)12:10<693::AID-ADMA693>3.0.CO;2-J.
D. Cao, P. Feng and J. Wu, Nano Lett., 4, 1489 (2004); doi:10.1021/nl0491475.
D.W. Breck, Zeolite Molecular Sieves; Wiley: New York, Ch.1-7 (1974).
R. Szostak, Molecular Sieves: Principles of Synthesis and Identification; Van Nostrand Reinhold: New York, 1989; Chapters 1 and 2.
A. Dyer, An Introduction to Zeolite Molecular Sieves, Wiley: New York (1988).
S. Bhatia, Zeolite Catalysis: Principles and Application; CRC: Boca Raton, FL, Ch. 1-5 and 10 (1996).
J.P. Kim, I.-H. Cho, I.-T. Kim, C.-U. Kim, N.H. Heo and S.-H. Suh, Rev. Roum. Chim., 51, 1121 (2006).
S. Galdiero, A. Falanga, M. Vitiello, M. Cantisani, V. Marra and M. Galdiero, Molecules, 16, 8894 (2011); doi:10.3390/molecules16108894.
S.N. Luoma, Y.B. Ho and G.W. Bryan, Mar. Pollut. Bull., 31, 44 (1995); doi:10.1016/0025-326X(95)00081-W.
J.V. Rogers, C.V. Parkinson, Y.W. Choi, J.L. Speshock and S.M. Hussain, Nanoscale Res. Lett., 3, 129 (2008); doi:10.1007/s11671-008-9128-2.
N.R. Panyala, E.M.P. Mendez and J. Havel, J. Appl. Biomed., 6, 117 (2008).
J.S. Lee, Y.-J. Lee, E.L. Tae, Y.S. Park and K.B. Yoon, Science, 301, 818 (2003); doi:10.1126/science.1086441.
R. Malkapuram, V. Kumar and Y.S. Negi, Reinf. Plast. Comp., 28, 1169 (2009); doi:10.1177/0731684407087759.
X.Y. Zhang, C. Duan, N. Zhao, H. Xiao, M. Shi, X. Zhang and J. Xu, Chinese J. Polym. Sci., 28, 841 (2010); doi:10.1007/s10118-010-0044-4.
S.-K. Park, V. Kurshev, Z. Luan, C. Wee Lee and L. Kevan, Micropor. Mesopor. Mater., 38, 255 (2000); doi:10.1016/S1387-1811(00)00145-1.
T.-T. Lim and X. Huang, Ind. Crops Prod., 26, 125 (2007); doi:10.1016/j.indcrop.2007.02.007.
H.J. Kim, C.H. Kwak, T.S. Suh and S.S. Suhr, Hwahak Konghak, 40, 377 (2000).